Journal of Chemical Crystallography

, Volume 40, Issue 12, pp 1180–1187 | Cite as

Spectroscopic, Thermal and Structural Studies of Cocrystals of 2,2′-Diamino-4,4′-bis(1,3-thiazole) with 2,5-Bis(4-pyridyl)-3,4-Diaza-2,4-Hexadiene and 1,2-Bis(4-pyridyl)Ethylenediamine

  • Jafar Abedini
  • Robabeh Safiei
  • Zohreh Rashidi Ranjbar
  • Ali Morsali
Original Paper
First Online:
Received:
Accepted:

Abstract

Two cocrystals of 2,2′-diamino-4,4′-bis(1,3-thiazole) (DABTZ) with 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene (bpdh) and 1,2-bis(4-pyridyl)ethylenediamine (bpen) {[(DABTZ)(bpdh)] and [(DABTZ)(bpen)], respectively} have been synthesized and characterized by elemental analysis, IR-, 1H NMR-, 13C NMR spectroscopy and were studied by thermal analysis and X-ray crystallography. Self-assembly of these compounds in the solid state is likely caused by hydrogen bonding with minor contributions from π–π stacking, C–H···π and possibly charge transfer interactions.

Graphical Abstract

Two cocrystals of 2,2′-diamino-4,4′-bis(1,3-thiazole) with 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene and 1,2-bis(4-pyridyl)ethylenediamine have been synthesized and characterized.

Keywords

Cocrystal 2,2′-Diamino-4,4′-bis(1,3-thiazole) 2,5-Bis(4-pyridyl)-3,4-diaza-2,4-hexadiene 1,2-Bis(4-pyridyl)ethylenediamine 
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Notes

Acknowledgments

This work was supported by the Payameh Noor University.

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Jafar Abedini
    • 1
  • Robabeh Safiei
    • 1
  • Zohreh Rashidi Ranjbar
    • 2
  • Ali Morsali
    • 2
  1. 1.Department of ChemistryPayame Noor UniversityZanjanIslamic Republic of Iran
  2. 2.Department of Chemistry, Faculty of SciencesTarbiat Modares UniversityTehranIslamic Republic of Iran

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