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Journal of Chemical Crystallography

, Volume 40, Issue 8, pp 712–715 | Cite as

X-ray Structure of mer-[Mo(CO)3(PPh3)(κ 2-dppm)]

  • Shishir Ghosh
  • Shariff E. Kabir
  • Farzana K. Camellia
  • Md. Kamal Hossain
  • Daniel T. Haworth
  • Sergey V. Lindeman
  • Tasneem A. Siddiquee
  • Dennis W. Bennett
Notes
  • 165 Downloads

Abstract

Treatment of [Mo(CO)3(NCMe)3] with bis(diphenylphosphino)methane (dppm) and triphenylphosphine (PPh3) at 50 °C afforded mer-[Mo(CO)3(PPh3)(κ 2-dppm)] (1) in 55% yield which has been characterized by single crystal X-ray diffraction studies and spectroscopic measurements. Compound 1 crystallizes in the triclinic space group P−1 with a = 10.3449(6), b = 11.1570(6), c = 17.8961(10) Å, β = 80.8400(10)°, Z = 2 and V = 1959.8(2) Å3.

Graphical Abstract

Synthesis and molecular structure of mer-[Mo(CO)3(PPh3)(κ 2-dppm)] are described

Keywords

Molybdenum Bis(diphenylphosphino)methane Triphenylphosphine X-ray structure 

Notes

Acknowledgments

Financial support of this work by the University Grants Commission of Bangladesh is gratefully acknowledged.

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Shishir Ghosh
    • 1
  • Shariff E. Kabir
    • 1
  • Farzana K. Camellia
    • 1
  • Md. Kamal Hossain
    • 1
  • Daniel T. Haworth
    • 2
  • Sergey V. Lindeman
    • 2
  • Tasneem A. Siddiquee
    • 3
  • Dennis W. Bennett
    • 3
  1. 1.Department of ChemistryJahangirnagar UniversitySavar, DhakaBangladesh
  2. 2.Department of ChemistryMarquette UniversityMilwaukeeUSA
  3. 3.Department of ChemistryUniversity of Wisconsin-MilwaukeeMilwaukeeUSA

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