Journal of Chemical Crystallography

, Volume 40, Issue 11, pp 909–913

Synthesis, Spectroscopic Studies and Structure of 2-[(Benzo[d]thiazol-2-ylamino)methyl]phenol

  • Mustafa Yıldız
  • Hava Özay
  • Hüseyin Ünver
  • Nazan Ocak İskeleli
  • D. Mehmet Zengin
  • Tahsin Nuri Durlu
Original Paper

DOI: 10.1007/s10870-010-9761-3

Cite this article as:
Yıldız, M., Özay, H., Ünver, H. et al. J Chem Crystallogr (2010) 40: 909. doi:10.1007/s10870-010-9761-3

Abstract

Schiff base (E)-2-[(benzo[d]thiazol-2-ylimino)methyl]phenol (1) has been synthesized from the reaction of 2-hydroxy-benzaldehyde with 2-aminobenzothiazole. The 2-[(benzo[d]thiazol-2-ylamino)methyl]phenol (2) was prepared reduction of the Schiff base 1 with sodium borohydride. The compounds 1 and 2 have been characterized by elemental analysis, FT-IR, 1H-NMR, 13C-NMR and UV–visible spectroscopic techniques. The structure of the compound 2 has also been examined crystallographically. The compound 2 crystallizes in the monoclinic space group P2/c. The unit cell parameters were found as a = 10.017(1), b = 11.725(1), c = 10.341(1) Å, V = 1208.1(1) Å3, Dx = 1.409 g cm−3 and Z = 4. The crystal structure was solved by direct methods and refined by the full-matrix least squares method and found as R1 = 0.0308 and wR2 = 0.0818 for 2032 for the observed reflections [I > 2σ(I)].

Graphical Abstract

Crystal and molecular structure of the compound 2-[(benzo[d]thiazol-2-ylamino)methyl]phenol have been studied in order to reveal the presence of either the enol-imine or keto-amine forms related with hydrogen bonding by using FT-IR, 1H-NMR, 13C-NMR, UV–visible spectroscopic and X-ray crystallographic techniques.

Keywords

Crystal structure Spectroscopic studies FT-IR UV–visible NMR 

Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Mustafa Yıldız
    • 1
  • Hava Özay
    • 1
  • Hüseyin Ünver
    • 2
  • Nazan Ocak İskeleli
    • 3
  • D. Mehmet Zengin
    • 2
  • Tahsin Nuri Durlu
    • 2
  1. 1.Department of Chemistry, Faculty of Science and ArtsÇanakkale Onsekiz Mart UniversityÇanakkaleTurkey
  2. 2.Department of Physics, Faculty of ScienceAnkara UniversityBeşevler-AnkaraTurkey
  3. 3.Department of Science EducationOndokuz Mayıs UniversityAtakum, SamsunTurkey

Personalised recommendations