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Journal of Chemical Crystallography

, Volume 39, Issue 3, pp 225–227 | Cite as

[KCl3{H2dabco}]: A Unique 3-D Charge-Assisted Hydrogen-Bonded Hybrid Network of Anionic KCl3 Chains and Organic Cations

  • Franck Thétiot
  • Isabelle Sasaki
  • Carine Duhayon
  • Jean-Pascal SutterEmail author
Communication

Abstract

The 3-D hybrid network [KCl3{H2dabco}] resulted from the assemblage of KCl and [{H2dabco}Cl2] (1,4-diazabicyclo[2.2.2]octane) in H2O. The compound crystallizes in the trigonal space group R-3c with a = b = 16.0437(2) Å, and c = 22.3094(2) Å. The structure consists in polymeric chains of anionic {KCl3}2− linked to {H2dabco}2+ units by hydrogen bonds. Each organic cation establishes such charge-assisted H···Cl interactions with two inorganic arrays leading to a 3-D network.

Index Abstract

Assemblage of KCl and [{H2dabco}Cl2] (1,4-diazabicyclo[2.2.2]octane) in H2O resulted in a 3-D hybrid network of inorganic {KCl3}2− chains H-bonded to bridging organic cations.

Keywords

Crystal structure KCl Hybrid material Hydrogen bond Dabco 

Notes

Acknowledgment

The authors are grateful to Dr. Neil Brooks, from Oxford Diffraction, for technical assistance.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Franck Thétiot
    • 1
    • 2
  • Isabelle Sasaki
    • 1
    • 2
  • Carine Duhayon
    • 1
    • 2
  • Jean-Pascal Sutter
    • 1
    • 2
    Email author
  1. 1.CNRS, LCC (Laboratoire de Chimie de Coordination)ToulouseFrance
  2. 2.Université de Toulouse, UPS, INPT, LCCToulouseFrance

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