Journal of Chemical Crystallography

, Volume 39, Issue 3, pp 169–172 | Cite as

Synthesis and Crystal Structure of a 1D Coordination Polymer [Cd(pydc)(phen)]n (H2pydc = pyridine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline)

  • Zheng-Bo Han
  • Guo-Xin Zhang
  • Jian-Wei Ji
  • Peng Zhang
Original Paper
First Online:
Received:
Accepted:

Abstract

A new 1D coordination polymer, [Cd(pydc)(phen)]n (1) (pydc = pyridine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline), has been hydrothermally synthesized and characterized by the elemental analysis, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 (C19H11CdN3O4) crystallizes in triclinic space group P-1, features an interesting 3D zipper-like network constructed from 1D ribbons via π–π stacking interactions. Unit cell parameters for 1: a = 7.681(1) Å, b = 10.546(2) Å, c = 11.358(2) Å, α = 107.12(2)°, β = 99.50(2)°, γ = 109.12 (2)° and Z = 2.

Index Abstract

The title compound, [Cd(pydc)(phen)]n (1) (pydc = pyridine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline), has been hydrothermally synthesized and characterized. X-ray diffraction analysis reveals that 1 features an interesting 3D zipper-like networks constructed by 1D ribbons via π–π stacking interactions.

Keywords

Synthesis Crystal structure Coordination polymer Zipper-like 
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Notes

Acknowledgements

This work was granted financial support from the Program for Liaoning Excellent Talents in University(RC-05-11).

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Zheng-Bo Han
    • 1
  • Guo-Xin Zhang
    • 1
  • Jian-Wei Ji
    • 1
  • Peng Zhang
    • 1
  1. 1.College of ChemistryLiaoning UniversityShenyangPeople’s Republic of China

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