Journal of Chemical Crystallography

, Volume 38, Issue 10, pp 787–792

Crystal Chemistry of 1:1 Molecular Complexes of Carbamate Salts Formed by Slow Aerial Carbonation of Amines

Original Paper

DOI: 10.1007/s10870-008-9391-1

Cite this article as:
Mondal, R. & Bhunia, M.K. J Chem Crystallogr (2008) 38: 787. doi:10.1007/s10870-008-9391-1

Abstract

Amines do have rare tendency to undergo aerial carbonation to form carbamic acid. Four different 1:1 molecular complex of carbamate salts reported herein obtained by the aerial carbonation of cyclic amines. X-ray crystal structures show a systematic change in the molecular structure did bring some gradual supramolecular change from one structural motif to another.

Index Abstract

Amines do have rare tendency to undergo aerial carbonation to form carbamic acid. Four different 1:1 molecular complexes of carbamate salts reported herein obtained by the aerial carbonation of cyclic amines. X-ray crystal structures show a systematic change in the molecular structure did bring some gradual supramolecular change from one structural motif to another.

Keywords

Amine carbonation Crystal growth Molecular structure and crystal engineering 

Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  1. 1.Department of Inorganic ChemistryIndian Association for the Cultivation of ScienceKolkataIndia

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