Journal of Chemical Crystallography

, Volume 36, Issue 10, pp 613–618 | Cite as

Synthesis and crystal structures of two new complexes [M(OH2)(HDPA)2]·3H2O (M = Mn, Co)

  • Ying Liu
  • Jianmin Dou
  • Daqi Wang
  • Dacheng Li
  • Zhaoping Gao
Original Article
First Online:
Received:
Accepted:

Two new transition metal complexes of [M(OH2)(HDPA)2]·3H2O (M=Mn(1); M=Co(2)) (H2DPA, 2,6-pyridine-dicarboxylic acid) have been prepared at room temperature from the reaction of MCl2·6H2O (M=Mn or Co) and H2DPA in the mixed solvent of H2O and EtOH in the presence of piperazine, and were characterized by X-ray analysis, elemental analysis. X-ray analysis reveals that the coordination geometries of Mn2+ and Co2+ are of octahedron and severely distorted square-based pyramid, respectively. Crystal data: [Mn(OH2)(HDPA)2]·3H2O (1), Mr=459.23, monoclinic, P2(1)/n, a=7.0056(3), b=(23.8125(12), c=10.7444(3) Å, β=99.834(2)°, Z=4, V=1766.28(13) Å3, R 1=0.0586, wR 2=0.1448 [I>2σ(I)]; Co(OH2)(HDPA)2]·3H2O (2), Mr=463.22, monoclinic, P2(1)/n, a=7.0014(2), b=23.8346(7), c=10.7212(4) Å, β=99.8540(10)°, Z=4, V=1762.71(10) Å3, R 1=0.0474, wR 2=0.1366 [I>2σ(I)].

KEY WORDS:

Manganese cobalt, 2 6-pyridine-dicarboxylic acid X-ray analysis. 
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Notes

Acknowledgments

The work was supported by the financial support of Liaocheng University (31801) and Professor Jianmin Dou

References

  1. 1.
    Poowell, J.F. Biochemistry 1953, 54, 205–207.Google Scholar
  2. 2.
    Pocker, Y.; Fong, C.T.O. Biochemistry 1980, 16, 2045–2049.CrossRefGoogle Scholar
  3. 3.
    Scapin, G.; Reddy, S.G.; Zheng, R.; Blanchard, J.S. Biochemstry. 1997, 36, 15081–15092.CrossRefGoogle Scholar
  4. 4.
    Scapin, G.; Reddy, S.G.; Zheng, R.; Blanchard, J.S. J. Am. Chem. Soc. 2000, 122, 11692–11702.Google Scholar
  5. 5.
    Scapin, G.; Reddy, S.G.; Zheng, R.; Blanchard, J.S. Cryst. Growth Des. 2004, 4, 1203–1209.Google Scholar
  6. 6.
    Scapin, G.; Reddy, S.G.; Zheng, R.; Blanchard, J.S. Chem. Mater. 2004, 16, 4916–4927.Google Scholar
  7. 7.
    Church, B.S.; Halvorson, H. Nature 1959, 183, 124–125.CrossRefGoogle Scholar
  8. 8.
    Kim, Y.; Lee, E.; Jung, D.Y. Chem. Mater. 2001, 13, 2684–2696.CrossRefGoogle Scholar
  9. 9.
    Ma, C.B.; Chen, C.N.; Liu, Q.T.; Liao, D.Z.; Li, L.C. Eur. J. Inorg. Chem. 2003, 1227–1231.Google Scholar
  10. 10.
    Macdonald, J.C.; Tzy-Jiun, M.Luo; Palmore, G.T.R. Cryst. Growth Des. 2004, 4, 1203–1207.CrossRefGoogle Scholar
  11. 11.
    Ma, C.B.; Fan, C.; Chen, C.N.; Liu, Q.T. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2002, 58, m553.CrossRefGoogle Scholar
  12. 12.
    Xie, C.Z.; Zhang, Z.F.; Liu, X.W.; Wang, X.Q.; Kou, H.Z.; Shen, G.Q.; Shen, D.Z. Inorg. Chem. Commun. 2004, 7, 1037–1041.CrossRefGoogle Scholar
  13. 13.
    Yang, L.Q.; Crans, D.C.; Miller, S.M.; la Cour, A.; Anderson, O.P.; Kaszynski, P.M. Inorg. Chem. 2002, 41, 4859–4871.CrossRefGoogle Scholar
  14. 14.
    Mogjimi, A.; Ranjbar, M.; Aghabozorg, H.; Jalali, F.; Shamsipur, M.; Chadha, K.K. Can. J. Chem. 2002, 80, 1687–1692.CrossRefGoogle Scholar
  15. 15.
    Tong, M.L.; Hung, K.L.; Chen, X.M.; Huang, R.B.; Thomas, C.W.M. J. Chem. Soc., Dalton Trans. 1999, 3657–3569.Google Scholar
  16. 16.
    Macdonald, J.C.; Tzy-Jiun, M.L.; Palmore, G.T.R. Cryst. Growth Des. 2004, 4, 1203–1205.CrossRefGoogle Scholar
  17. 17.
    Hunter, C.A.; Sanders, J.K.M. J. Am. Chem. Soc. 1990, 112, 5525–5527.CrossRefGoogle Scholar
  18. 18.
    Deverreux, M.; Mccan, M.; Leon, V.; Mckee, V.; Ball, R.J. Polyhedron 2002, 21, 1063.CrossRefGoogle Scholar
  19. 19.
    Ma, C.B.; Chen, C.N.; Chen, F.; Hang, X.F.; Zhu, H.P.; Liu, Q.T.; Liao, D.Z.; Li, L.C. Bull. Chem. Soc. Jpn. 2003, 76, 301–307.CrossRefGoogle Scholar
  20. 20.
    Limburg, J.; Brudvig, G.W.; Crabtree, R.H. J. Am. Chem. Soc. 1997, 119, 2761–2762.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • Ying Liu
    • 1
  • Jianmin Dou
    • 1
  • Daqi Wang
    • 1
  • Dacheng Li
    • 1
  • Zhaoping Gao
    • 1
  1. 1.Department of ChemistryLiaocheng UniversityLiaochengP. R. China

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