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Journal of Materials Science: Materials in Medicine

, Volume 19, Issue 9, pp 3063–3070 | Cite as

Preparation, characterization and mechanical performance of dense β-TCP ceramics with/without magnesium substitution

  • Xing Zhang
  • Fengchun Jiang
  • Todd Groth
  • Kenneth S. Vecchio
Article
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Abstract

Beta-tricalcium phosphate (β-TCP) powder was prepared by a two-step process: wet precipitation of apatitic tricalcium phosphate [Ca9(HPO4)(PO4)5(OH)] (β-TCP ‘precursor’) and calcination of the precursor at 800°C for 3 h to produce β-TCP. Magnesium-substituted tricalcium phosphate (β-TCMP) was produced by adding Mg(NO3)2 · 6H2O into Ca(NO3)2 solution as Mg2+ source before the precipitation step. The transition temperature from β-TCP to α-TCP increases with the increase of Mg2+ content in β-TCMP. β-TCMP with 3 mol.% Mg2+ has β-TCP to α-TCP transition temperature above 1,300°C. Dense β-TCMP (3 mol.% Mg2+) ceramics (∼99.4% relative density) were produced by pressing the green bodies at 100 MPa and further sintering at 1,250°C for 2 h. The average compressive strength of dense β-TCP ceramics sintered at 1,100°C is ∼540 MPa, while that of β-TCMP (3 mol.% Mg2+) ceramics is ∼430 MPa.

Keywords

Compressive Strength Tricalcium Phosphate Pressureless Sinter Ceramic Density Average Compressive Strength 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Xing Zhang
    • 1
  • Fengchun Jiang
    • 2
  • Todd Groth
    • 2
  • Kenneth S. Vecchio
    • 2
  1. 1.Materials Science and Engineering ProgramUC San DiegoLa JollaUSA
  2. 2.Department of NanoEngineeringUC San DiegoLa JollaUSA

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