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Red emission from a novel rare earth free oxide-based CaO–0.5Al2O3–0.5Nb2O5:Mn4+ phosphor with high water-resistance property

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Abstract

A 657 nm red emission from a novel rare earth free oxide-based CaO–0.5Al2O3–0.5Nb2O5:xMn4+ (0.001 ≤ x ≤ 0.008) phosphors with high water-resistance property were prepared by solid-state reaction method. The composition and structure of the as-prepared phosphors was studied. Under relative ultraviolet (331/365 nm) and blue (465 nm) light excitation, the as-prepared phosphor presents a 657 nm red emission that assigned to the 2Eg → 4A2g transition of Mn4+ ions. The red light source in CaO–0.5Al2O3–0.5Nb2O5:Mn4+ system was discussed, and the water resistance property of the phosphor was also investigated. The as-prepared phosphor presents more proper red emission position than those of similar oxide-based Mn4+-activated phosphors and shows excellent water-resistance property compared with commercial used K2SiF6:Mn4+ phosphor. With the further optimization of its photo-luminescent properties, the as-prepared CaO–0.5Al2O3–0.5Nb2O5:Mn4+ phosphors may find its potential application in the field of white LEDs.

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Acknowledgements

This work is financially supported by the National Natural Science Foundation of China (NSFC) (Grant Numbers: 51672177, 51902203, 61605115) and the Program of Shanghai Academic/Technology Research Leader (Grant No. 19XD1434700).

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Correspondence to Yongzheng Fang or Jingshan Hou.

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He, D., Fang, Y., Zhang, G. et al. Red emission from a novel rare earth free oxide-based CaO–0.5Al2O3–0.5Nb2O5:Mn4+ phosphor with high water-resistance property. J Mater Sci: Mater Electron (2020). https://doi.org/10.1007/s10854-019-02850-4

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