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Improved room-temperature multiferroicity in Co-doped Aurivillius Sr0.5Bi5.5Fe1.5Ti3.5O18 ceramics

  • Yuxi Lu
  • Hui SunEmail author
  • Zhifeng Wang
  • Xi Xie
  • Tiaoshu Yao
  • Jianlin Wang
  • Yajun Qi
  • Xiaobing Chen
  • Yalin Lu
Article
  • 12 Downloads

Abstract

Multiferroic Sr0.5Bi5.5Fe1.5−xCoxTi3.5O18 (0 ≤ x ≤ 0.5, SBFCT-x) ceramics with layered perovskite structure were successfully prepared by the sol–gel auto-combustion method. The coexistence of ferroelectricity and ferromagnetism was observed at room temperature (RT) for all Co-doped samples. Co substitution can not only remarkably improve ferroelectricity but also enhance the ferromagnetism obviously. In particular, the SBFCT-0.4 sample shows the highest remnant magnetization (2Mr) ~ 1.82 emu/g and the largest remnant polarization (2Pr) ~ 24.4 μC/cm2. Furthermore, dielectric anomalies (x = 0.2–0.5) have been found, which can be ascribed to the long-range migration of oxygen vacancies. The effects of Co doping on ferroelectric, magnetic, and dielectric properties were discussed. The SBFCT-0.4 sample was also found to exhibit the magnetoelectric (ME) effect detectable under a low response magnetic field at RT. And the obvious magnetocapacitance (MC) performance was also observed at and above RT (373 K), which is important to potential applications in sensor technology and memory devices.

Notes

Acknowledgements

This work was supported by National Science Foundation of China (Grant Nos. 51402256, 51472078 and 11374227), Natural Science Foundation of Jiangsu Province, China (No. BK 20161409), and Natural Science Foundation of Higher Education Institutions of Jiangsu Province, China (Grant No. 12KJB140013).

Compliance with ethical standards

Conflict of interest

The authors declare that there is no conflict of interest.

Supplementary material

10854_2019_2614_MOESM1_ESM.docx (152 kb)
Supplementary material 1 (DOCX 152 kb)

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Authors and Affiliations

  1. 1.College of Physics Science and TechnologyYangzhou UniversityYangzhouChina
  2. 2.Guangling College of Yangzhou UniversityYangzhouChina
  3. 3.Testing CenterYangzhou UniversityJiangsuChina
  4. 4.National Laboratory of Solid State Microstructures and Department of PhysicsNanjing UniversityNanjingChina
  5. 5.National Synchrotron Radiation LaboratoryUniversity of Science and Technology of ChinaHefeiChina
  6. 6.Department of Materials Science and EngineeringHubei UniversityWuhanChina

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