Facile fabrication of PVA nanofiber coated with PEDOT as a counter electrode for dye-sensitized solar cell

  • Nur Amilah Fadlina Basri
  • Muhammad Norhaffis Mustafa
  • Yusran SulaimanEmail author


Polyvinyl alcohol (PVA) nanofibers coated with poly(3,4-ethylenedioxythiophene) (PEDOT) as a counter electrode (CE) is a promising material to substitute platinum CE for dye-sensitized solar cell due to the high conductivity of PEDOT and high surface area to volume ratio of PVA. PVA nanofibers and PEDOT were prepared through facile techniques of electrospinning and electropolymerization, respectively. Field emission scanning electron microscopy revealed that PEDOT was distributed evenly on PVA nanofibers with porous cauliflower-like structure. PVA/PEDOT nanofibers CE had low charge transfer resistance (Rct) and possessed a good electrocatalytic activity with a low value of peak-to-peak separation (Epp = 0.34 V), thus an improved efficiency of 2.11% was obtained in comparison to platinum (1.14%), PEDOT (1.39%) and PVA nanofibers (0.017%).



This research work was supported by the Universiti Putra Malaysia Research Grant (GP-IPS/2018/9619300).


  1. 1.
    S. Tampakis, G. Arabatzis, G. Tsantopoulos, I. Rerras, Renew. Sustain. Energy Rev. 79(Suppl C), 39–49 (2017)CrossRefGoogle Scholar
  2. 2.
    A. Yousef, M.S. Akhtar, N.A.M. Barakat, M. Motlak, O.B. Yang, H.Y. Kim, Electrochim. Acta 102(Suppl C), 142–148 (2013)CrossRefGoogle Scholar
  3. 3.
    B. O’Regan, M. Grätzel, Nature 353(6346), 737–740 (1991)CrossRefGoogle Scholar
  4. 4.
    G. Richhariya, A. Kumar, P. Tekasakul, B. Gupta, Renew. Sustain. Energy Rev. 69, 705–718 (2017)CrossRefGoogle Scholar
  5. 5.
    H.R. Baek, I.S. Eo, Curr. Appl. Phys. 17(6), 854–857 (2017)CrossRefGoogle Scholar
  6. 6.
    S. Yun, J.N. Freitas, A.F. Nogueira, Y. Wang, S. Ahmad, Z.-S. Wang, Prog. Polym. Sci. 591, 40 (2016)Google Scholar
  7. 7.
    J. Gong, J. Liang, K. Sumathy, Renew. Sustain. Energy Rev. 16(8), 5848–5860 (2012)CrossRefGoogle Scholar
  8. 8.
    T.-H. Le, Y. Kim, H. Yoon, Polymers 9(4), 150 (2017)CrossRefGoogle Scholar
  9. 9.
    W. Lövenich, Polym. Sci. Ser. C 56(1), 135–143 (2014)CrossRefGoogle Scholar
  10. 10.
    B. Wang, Z. Chen, J. Zhang et al., Colloids Surf. A 457(Suppl C), 318–325 (2014)CrossRefGoogle Scholar
  11. 11.
    M.N. Mustafa, S. Shafie, Z. Zainal, Y. Sulaiman, J. Nanomater. 2017, 1–9 (2017)CrossRefGoogle Scholar
  12. 12.
    M.H. Yeh, C.P. Lee, C.Y. Chou et al., Electrochim. Acta 57, 277–284 (2011)CrossRefGoogle Scholar
  13. 13.
    N.A.M. Barakat, M. Shaheer Akhtar, A. Yousef, M. El-Newehy, H.Y. Kim, Chem. Eng. J. 211–212, 9–15 (2012)CrossRefGoogle Scholar
  14. 14.
    D. Sebastián, V. Baglio, M. Girolamo, R. Moliner, M.J. Lázaro, A.S. Aricò, Carbon nanofiber-based counter electrodes for low cost dye-sensitized solar cells. J. Power Sources 250, 242–249 (2014)CrossRefGoogle Scholar
  15. 15.
    N.A. Zubair, N.A. Rahman, H.N. Lim, Y. Sulaiman, Nanoscale Res. Lett. 12(1), 113 (2017)CrossRefGoogle Scholar
  16. 16.
    N.A. Zubair, N.A. Rahman, H.N. Lim, R.M. Zawawi, Y. Sulaiman, RSC Adv. 6(21), 17720–17727 (2016)CrossRefGoogle Scholar
  17. 17.
    A. Baji, Y.-W. Mai, S.-C. Wong, M. Abtahi, P. Chen, Compos. Sci. Technol. 70(5), 703–718 (2010)CrossRefGoogle Scholar
  18. 18.
    S.N.J. Syed Zainol Abidin, M.S. Mamat, S.A. Rasyid, Z. Zainal, Y. Sulaiman, Electrochim. Acta 261, 548–556 (2018)CrossRefGoogle Scholar
  19. 19.
    S.N.J. Syed Zainol Abidin, S. Mamat, S. Abdul Rasyid, Z. Zainal, Y. Sulaiman, J. Polym. Sci. Part A 56(1), 50–58 (2018)CrossRefGoogle Scholar
  20. 20.
    M.A.A. Mohd Abdah, N.A. Zubair, N.H.N. Azman, Y. Sulaiman, Mater. Chem. Phys. 192, 161–169 (2017)CrossRefGoogle Scholar
  21. 21.
    I.M.A. Mohamed, A.S. Yasin, N.A.M. Barakat, S.A. Song, H.E. Lee, S.S. Kim, Appl. Surf. Sci. 435, 122–129 (2018)CrossRefGoogle Scholar
  22. 22.
    A.M. Hossein, K.M.W. Ahmad, K. Eunice, B.W.F.W. Farahhanim, B.I.N. Fazilah, J. Appl. Polym. Sci. 135(10), 45957 (2018)CrossRefGoogle Scholar
  23. 23.
    Y. Di, Z. Xiao, Z. Liu, B. Chen, J. Feng, Org. Electron. 57, 171–177 (2018)CrossRefGoogle Scholar
  24. 24.
    P. Vijayakumar, M. Senthil Pandian, A. Pandikumar, P. Ramasamy, Mater. Sci. Eng. 222, 7–17 (2017)CrossRefGoogle Scholar
  25. 25.
    F. Gong, H. Wang, X. Xu, G. Zhou, Z.S. Wang, J. Am. Chem. Soc. 134(26), 10953–10958 (2012)CrossRefGoogle Scholar
  26. 26.
    M. Chen, L.-L. Shao, Chem. Eng. J. 304, 629–645 (2016)CrossRefGoogle Scholar
  27. 27.
    J. He, M. Zhou, L. Wang et al., Electrochim. Acta 215, 626–636 (2016)CrossRefGoogle Scholar
  28. 28.
    S. Yun, P.D. Lund, A. Hinsch, Energy Environ. Sci. 8(12), 3495–3514 (2015)CrossRefGoogle Scholar
  29. 29.
    X. Zhao, M. Li, D. Song et al., Nanoscale Res. Lett. 9(1), 202–202 (2014)CrossRefGoogle Scholar
  30. 30.
    T. Sakthivel, K.A. Kumar, J. Senthilselvan, K. Jagannathan, J. Mater. Sci.: Mater. Electron. 29(3), 2228–2235 (2018)Google Scholar
  31. 31.
    S. Hussain, S.A. Patil, D. Vikraman et al., Sci. Rep. 8(1), 29 (2018)CrossRefGoogle Scholar
  32. 32.
    R. Bhattacharjee, I.M. Hung, Mater. Chem. Phys. 143(2), 693–701 (2014)CrossRefGoogle Scholar
  33. 33.
    K.S. Yun, M. Jianwei, Y.H. Bin et al., Adv. Mater. Interfaces 2(18), 1500384 (2015)CrossRefGoogle Scholar
  34. 34.
    M.N. Mustafa, S. Shafie, Z. Zainal, Y. Sulaiman, Mater. Des. 136, 249–257 (2017)CrossRefGoogle Scholar
  35. 35.
    J. Dong, J. Wu, J. Jia, L. Fan, J. Lin, J. Colloid Interface Sci. 498, 217–222 (2017)CrossRefGoogle Scholar
  36. 36.
    M. Wang, Q. Tang, P. Xu, B. He, L. Lin, H. Chen, Electrochim. Acta 137, 175–182 (2014)CrossRefGoogle Scholar
  37. 37.
    X. Liang, H.W. Zheng, X.J. Li et al., Ceram. Int. 42(11), 12888–12893 (2016)CrossRefGoogle Scholar
  38. 38.
    N.A.M. Barakat, M. Shaheer Akhtar, A. Yousef, M. El-Newehy, H.Y. Kim, Chem. Eng. J. 211(Suppl C), 9–15 (2012)CrossRefGoogle Scholar
  39. 39.
    D.H. Yoon, S.H. Yoon, K.-S. Ryu, Y.J. Park, Sci. Rep. 6, 19962 (2016)CrossRefGoogle Scholar
  40. 40.
    I. Juhász Junger, D. Wehlage, R. Böttjer et al., Materials 11(9), 1604 (2018)CrossRefGoogle Scholar
  41. 41.
    A. Vasanth, C.O. Sreekala, K.S. Sreelatha, I. Jinchu. Micro contact printed PEDOT: PSS as cathode in dye sensitized solar cells. in 2017 International Conference on Technological Advancements in Power and Energy (TAP Energy), 21 Dec 2017Google Scholar

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Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of ScienceUniversiti Putra MalaysiaSerdangMalaysia
  2. 2.Functional Devices Laboratory, Institute of Advanced TechnologyUniversiti Putra MalaysiaSerdangMalaysia

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