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Effect of different pretreatment methods on sesame husk-based activated carbon for supercapacitors with aqueous and organic electrolytes

  • Xiaoxiao Qu
  • Yuhao Liu
  • Chuanxiang ZhangEmail author
  • Ahui Zhu
  • Tao Wang
  • Ye Tian
  • Jia Yu
  • Baolin Xing
  • Guangxu Huang
  • Yijun Cao
Article
  • 7 Downloads

Abstract

Sesame husks have been explored as a novel precursor to prepare high-performance activated carbons through two pretreatment processes coupled with KOH activation. The optimal structure of as-prepared carbon, which consisted of numerous micropores, well-defined mesopores, high specific surface of 2772 m2/g and large total pore volume of 1.206 cm3/g, is obtained via pre-carbonization and KOH activation. When applied in supercapacitors, the as-prepared carbon-based electrode achieves high specific capacitance of 301 F/g and 155 F/g in 6 M KOH aqueous electrolyte and 1 M Et4NBF4/PC organic electrolyte, respectively. Moreover, it also shows superior cycling stability of 94.9% and 92.5% capacitance retention after 10,000 cycles in KOH and Et4NBF4/PC electrolyte. Hence, this work makes the sesame husks act as a novel carbonaceous precursor and makes the pre-carbonization combined with KOH activation as an effective method for electrode materials in supercapacitor applications.

Notes

Acknowledgements

This work is financially supported by the National Natural Science Foundation of China (Grant Nos. 51404098, U1361119), International Science and Technology Cooperation Program of Henan (Grant No. 152102410047), Key Program of Science and Technology of the Education Department of Henan Province (Grant No. 14A440014), Natural Science Foundation of Henan (162300410115), Program for Innovative Research Team (in Science and Technology) in the University of Henan Province (Grant No. 16IRTSTHN005).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Xiaoxiao Qu
    • 1
    • 2
    • 3
  • Yuhao Liu
    • 1
  • Chuanxiang Zhang
    • 1
    • 2
    • 3
    Email author
  • Ahui Zhu
    • 1
  • Tao Wang
    • 1
  • Ye Tian
    • 1
  • Jia Yu
    • 4
  • Baolin Xing
    • 1
  • Guangxu Huang
    • 1
  • Yijun Cao
    • 5
  1. 1.College of Chemistry and Chemical EngineeringHenan Polytechnic UniversityJiaozuoChina
  2. 2.Coal Production Safety Collaborative Innovation Center in Henan ProvinceJiaozuoChina
  3. 3.Henan Key Laboratory of Coal Green ConversionJiaozuoChina
  4. 4.Hami Vocational &Technical CollegeHamiChina
  5. 5.Henan Province Industrial Technology Research Institute of Resources and MaterialsZhengzhou UniversityZhengzhouChina

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