Advertisement

Effect of partial substitution of Mn by Fe on the structure, magnetic phase transition and magnetocaloric response in La0.67Pb0.33Mn1−xFexO3 compounds

  • Li-an HanEmail author
  • Hui Qiao
  • Feng Gao
  • Huaze Zhu
  • Jing Yang
  • Tao Zhang
Article
  • 7 Downloads

Abstract

The compounds La0.67Pb0.33Mn1−xFexO3 (0 ≤ x ≤ 0.10) have been fabricated by ceramic procedures mainly to investigate their structure, magnetic phase transition and magnetocaloric effect. All samples have a rhombohedral structure belonging to \(R\overline {3} C\) space group by structural analysis. As the Fe concentration x increases up to 0.10, Curie temperature value significantly decreases from 360 to 210 K. The maximum values of MEC (magnetic entropy change) are found to be 4.17, 2.99, 2.58 J kg−1 K−1 under 5 T field change for x = 0, 0.05, 0.10, respectively. The corresponding values of RCP (relative cooling power) are 229.8, 235.4, 216.5 J kg−1. The relatively large MEC, high RCP values and the convenient adjustment of the TC suggest that the prepared La0.67Pb0.33Mn1−xFexO3 compounds could be appropriate materials for magnetic cooling in a wide working temperature range. The analysis of isothermal magnetization using the Arrott curves and Franco’s universal method reveals that the La0.67Pb0.33Mn1−xFexO3 manganites show a second-order ferromagnetic–paramagnetic transition.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 11605133, 61201088), and Foundation Industrial Public Relation Project of Shaanxi Technology Committee (2016GY-041).

References

  1. 1.
    A.-M. Haghiri-Gosnet, J.-P. Renard, CMR manganites: physics, thin films and devices. J. Phys. D 36, R127–R150 (2003)CrossRefGoogle Scholar
  2. 2.
    C.N.R. Rao, R. Raveau, Colossal Magnetoresistance, Charge Ordering and Related Properties of Manganese Oxides (World Scientific, Singapore, 1998)CrossRefGoogle Scholar
  3. 3.
    E. Dagotto, T. Hotta, A. Moreo, Collossal magnetoresistant materials: the key role of phase separation. Phys. Rep. 344, 1–153 (2001)CrossRefGoogle Scholar
  4. 4.
    C. Zener, Interaction between the d-shells in the transition metals. II. Ferromagnetic compounds of manganese with perovskite structure. Phys. Rev. 82, 403–405 (1951)CrossRefGoogle Scholar
  5. 5.
    J.A. Millis, B.P. Littlewood, I.B. Shraiman, Double exchange alone does not explain the resistivity of La1−xSrxMnO3. Phys. Rev. Lett. 74, 5144–5147 (1995)CrossRefGoogle Scholar
  6. 6.
    A. Moreo, S. Yunoki, E. Dagotto, Phase separation scenario for manganese oxides and related materials. Science 283, 2034–2040 (1999)CrossRefGoogle Scholar
  7. 7.
    J. Mira, J. Rivas, L.E. Hueso, F. Rivadulla, M.A. Lopez Quintela, Drop of magnetocaloric effect related to the change from first- to second-order magnetic phase transition in La2/3(Ca1−xSrx)2/3MnO3. J. Appl. Phys. 91, 8903–8905 (2002)CrossRefGoogle Scholar
  8. 8.
    M.H. Phan, S.C. Yu, Review of the magnetocaloric effect in manganite materials. J. Magn. Magn. Mater. 308, 325–340 (2007)CrossRefGoogle Scholar
  9. 9.
    J.Y. Fan, L.S. Ling, B. Hong, L. Pi, Y.H. Zhang, Magnetocaloric effect in perovskite manganite Nd0.6La0.1Sr0.3MnO3. J. Magn. Magn. Mater. 321, 2838–2841 (2009)CrossRefGoogle Scholar
  10. 10.
    L. Chen, J. Fan, W. Tong, D. Hu, L. Zhang, L. Ling, L. Pi, Y. Zhang, H. Yang, Short-range antiferromagnetic correlations and large magnetic entropy change in (La0.5Pr0.5)0.67Ca0.33MnO3. J. Mater. Sci. 53, 323–332 (2018)CrossRefGoogle Scholar
  11. 11.
    N. Zaidi, S. Mnefgui, A. Dhahri, J. Dhahri, E.K. Hlil, The effect of Dy doped on structural, magnetic and magnetocaloric properties of La0.67−xDyxPb0.33MnO3 (x = 0.00, 0.15 and 0.20) compounds. Physica B 450, 155–161 (2014)CrossRefGoogle Scholar
  12. 12.
    N. Chau, H.N. Nhat, N.H. Luong, D.L. Minh, N.D. Tho, N. N. Chau, Structure, magnetic, magnetocaloric and magnetoresistance properties of La1−xPbxMnO3 perovskite. Physica B 327, 270–278 (2003)CrossRefGoogle Scholar
  13. 13.
    N. Zaidi, S. Mnefgui, A. Dhahri, E.K. Hlil, J. Dhahri, Critical parameters near the phase transition temperature in La0.67–xDyxPb0.33MnO3. J. Rare Earth. 33, 168–176 (2015)CrossRefGoogle Scholar
  14. 14.
    S.L. Young, Y.C. Chen, H.Z. Chen, L. Horng, J.F. Hsueh, Effect of the substitutions of Ni3+, Co3+, and Fe3+ for Mn3+ on the ferromagnetic states of the La0.7Pb0.3MnO3 manganite. J. Appl. Phys. 91, 8915–8917 (2002)CrossRefGoogle Scholar
  15. 15.
    J. Gutiérrez, J.M. Barandiarán, M. Insausti, L. Lezama, M. Pena, J.J. Blanco, T. Rojo, Magnetic and transport properties of Pb perovskites and Fe containing giant magnetoresistance perovskites. J. Appl. Phys. 83, 7171–7173 (1998)CrossRefGoogle Scholar
  16. 16.
    A. Dhahri, J. Dhahri, E.K. Hlil, E. Dhahri, Effect of Ti-substitution on magnetic and magnetocaloric properties of La0.57Nd0.1Pb0.33MnO3. J. Alloys Compd. 530, 1–5 (2012)CrossRefGoogle Scholar
  17. 17.
    R.A. Young, D.B. Wiles, Profile shape functions in Rietveld refinements. J. Appl. Cryst. 15, 430–438 (1982)CrossRefGoogle Scholar
  18. 18.
    N. Zaidi, S. Mnefgui, A. Dhahri, J. Dhahri, E.K. Hlil, Study of electrical transport and magnetoresistive properties of La0.67−xDyxPb0.33MnO3 (x = 0.00, 0.10 and 0.15). J. Alloys Compd. 616, 378–384 (2014)CrossRefGoogle Scholar
  19. 19.
    G.F. Wang, Z.R. Zhao, H.L. Li, X.F. Zhang, Magnetocaloric effect and critical behavior in Fe-doped La0.67Sr0.33Mn1−xFexO3 manganites. Ceram. Int. 42, 18196–18203 (2016)CrossRefGoogle Scholar
  20. 20.
    Z. Yu, X. Zhu, S. Li, Structure, magnetic, electrical transport and magnetoresistance properties of La0.67Sr0.33Mn1−xFexO3 (x = 0–0.15) doped manganite coatings. Ceram. Int. 43, 3679–3687 (2017)CrossRefGoogle Scholar
  21. 21.
    J.M. De Teresa, M.R. Ibarra, P.A. Algarabel, C. Ritter, C. Marquina, J. Balasco, J. Garcia, A. del Moral, Z. Arnold, Evidence for magnetic polarons in the magnetoresistive perovskites. Nature 386, 256–259 (1997)CrossRefGoogle Scholar
  22. 22.
    H. Terashita, J.J. Neumeier, Bulk magnetic properties of La1−xCaxMnO3 (0 ≤ x ≤ 0.14): signatures of local ferromagnetic order. Phys. Rev. B 71, 134402 (2005)CrossRefGoogle Scholar
  23. 23.
    I. Hussain, M.S. Anwar, J.W. Kim, K.C. Chung, B.H. Koo, Influence of La addition on the structural, magnetic and magnetocaloric properties in Sr2−2xLaxFeMnO6 (0 ≤ x ≤ 0.3) double perovskite. Ceram. Int. 42, 13098–13103 (2016)CrossRefGoogle Scholar
  24. 24.
    K. Snini, F. Ben Jemaa, M. Ellouze, E.K. Hlil, Structural, magnetic and magnetocaloric investigations in Pr0.67Ba0.22Sr0.11Mn1–xFexO3 (0 ≤ x ≤0.15) manganite oxide. J. Alloys Compd. 739, 948–954 (2018)CrossRefGoogle Scholar
  25. 25.
    B.C. Zhao, Y.P. Sun, X.B. Zhu, W.H. Song, Magnetic and magnetocaloric properties of Cu-substituted La1−xPbxMnO3 (x ~ 0.14) single crystals. J. Appl. Phys. 101, 053920 (2007)CrossRefGoogle Scholar
  26. 26.
    A.M. Tishin, Y.I. Spichkin, Recent progress in magnetocaloric effect: mechanism and potential applications. Int. J. Refrig. 37, 223–229 (2014)CrossRefGoogle Scholar
  27. 27.
    W. Zhong, C.T. Au, Y.W. Du, Review of magnetocaloric effect in perovskite-type oxides. Chin. Phys. B 22, 057501 (2013)CrossRefGoogle Scholar
  28. 28.
    Z.M. Wang, Q.Y. Xu, H. Zhang, Magnetocaloric effect at room temperature in manganese perovskite La0.65Nd0.05Pb0.3MnO3 with double resistivity peaks. J. Magn. Magn. Mater. 323, 3229–3233 (2011)CrossRefGoogle Scholar
  29. 29.
    A. Tozri, E. Dhahri, E.K. Hlil, Magnetic transition and magnetic entropy changes of La0.8Pb0.1MnO3 and La0.8Pb0.1Na0.1MnO3. Mater. Lett. 64, 2138–2141 (2010)CrossRefGoogle Scholar
  30. 30.
    S.K. Çetin, M. Acet, M. Güneş, A. Ekicibil, M. Farle, Magnetocaloric effect in (La1−xSmx)0.67Pb0.33MnO3 (0 ≤ x ≤ 0.3) manganites near room temperature. J. Alloys Compd. 650, 285–294 (2015)CrossRefGoogle Scholar
  31. 31.
    A. Ben Hassine, A. Dhahri, M.-L. Bouazizi, M. Oumezzine, E.K. Hlil, Effect of trivalent rare earth doping on magnetic and magnetocaloric properties of La0.47(Y, Eu)0.2Pb0.33MnO3 manganites. Ceram. Int. 43, 1390–1393 (2017)CrossRefGoogle Scholar
  32. 32.
    K. Çetin, M. Acet, A. Ekicibil, Effect of Pr-substitution on the structural, magnetic and magnetocaloric properties of (La1−xPrx)0.67Pb0.33MnO3 (0 ≤ x ≤ 0.3) manganites. J. Alloys Compd. 727, 1253–1262 (2017)CrossRefGoogle Scholar
  33. 33.
    T.A. Ho, T.L. Phan, P.D. Thang, S.C. Yu, Influence of Pb doping on the magnetocaloric effect and critical behavior of (La0.9Dy0.1)0.8Pb0.2MnO3. J. Electron. Mater. 45, 2328–2333 (2016)CrossRefGoogle Scholar
  34. 34.
    Meenakshi, A. Kumar, R.N. Mahato, Effect of Fe substitution on structural, magnetic and magnetocaloric properties of nanocrystalline La0.7Te0.3Mn1–xFexO3 (x = 0.1, 0. Physica B 511(3), 83–88 (2017)CrossRefGoogle Scholar
  35. 35.
    F. Ben Jemaa, S. Mahmood, M. Ellouze, E.K. Hlil, F. Halouani, I. Bsoul, M. Awawdeh, Structural, magnetic and magnetocaloric properties of La0.67Ba0.22Sr0.11Mn1–xFexO3 nanopowders. Solid State Sci. 37, 121–130 (2014)CrossRefGoogle Scholar
  36. 36.
    S.K. Barik, C. Krishnamoorthi, R. Mahendiran, Effect of Fe substitution on magnetocaloric effect in La0.7Sr0.3Mn1–xFexO3 (0.05 ≤ x ≤ 0.20). J. Magn. Magn. Mater. 323, 1015–1021 (2011)CrossRefGoogle Scholar
  37. 37.
    K.A. Gschneidner Jr., V.K. Pecharsky, A.O. Tsokol, Recent developments in magnetocaloric materials. Rep. Prog. Phys. 68, 1479–1539 (2005)CrossRefGoogle Scholar
  38. 38.
    B.K. Banerjee, On a generalized approach to first and second order magnetic transitions. Phys. Lett. 12, 16–17 (1964)CrossRefGoogle Scholar
  39. 39.
    C.M. Bonilla, J. Herrero-Albillos, F. Bartolomé, L.M. García, M. Parra-Borderías, V. Franco, Universal behavior for magnetic entropy change in magnetocaloric materials: an analysis on the nature of phase transitions. Phys. Rev. B 81, 224424–224431 (2010)CrossRefGoogle Scholar
  40. 40.
    V. Franco, J.S. Blázquez, J.J. Ipus, J.Y. Law, L.M. Moreno-Ramírez, A. Conde, Magnetocaloric effect: from materials research to refrigeration devices. Prog. Mater Sci. 93, 112–232 (2018)CrossRefGoogle Scholar
  41. 41.
    X.D. Si, Y.S. Liu, X.X. Ma, J. Lin, J. Yang, T. Zhou, The analysis of magnetic entropy change and long-range ferromagnetic order in Mn1−xAgxCoGe. J. Mater. Sci. 54, 3196–3210 (2018)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Li-an Han
    • 1
    Email author
  • Hui Qiao
    • 1
  • Feng Gao
    • 1
  • Huaze Zhu
    • 1
  • Jing Yang
    • 1
  • Tao Zhang
    • 1
  1. 1.Department of Applied PhysicsXi’an University of Science and TechnologyXi’anChina

Personalised recommendations