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Low-cost Schiff bases chromophores as efficient co-sensitizers for MH-13 in dye-sensitized solar cells

  • M. Abdel-ShakourEmail author
  • Waleed A. El-SaidEmail author
  • Islam M. Abdellah
  • Rui Su
  • Ahmed El-Shafei
Article
  • 49 Downloads

Abstract

Herein, we reported on the synthesis of four Schiff bases (S1–4) based on salicylaldehyde moieties and their applications as metal-free organic chromophores for sensitization and co-sensitization of dye-sensitized solar cells (DSSCs). These sensitizers are comprised of a phenyl ring as a donor scaffold connected with a carboxylic group as acceptor/anchoring unit. To gauge their applicability as photosensitizers for DSSCs the photophysical, electrochemical, theoretical studies and charge transport characteristics were carried out. Interestingly, uses of S2 and S4 dyes as co-sensitizers with well-known MH-13 dye resulted in enhancing its photovoltaic properties from 8.217 to 8.79% and 8.48%, respectively. Furthermore, the photo-sensitizer S3 individually shows better photovoltaic properties compared to S1, S2 and S4, due to the fast photo-induced electron transfer from the phenyl ring to the nitro group. This fast electron transfer resulted from the overlapping between HOMO and LUMO levels on phenyl ring bearing nitro group. The results indicate that these simple and easy prepared Schiff bases moieties may be considered as promising and low-cost co-sensitizers for DSSCs.

Notes

Acknowledgements

The authors of this manuscript would like to thank science and technology development fund (STDF), Egypt (http://www.stdf.org.eg/index.php/en/) for the financial support of this scientific research work through Short–Term Fellowship (STF) project. Also, my sincere thanks to Prof. Dr. Ahmed Elshafei (College of textiles, North Carolina State University, USA) for his acceptance to perform a part of this work in his lab.

Compliance with ethical standards

Conflict of interest

The authors declared no conflict of interests.

Supplementary material

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Supplementary material 1 (DOCX 4276 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Chemistry Department, Faculty of ScienceAssiut UniversityAssiutEgypt
  2. 2.Polymer and Color Chemistry ProgramNorth Carolina State UniversityRaleighUSA
  3. 3.Chemistry Department, Faculty of ScienceUniversity of JeddahJeddahSaudi Arabia

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