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Journal of Materials Science: Materials in Electronics

, Volume 29, Issue 21, pp 18674–18683 | Cite as

Fluorine and oxygen co-doped porous carbons derived from third-class red dates for high-performance symmetrical supercapacitors

  • Chang Peng
  • Tianqin Zeng
  • Yong Yu
  • Zefan Li
  • Zeyuan Kuai
  • Wenkui Zhao
Article
  • 31 Downloads

Abstract

Recently, the incorporation of foreign atoms (e.g. nitrogen, phosphorus, fluorine, and oxygen, etc.) into the carbocycle has been demonstrated to be very promising for enhancing the electrochemical property of carbon-based supercapacitor. Herein, for the first time, fluorine and oxygen co-doped porous carbons (FOPCs) were successfully prepared by employing third-class red dates as precursor, which showed high specific surface area (1229 m2 g−1), highly-developed micropores (~ 93%), rich oxygen-content (22.8 wt%) and moderate fluorine doping (1.0 wt%). Owing to the aforementioned advantages, the resultant FOPC-800 electrode displayed high specific capacities of 261 and 168 F g−1 at 1 and 20 A g−1 respectively, in 6 M KOH electrolyte. Moreover, high energy density (23.2 W h kg−1) of the FOPC-800-based symmetric supercapacitor was achieved in 1 M Na2SO4 electrolyte, with outstanding cyclic stability (93.5% retention after 5000 cycles).

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21606081).

Compliance with ethical standards

Conflict of interest

The authors declare no conflict of interest.

Supplementary material

10854_2018_9990_MOESM1_ESM.docx (249 kb)
Supplementary material 1 (DOCX 248 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of ScienceHunan Agricultural UniversityChangshaPeople’s Republic of China

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