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Journal of Materials Science: Materials in Electronics

, Volume 29, Issue 21, pp 18074–18081 | Cite as

Enhanced performance of 4,4′-bipyridine-doped PVDF/KI/I2 based solid state polymer electrolyte for dye-sensitized solar cell applications

  • Kannadhasan Sundaramoorthy
  • Senthil Pandian Muthu
  • Ramasamy Perumalsamy
Article
  • 81 Downloads

Abstract

Pure (PVDF/KI/I2) and 4,4′-bipyridine-doped PVDF/KI/I2 solid state polymer electrolytes were prepared by solution casting method using N,N-dimethylformamide (DMF) as solvent. The solid state polymer electrolytes were characterized by the powder X-ray diffraction (PXRD), Fourier transform infrared (FTIR), AC-impedance, dielectric measurements and scanning electron microscopy (SEM) analysis. The crystallinity of the solid state polymer electrolytes was analyzed by PXRD measurement. The functional groups of the solid state polymer electrolytes were confirmed by FTIR analysis. The AC-impedance analysis was carried out to calculate the ionic conductivity of the solid state polymer electrolytes. The ionic conductivity value of pure (PVDF/KI/I2) and 4,4′-bipyridine-doped PVDF/KI/I2 solid state polymer electrolytes are 2.00 × 10−6 S cm−1 and 4.60 × 10−5 S cm−1, respectively. The dielectric properties of solid state polymer electrolytes were calculated by using the dielectric measurements. From the SEM analysis, the surface morphology of the solid state polymer electrolytes was analyzed. The power conversion efficiencies of pure (PVDF/KI/I2) and 4,4′-bipyridine-doped PVDF/KI/I2 solid state polymer electrolytes are 1.8% and 4.4%, respectively. 4,4′-bipyridine-doped PVDF/KI/I2 solid state polymer electrolyte has higher power conversion efficiency due to its increased amorphous nature and ionic mobility.

Notes

Acknowledgements

The authors gratefully acknowledge the financial support received from UGC-DAE CSR, Indore (Sanction Order No. CSR-KN/CRS-66/2014-15/506). We gratefully acknowledge the financial support received from Department of Science and Technology (DST-SERI) New Delhi, the Grant Number DST (SERI) DST/TM/SERI/2k12/40(G).

References

  1. 1.
    J. Wu, Z. Lan, J. Lin, M. Huang, Y. Huang, L. Fan, G. Luo, Electrolytes in dye-sensitized solar cells. Chem. Rev. 115, 2136–2173 (2015)CrossRefGoogle Scholar
  2. 2.
    O. Dayan, N. Ozdemir, F. Yakuphanoglu, Z. Serbetci, A. Bilici, B. Cetinkaya, M. Tercan, Synthesis and photovoltaic properties of new Ru(II) complexes for dye-sensitized solar cells. J. Mater. Sci.-Mater. Electron. 29, 11045 (2018)CrossRefGoogle Scholar
  3. 3.
    T.Y. Chen, Y.J. Huang, C.T. Li, C.W. Kung, R. Vittal, K.C. Ho, Metal-organic framework/sulfonated polythiophene on carbon cloth as a flexible counter electrode for dye-sensitized solar cells. Nano Energy 32, 19–27 (2017)CrossRefGoogle Scholar
  4. 4.
    Y. Yu, H. Zheng, X. Zhang, X. Liang, G. Yue, F. Li, M. Zhu, T. Li, J. Tian, G. Yin, An efficient dye-sensitized solar cell with a promising material of Bi4Ti3O12 nanofibers/graphene. Electrochim. Acta 215, 543–549 (2016)CrossRefGoogle Scholar
  5. 5.
    S. Venkatesan, I.P. Liu, J.C. Lin, M.H. Tsai, H. Teng, Y.L. Lee, Highly efficient quasi-solid-state dye-sensitized solar cell using polyethylene oxide (PEO) and poly(methyl methacrylate) (PMMA)-based printable electrolytes. J. Mater. Chem. A 6, 10085 (2018)CrossRefGoogle Scholar
  6. 6.
    X. Liang, H.W. Zheng, X.J. Li, Y.H. Yu, G.T. Yue, W. Zhang, J.J. Tian, T.F. Li, Nanocomposites of Bi5FeTi3O15 with MoS2 as novel Pt-free counter electrode in dye-sensitized solar cells. Ceram. Int. 42, 12888–12893 (2016)CrossRefGoogle Scholar
  7. 7.
    B. O’Regan, M. Gratzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353, 737–740 (1991)CrossRefGoogle Scholar
  8. 8.
    S. Yun, P.D. Lund, A. Hinsch, Stability assessment of alternative platinum free counter electrodes for dye-sensitized solar cells. Energy Environ. Sci. 8, 3495–3514 (2015)CrossRefGoogle Scholar
  9. 9.
    M.M. Noor, M.H. Buraidah, M.A. Careem, S.R. Majid, A.K. Arof, An optimized poly (vinylidene fluoride-hexafluoropropylene)-NaI gel polymer electrolyte and its application in natural dye-sensitized solar cells. Electrochim. Acta 121, 159–167 (2014)CrossRefGoogle Scholar
  10. 10.
    K.K. Kumar, M. Ravi, Y. Pavani, S. Bhavan, A.K. Sharma, V.V.R. Narasimha, Rao, Investigations on PEO/PVP/NaBr complexed polymer blend electrolytes for electrochemical cell applications. J. Membr. Sci. 454, 200–211 (2014)CrossRefGoogle Scholar
  11. 11.
    S. Ramesh, S.C. Lu, Effect of lithium salt concentration on crystallinity of poly (vinylidene fluoride-co-hexafluoropropylene)-based solid polymer electrolytes. J. Mol. Struct. 994, 403–409 (2011)CrossRefGoogle Scholar
  12. 12.
    T.M.W.J. Bandara, M.A.K.L. Dissanayake, B.E. Mellander, Dye-sensitized solar cells with poly (acrylonitrile) based plasticized electrolyte containing MgI2. Electrochim. Acta 55, 2044–2047 (2010)CrossRefGoogle Scholar
  13. 13.
    R.A. Senthil, J. Theerthagiri, J. Madhavan, A.K. Arof, Dye-sensitized solar cell using 4-chloro-7-nitrobenzofurazan incorporated polyvinyl alcohol polymer electrolyte. Indian J. Phys. 90, 1265–1270 (2016)CrossRefGoogle Scholar
  14. 14.
    B. Muthuraaman, S. Ganesan, B. Joseph Paul, P. Maruthamuthu, S.A. Suthanthiraraj, Studies on isomeric effects of 2- and 4-Mercapto pyridine as dopants in polymer electrolyte in dye-sensitized solar cells. Electrochim. Acta 56, 5405–5409 (2011)CrossRefGoogle Scholar
  15. 15.
    R.A. Senthil, J. Theerthagiri, J. Madhavan, Optimization of performance characteristics of 2-mercaptopyridine-doped polyvinylidene fluoride (PVDF) polymer electrolytes for dye-sensitized solar cells. J. Non-Cryst. Solids 406, 133–138 (2014)CrossRefGoogle Scholar
  16. 16.
    J. Theerthagiri, R.A. Senthil, M.H.A. Buraidah, J. Madhavan, A.K. Arof, Effect of tetrabutylammonium iodide content on PVDF-PMMA polymer blend electrolytes for dye-sensitized solar cells. Ionics 21, 2889–2896 (2015)CrossRefGoogle Scholar
  17. 17.
    R.A. Senthil, J. Theerthagiri, J. Madhavan, Hematite Fe2O3 nanoparticles incorporated polyvinyl alcohol based polymer electrolytes for dye-sensitized solar cells. Mater. Sci. Forum 832, 72–83 (2015)CrossRefGoogle Scholar
  18. 18.
    R.A. Senthil, J. Theerthagiri, J. Madhavan, A.K. Arof, Enhanced performance of dye-sensitized solar cell using 2-mercaptobenzothiazole-doped poly (vinylidinefluoride-co-hexafluoropropylene) polymer electrolyte. Ionics 22, 1225–1230 (2016)CrossRefGoogle Scholar
  19. 19.
    R.A. Senthil, J. Theerthagiri, J. Madhavan, A.K. Arof, Influence of pyrazole on the photovoltaic performance of dye-sensitized solar cell with polyvinylidene fluoride polymer electrolytes. Ionics 22, 425–433 (2016)CrossRefGoogle Scholar
  20. 20.
    S. Ganesan, V. Mathew, B. Joseph Paul, P. Maruthamuthu, S. Austin Suthanthiraraj, Influence of organic nitrogenous compounds phenothiazine and diphenyl amine in poly (vinylidene fluoride) blended with poly (ethylene oxide) polymer electrolyte in dye-sensitized solar cells. Electrochim. Acta 102, 219–224 (2013)CrossRefGoogle Scholar
  21. 21.
    B. Muthuraaman, G. Will, H. Wang, P. Moonie, J. Bell, Increased charge transfer of poly (ethylene oxide) based electrolyte by addition of small molecule and its application in dye-sensitized solar cells. Electrochim. Acta 87, 526–531 (2013)CrossRefGoogle Scholar
  22. 22.
    R.A. Senthil, J. Theerthagiri, J. Madhavan, A.K. Arof, High performance dye-sensitized solar cell based on 2-mercaptobenzimidazole doped poly(vinylidinefluoride-co-hexafluoropropylene) based polymer electrolyte. J. Macromol. Sci. Pure Appl. Chem. 53, 245–251 (2016)CrossRefGoogle Scholar
  23. 23.
    R. Govindraj, M. Magesh, M. Senthil Pandian, P. Ramasamy, S. Mukhopadhyay, Nanorods and nanoparticles of titanium dioxide and their use in dye-sensitized solar cells. AIP Conf. Proc. 1731, 050111-1–050111-3 (2016)Google Scholar
  24. 24.
    P. Singh, H. Borkar, B.P. Singh, V.N. Singh, A. Kumar, Ferroelectric polymer-ceramic composite thick films for energy storage applications. AIP Adv. 4(8), 087117 (2014)CrossRefGoogle Scholar
  25. 25.
    N.A. Hoque, P. Thakur, N. Bala, A. Kool, S. Das, P.P. Ray, Tunable photoluminescence emissions and large dielectric constant of the electroactive poly (vinylidene fluoride–hexafluoropropylene) thin films modified with SnO2 nanoparticles. RSC Adv. 6(36), 29931–29943 (2016)CrossRefGoogle Scholar
  26. 26.
    X. Cai, T. Lei, D. Sun, L. Lin, A critical analysis of the α, β and γ phases in poly (vinylidene fluoride) using FTIR. RSC Adv. 7(25), 15382–15389 (2017)CrossRefGoogle Scholar
  27. 27.
    R.A. Senthil, J. Theerthagiri, J. Madhavan, A.K. Arof, Performance characteristics of guanine incorporated PVDF-HFP/PEO polymer blend electrolytes with binary iodide salts for dye-sensitized solar cells. Opt. Mater. 58, 357–364 (2016)CrossRefGoogle Scholar
  28. 28.
    S. Ramesh, C.W. Liew, A.K. Arof, Ion conducting corn starch biopolymer electrolytes doped with ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. J. Non-Cryst. Solids 357(21), 3654–3660 (2011)CrossRefGoogle Scholar
  29. 29.
    N. Rajeswari, S. Selvasekarapandian, S. Karthikeyan, M. Prabu, G. Hirankumar, H. Nithya, C. Sanjeeviraja, Conductivity and dielectric properties of polyvinyl alcohol–polyvinylpyrrolidone poly blend film using non-aqueous medium. J. Non-Crys. Solids 357, 3751–3756 (2011)CrossRefGoogle Scholar
  30. 30.
    S. Ganesan, B. Muthuraaman, V. Mathew, J. Madhavan, P. Maruthamuthu, S.A. Suthanthiraraj, Performance of a new polymer electrolyte incorporated with diphenylamine in nanocrystalline dye-sensitized solar cell. Sol. Energy Mater. Sol. Cells 92, 1718–1722 (2008)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Kannadhasan Sundaramoorthy
    • 1
  • Senthil Pandian Muthu
    • 1
  • Ramasamy Perumalsamy
    • 1
  1. 1.SSN Research CentreSSN College of EngineeringChennaiIndia

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