Advertisement

Journal of Materials Science: Materials in Electronics

, Volume 29, Issue 17, pp 14495–14500 | Cite as

Influence of Eu3+ concentration on photoluminescence and structure of Ba3Y1 − zEuz(BO3)3

  • Zhiyuan Cheng
  • Yanjie Zhang
  • Jingjie Yu
  • Hongyu Ning
  • Chao Dong
  • Nianyu Zou
Article
  • 26 Downloads

Abstract

A series of Ba3Y1 − zEuz(BO3)3 has been synthesized via a conventional solid state method. XRD, SEM, FL, EDS and lifetime decay curves were utilized for characterization. XRD and SEM confirmed that the phase of samples was transited from α-Ba3Y(BO3)3 to β-Ba3Eu(BO3)3 while Eu3+ concentration (z) increased from 0.20 to 0.40. The structure distortion due to different radius of Eu3+ and Y3+ and point defects due to the exchange of Eu3+ and Ba2+ ions were responsible for phase transition. In α phase, the R/O ratio of Eu3+ increased with z because of the point defects. On the other hand, R/O ratio stayed at around 1.080 in β phase. Second-order exponential decay curve of Ba3Y0.95Eu0.05(BO3)3 was a solid evidence for point defects in α phase. Excited at 394 nm, Ba3Y1 − zEuz(BO3)3 mainly showed intensive luminescence peaks at 596 and 616 nm ascribed to electron transitions 5D07F1 and 7F2, respectively. The obtained red phosphor is a great option for displays.

Notes

Acknowledgements

This work was supported by the Natural Science Foundation of Liaoning Province (20170540074).

References

  1. 1.
    E.F. Schubert, J.K. Kim, Science 308, 1274 (2005)CrossRefGoogle Scholar
  2. 2.
    R.D. Dupuis, M.R. Krames, J. Lightwave Technol. 26, 1154 (2008)CrossRefGoogle Scholar
  3. 3.
    V.F. Guimarães, M. Salaün, P. Burner, L.J.Q. Maia, A. Ferrier, B. Viana, I. Gautier-Luneau, A. Ibanez. Solid State Sci. 65, 6 (2017)CrossRefGoogle Scholar
  4. 4.
    G.S.R. Raju, J.Y. Park, G.P. Nagaraju, E. Pavitra, H.K. Yang, B.K. Moon, J.S. Yu, Y.S. Huh, J.H. Jeong, J. Mater. Chem. C 5, 4246 (2017)CrossRefGoogle Scholar
  5. 5.
    G.S.R. Raju, L. Benton, E. Pavitra, J.S. Yu, Chem. Comm. 51, 13248 (2015)CrossRefGoogle Scholar
  6. 6.
    E. Pavitra, G.S.R. Raju, J.Y. Park, L.L. Wang, B.K. Moon, J.S. Yu, Sci. Rep-UK 5, 10296 (2015)CrossRefGoogle Scholar
  7. 7.
    X.L. Liu, W.H. Hou, X.Y. Yang, J.Y. Liang, Crystengcomm 16, 1268 (2014)CrossRefGoogle Scholar
  8. 8.
    R. Van Deun, D. Ndagsi, J. Liu, I. Van Driessche, K. Van Hecked, A.M. Kaczmarek, Dalton Trans. 44, 15022 (2015)CrossRefGoogle Scholar
  9. 9.
    B. Yuan, Y. Sheng, Y.H. Song, K.Y. Zheng, X.Q. Zhou, X.C. Xu, H.F. Zou, J. Alloy. Compd. 644, 82 (2015)CrossRefGoogle Scholar
  10. 10.
    A. Dobrowolska, E.C. Karsu, A.J.J. Bos, P. Dorenbos, J. Lumin. 160, 321 (2015)CrossRefGoogle Scholar
  11. 11.
    S.A. Mohitkar, K. Vidyasagar, J. LUMIN. 161, 180 (2015)CrossRefGoogle Scholar
  12. 12.
    L.X. Wang, M.J. Xu, H.Y. Zhao, D.Z. Jia, New J. Chem. 40, 3086 (2016)CrossRefGoogle Scholar
  13. 13.
    Y. Zhang, W.T. Gong, J.J. Yu, Z.Y. Cheng, G.L. Ning, RSC Adv. 6, 30886 (2016)CrossRefGoogle Scholar
  14. 14.
    Z.F. Yang, D.H. Xu, J.Y. Sun, J.N. Du, X.D. Gao, Mater. Sci. Eng. B 211, 13 (2016)CrossRefGoogle Scholar
  15. 15.
    X.B. Qiao, J. Xin, X.M. Nie, J. Xu, S. Qi, Z.S. Jiang, Dyes Pigments 143, 103 (2017)CrossRefGoogle Scholar
  16. 16.
    A. Durugkar, S. Tamboli, N.S. Dhoble, S.J. Dhoble, Mater. Res. Bull. 97, 466 (2018)CrossRefGoogle Scholar
  17. 17.
    G.S.R. Raju, J.Y. Park, H.C. Jung, E. Pavitra, B.K. Moon, J.H. Jeong, J.S. Yu, J.H. Kim, H. Choi, J. Alloy. Compd. 509, 7537 (2011)CrossRefGoogle Scholar
  18. 18.
    Y.Y. Bu, X.H. Yan, J. Lumin. 190, 50 (2017)CrossRefGoogle Scholar
  19. 19.
    S.K. Gupta, N. Pathak, R.M. Kadam, J. Lumin. 169, 106 (2016)CrossRefGoogle Scholar
  20. 20.
    M.D. Jong, A. Meijerink, J. Lumin. 170, 240 (2016)CrossRefGoogle Scholar
  21. 21.
    J. He, R. Shi, M.G. Brik, P. Dorenbos, Y. Huang, Y. Tao, H.B. Liang, J. Lumin. 161, 257 (2015)CrossRefGoogle Scholar
  22. 22.
    L. Zhang, C.Y. Li, Q. Su, J. Rare Earth. 24, 196 (2006)CrossRefGoogle Scholar
  23. 23.
    Z.G. Wei, L.D. Sun, C.S. Liao, X.C. Jiang, C.H. Yan, Y. Tao, X.Y. Hou, X. Ju, J. Appl. Phys. 93, 9783 (2003)CrossRefGoogle Scholar
  24. 24.
    Z.G. Xia, M.S. Molokeev, W.B. Im, S. Unithrattil, Q.L. Liu, J. Phys. Chem. C 119, 9488 (2015)CrossRefGoogle Scholar
  25. 25.
    L.Y. Zhou, J.L. Huang, L.H. Yi, M.L. Gong, J.X. Shi, J. Rare Earth. 27, 54 (2009)CrossRefGoogle Scholar
  26. 26.
    Z.Y. Cheng, J.J. Yu, Y.J. Zhang, N.Y. Zou, J. Lumin. 192, 1004 (2017)CrossRefGoogle Scholar
  27. 27.
    J.R. Cox, D.A. Keszler, J.F. Huang, Chem. Mater. 6, 2008 (1994)CrossRefGoogle Scholar
  28. 28.
    D.Y. Wang, T.M. Chen, B.M. Cheng, Inorg. Chem. 51, 2961 (2012)CrossRefGoogle Scholar
  29. 29.
    T.N. Khamaganova, N.M. Kuperman, Z.G. Bazarova, J. Solid State Chem. 145, 33 (1999)CrossRefGoogle Scholar
  30. 30.
    X.Z. Li, X.L. Chen, J.K. Jian, L. Wu, Y.P. Xu, Y.G. Cao, J. Solid State Chem. 177, 216 (2004)CrossRefGoogle Scholar
  31. 31.
    X.Z. Li, X.L. Chen, L. Wu, Y.G. Cao, T. Zhou, Y.P. Xu, J. Alloy. Compd. 370, 53 (2004)CrossRefGoogle Scholar
  32. 32.
    Q. Su, J. Lumin. 40–41, 113 (1988)CrossRefGoogle Scholar
  33. 33.
    G. Blasse, J. Solid State Chem. 62, 207 (1986)CrossRefGoogle Scholar
  34. 34.
    D.L. Dexter, J. Chem. Phys. 21, 836 (1953)CrossRefGoogle Scholar
  35. 35.
    L.G. Van Uitert, J. Electrochem. Soc. 114, 1048 (1967)CrossRefGoogle Scholar
  36. 36.
    Q. Ren, B.X. Wang, X.L. Wu, T.Y. Wei, Z.Z. Huo, J. Alloy. Compd. 684, 677 (2016)CrossRefGoogle Scholar
  37. 37.
    Z.W. Zhang, A.J. Song, Y. Yue, H. Zhong, X.Y. Zhang, M.Z. Ma, R.P. Liu, J. Alloy. Compd. 650, 410 (2015)CrossRefGoogle Scholar
  38. 38.
    J.Y. Sun, X.Y. Zhang, Z.G. Xia, H.Y. Du, Mater. Res. Bull. 46, 2179 (2011)CrossRefGoogle Scholar
  39. 39.
    S. Li, X.T. Wei, K.M. Deng, X.N. Tian, Y.G. Qin, Y.H. Chen, M. Yi, Curr. Appl. Phys. 13, 1288 (2013)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Zhiyuan Cheng
    • 1
  • Yanjie Zhang
    • 1
  • Jingjie Yu
    • 1
  • Hongyu Ning
    • 1
  • Chao Dong
    • 1
  • Nianyu Zou
    • 1
  1. 1.Research Institute of PhotonicsDalian Polytechnic UniversityDalianChina

Personalised recommendations