Synthesis, physico-chemical studies and Hirshfeld surface analysis of a first 0-D Chlorozincophosphate, (H2N(CH2)4NH(CH2)2NH3Cl)ZnCl2(HPO4)
An original zero-dimensional chloro-substituted zincophosphate monomer, (H2N(CH2)4NH(CH2)2NH3Cl)Zn(HPO4)Cl2, was isolated by the reaction of zinc chloride (Zn2+, 2Cl−) with the amine, 1-(2-aminoethyl)piperazine, H3PO4 and HCl under ambient conditions. This phase crystallizes in the triclinic space group P-1 (No. 2) with the lattice parameters a = 8.834(2), b = 8.539(3), c = 11.163(2) Å, α = 93.58(2)°, β = 108.62(2)°, γ = 62.96(2)°, V = 707.3(4) Å3, Z = 2, R = 0.027 and Rw = 0.037. The tri-protonited organic cations are linked to the isolated chloride ions Cl− through N–H⋯Cl and C–H⋯Cl hydrogen bonds, forming corrugated cationic layers extending parallel to (a b) plane. The inorganic framework of the title compound consists of a network of ZnO3Cl and HPO4 tetrahedral units linked by their oxygen vertices, forming isolated 4-membered rings. These anionic monomers, (Zn2P2O8Cl4H2)4−, which are held by O–H⋯O hydrogen-bonding interactions, lie between the cationic layers to maximize the electrostatic interactions and are linked to (H2N(CH2)4NH(CH2)2NH3Cl)2+cations via N–H⋯O or N–H⋯Cl hydrogen bonds, forming a 3-D supra molecular structure. Hirshfeld surface analysis, Solid state NMR, Infrared spectroscopies and DTA/TGA analysis were also performed to characterize the title compound. Solid state31P and13C MAS NMR spectroscopy results were found to be in full agreement with the XRD results.
- 6.K.V. Khot, S.S. Mali, R.M. Mane, P.S. Patil, C.K. Hong, J.H. Kim, J. Heo, P.N. Bhosale, J. Mater. Sci. 26, 6897–6906 (2015)Google Scholar
- 20.K. Brandenburg, Diamond Version 2.0 Impact. (GbR, Bonn, 1998)Google Scholar
- 27.D. Zhao-jun, Y. Yan, Z. Rong-fenj, L.H. Zheng-guo, Y. Ji-hong, Chem. Res. Chin.Univ. 27(4), 531–535 (2011)Google Scholar
- 29.S.K. Wolff, D.J. Grimwood, J.J. McKinnon, M.J. Turner, D. Jayatilaka, M.A. Spackman, Crystal Explorer (Version 3.1) (University of Western Australia, Perth, 2012)Google Scholar
- 38.G.L. Turner, K.A. Smith, R.J. Kirkpatrick, E.J. Oldfield, J. Magn. Reson. 70, 408 (1986)Google Scholar