Synthesis of W(3%)-doped CdS thin film by SILAR and its characterization
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Abstract
In this study, the structural, elemental, optical and photovoltaic properties of W(3%)-doped CdS thin film on a glass substrate at room temperature using the low-cost successive ionic layer adsorption and reaction (SILAR) technique were investigated. Based on the obtained -ray diffraction patterns, it was determined that the structure of W(3%)-doped CdS thin film is cubic compared with the standard data. The spectrum obtained from energy dispersive X-ray analysis revealed that the doping process is successfully carried out by the SILAR method. The band gap (Eg) of W(3%)-doped CdS thin film was observed with both optical absorption and photoluminescence measurements, which were higher than the pure CdS. Finally, the photovoltaic properties of W(3%)-doped CdS thin film grown on TiO2 coated on the fluorine doped tin oxide conductive glass by SILAR method at room temperature were examined by both current density–voltage and incident photon to current efficiency measurements. Consequently, it can be seen from the application point of view that W(3%)-doped CdS thin film can be used as a promising sensitizer in thin film sensitized solar cells.
References
- 1.F. Aftab, J. Iqbal, A. Iqbal, A. Mahmood, Q. Raza,, Effect of Cu incorporation on the physical properties of CdS thin films deposited by using the thermal evaporation technique. J. Korean Phys. Soc. 69 593–594 (2016)CrossRefGoogle Scholar
- 2.N.N. Banu, K. Ravichandran, Analysis of sulphur deficiency defect prevalent in SILAR-CdS films. J. Mater. Sci.: Mater. Electron. 28, 11584–11590 (2017)Google Scholar
- 3.T.T. Xuan, J.Q. Liu, R.J. Xie, H.L. Li, Z. Sun, Microwave-assisted synthesis of CdS/ZnS: Cu quantum dots for white light emitting diodes with high color rendition. Chem. Mater. 27, 1187–1193 (2015)CrossRefGoogle Scholar
- 4.Y. Wang, S. Ge, L. Zhang, J. Yu, m Yan, J. Huang, Visible photo electrochemical sensing platform by in situ generated CdS quantum dots decorated branched- TiO2 nanorods equipped with Prussian blue electro chromic display. Biosens. Bioelectron. 89, 859–865 (2017)CrossRefGoogle Scholar
- 5.H.S. Rao, W.Q. Wu, Y. Liu, Y.F. Xu, B.X. Chen, H.Y. chen, D.B. Kuang, C.Y. Su, CdS/CdSe co-sensitized vertically aligned anatese TiO2 nanowire arrays for efficient solar cells. Nano Energy 8, 1–8 (2014)CrossRefGoogle Scholar
- 6.H. Fu, H. Liu, W. Shen, A composite CdS thin film/TiO2 nanotube structure by ultrafast successive electrochemical deposition toward photovoltaic application. Nanoscale Res. Lett. 9, 631–644 (2014)CrossRefGoogle Scholar
- 7.M. McDaniel, N. Fuke, N.S. Makamu, J.U. Pietryga, V.I. Klimov, An integrated approach to realizing high performance liquid-junction quantum dot sensitized solar cells. Nat. Commun. 4, 2887–2897 (2013)CrossRefGoogle Scholar
- 8.K. Pitchaimani, L. Amalaraj, S. Muthukumaran, Investigation of structural, photoluminescence and antibacterial behavior of Mn-doped and Co, Mn dual doped thin films by CBD method. J. Mater. Sci.: Mater. Electron. 27, 12021–12027 (2016)Google Scholar
- 9.P. Elavarthi, A.A. Kumar, G. Murali, D.A. Reddy, K.R. Gunasekhar, Room temperature ferromagnetism ad white light emissive CdS:Cr nanoparticles synthesized by chemical co-precipitation method. J. Alloy. Compd. 656, 510–517 (2016)CrossRefGoogle Scholar
- 10.A. Nazir, A. Toma, N.A. Shah, S. Panaro, S. Butt, R.U.R. Sagar, W. Raja, K. Rasool, A. Maqsood, Effect of Ag doping on opto-electrical properties of CdS thin films for solar cell applications. J. Alloy. Compd. 609, 40–45 (2014)CrossRefGoogle Scholar
- 11.P. Roy, S.K. Srivastava, In situ deposition of Sn-doped CdS thin films by chemical bath deposition and their characterization. J. Phys. D: Appl. Phys. 39, 4771–4776 (2006)CrossRefGoogle Scholar
- 12.A. Jafari, A. Zakaria, Z. Rizwan, M.S. Ghazali, Effect of low concentration Sn doping on optical properties of CdS films grown by CBD technique. Int. J. Mol. Sci. 12, 6320–6328 (2011)CrossRefGoogle Scholar
- 13.T. Abza, F.K. Ampong, F.G. Hone, I. Nkrumah, R.K. Nkum, F. Boakye, A new route for the synthesis of CdS thin films from acidic chemical baths. Int. J. Thin Films Sci. Technol. 6, 67–71 (2017)CrossRefGoogle Scholar
- 14.B. Ullrich, H. Sokai, Y. Segawa, Optoelectronic properties of thin film CdS formed by ultraviolet and infrared pulsed-laser deposition. Thin Solid Films. 385, 220–224 (2001)CrossRefGoogle Scholar
- 15.D. Kim, Y. Park, M. Kim, Y. Choi, Y.S. Park, J. Lee, Optical and structural properties of sputtered CdS films for thin film solar cell applications. Mater. Res. Bull. 69, 78–83 (2015)CrossRefGoogle Scholar
- 16.A. Mukherjee, P. Ghosh, M. Fu, A.A. Aboud, P. Mitra, Microstructural characterization of chemical bath deposition synthesized CdS thin films: application as H2S sensor. Adv. Sci. Lett. 22, 179–183 (2016)CrossRefGoogle Scholar
- 17.Z.D. Eygi, B.D. Selcuk, V. Bilgin, Influence of Sn doping on CdS thin film grown by ultrasonic spray pyrolysis. Int. J. Thin Films Sci. Technol. 5, 103–106 (2016)CrossRefGoogle Scholar
- 18.H. Uda, H. Yonezama, Y. Ohtsubo, M. Kosaka, H. Sonomura, Thin CdS films prepared by metal organic chemical vapor deposition. Sol. Energy Mater. Sol. Cells. 75, 219–226 (2003)CrossRefGoogle Scholar
- 19.P. Boieriu, R. Sporken, Y. Xin, N.D. Browning, S. Sivananthan, Wurtize CdS on CdTe grown by molecular beam epitaxy. J. Electron. Mater. 2, 718–722 (2007)Google Scholar
- 20.R. Zhou, Q. Zhang, J. Tian, D. Myers, M. Yin, G. Gao, Influence of cationic precursors on CdS quantum-dot-sensitized solar cells prepared by successive ionic layer adsorption and reaction. J. Phys. Chem. C 117, 26948–26951 (2013)CrossRefGoogle Scholar
- 21.P. Mitra, S. Mondal, Structural and morphological characterization of ZnO thin films synthesized by SILAR. Prog. Theor. Appl. Phys. 1 (2013), 17–31Google Scholar
- 22.F.N.J. Garcia, B.S. Giraldo, E.R. Parra, G.A.L. Lopez, Synthesis of TiO2 thin films by the SILAR method and study of the influence of annealing on its structural, morphological and optical properties. Ing. -Rev. Chil. Ing. 23, 622–629 (2015)CrossRefGoogle Scholar
- 23.R.L. Morales, M.R. Falfan, O.Z. Angel, R.R. Bon, Characterization of cubic CdS thin films annealed in vacuum. J. Phys. Chem. Solids. 59, 1393–1398 (1998)CrossRefGoogle Scholar
- 24.R. R.Kulkarni, M. Molladi, M. Hanagadakar, B. Doddamani, S. Santhakumari, Kulkarni, Ru-TiO2 semiconducting nanoparticles for the photo-catalytic degradation of bromothymol blue. J. Mater. Sci.: Mater. Electron. 27, 13065–13074 (2016)Google Scholar
- 25.L. Brus, Electronic wave functions in semiconductor clusters experiment and theory. J. Phys. Chem. 90, 2555–2560 (1986)CrossRefGoogle Scholar
- 26.S. Horoz, O. Sahin, Synthesis, characterizations and photovoltaic properties of Cr-doped CdS QDs. J. Mater. Sci.: Mater. Electron. 28, 17784–17790 (2017)Google Scholar
- 27.B. Ullrich, D.M. Bagnall, H. Sokai, Y. Segawa, Photoluminescence properties of thin CdS films on glass formed by laser ablation. Solid State Commun. 109, 757–760 (1999)CrossRefGoogle Scholar