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Composition induced structural transition and improved magnetic behavior in La substituted BiFeO3 compound

  • Deepika Tripathi
  • Shreeja Pillai
  • Vilas Shelke
Article
  • 21 Downloads

Abstract

We present a detailed study on the structural, electronic, magnetic and dielectric properties of La substituted multiferroic bismuth ferrite. Polycrystalline Bi1 − xLaxFeO3 (0.1 ≤ x ≤ 0.3) samples were prepared by conventional solid state reaction method. The Rietveld refinement of x-ray diffraction data and Raman spectroscopy study showed clear indication of emergence of orthorhombic phase. Significant improvement in magnetic properties has been observed owing to the rhombohedral (R3c) to orthorhombic (Pnma) structural transition for 30 mol% La substituted sample. The x-ray photoelectron spectroscopy study confirmed the absence of mixed valency or detectable vacancies. Therefore, the increase in magnetization is the attribute of structural variance. The dielectric behavior showed initial increase in permittivity with La substitution but further decrease with structural change.

Notes

Acknowledgements

The financial support by the Department of Atomic Energy Board of Research in Nuclear Sciences (BRNS), Department of Science and Technology (DST) and Council of Scientific and Industrial Research (CSIR) to VS, DT, SP respectively is gratefully acknowledged. The authors are thankful to Dr Alok Banerjee, Dr. Mukul Gupta, Dr. Vasant Sathe, Dr. Deshpande and Dr Awasthi of UGC-DAE Consortium for Scientific Research, Indore for providing characterization facilities.

References

  1. 1.
    B. Keimer, J. Maier, J. Mannhart, Nat. Mater. 11, 751 (2012)CrossRefGoogle Scholar
  2. 2.
    J.F. Scott, J. Mater. Chem. 22, 4567 (2012)CrossRefGoogle Scholar
  3. 3.
    S.W. Cheong, M. Mostovoy, Nat. Mater. 6, 13 (2007)CrossRefGoogle Scholar
  4. 4.
    G. Catalan, J.F. Scott, Adv. Mater. 21, 2463 (2009)CrossRefGoogle Scholar
  5. 5.
    J. Wang, J.B. Neaton, H. Zheng, V. Nagarajan, S.B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D.G. Schlom, U.V. Waghmare, N.A. Spaldin, K.M. Rabe, M. Wuttig, R. Ramesh, Science 299, 1719 (2003)CrossRefGoogle Scholar
  6. 6.
    T. Choi, S. Lee, Y.J. Choi, V. Kiryukhin, S.W. Cheong, Science 324, 63 (2009)CrossRefGoogle Scholar
  7. 7.
    J.B. Neaton, C. Ederer, U.V. Waghmare, N.A. Spaldin, K.M. Rabe, Phys. Rev. B 71, 014113 (2005)CrossRefGoogle Scholar
  8. 8.
    C. Ederer, N.A. Spaldin, Phys. Rev. B 71, 060401R (2005)CrossRefGoogle Scholar
  9. 9.
    V. Shelke, V.N. Harshan, S. Kotru, A. Gupta, J. Appl. Phys. 106, 104114 (2009)CrossRefGoogle Scholar
  10. 10.
    V. Shelke, D. Mazumdar, G. Srinivasan, A. Kumar, S. Jesse, S. Kalinin, A. Baddrof, A. Gupta, Adv. Mater. 23, 669 (2011)CrossRefGoogle Scholar
  11. 11.
    D. Mazumdar, V. Shelke, M. Iliev, S. Jesse, A. Kumar, S.V. Kalinin, A.P. Baddrof, A. Gupta, Nano Lett. 10, 2555 (2010)CrossRefGoogle Scholar
  12. 12.
    R. Palai, R.S. Katiyar, H. Schmid, P. Tissot, S.J. Clark, J. Robertson, S.A.T. Redfern, J.F. Scott, Phys. Rev. B 77, 014110 (2008)CrossRefGoogle Scholar
  13. 13.
    A.G. Gavriliuk, V.V. Struzhkin, I.S. Lyubutin, S.G. Ovchinnikov, M.Y. Hu, P. Chow, Phys. Rev. B 77, 155112 (2008)CrossRefGoogle Scholar
  14. 14.
    M.E. Castillo, V.V. Shvartsman, D. Gobeljic, Y. Gao, J. Landers, H. Wende, D.C. Lupascu, Nanotechnology 24, 355701 (2013)CrossRefGoogle Scholar
  15. 15.
    C. Yang, D. Kan, I. Takeuchi, V. Nagarajan, J. Seidel, Phys. Chem. Chem. Phys. 14, 15953 (2012)CrossRefGoogle Scholar
  16. 16.
    H. Ishiwara, Curr. Appl. Phys. 12, 603 (2012)CrossRefGoogle Scholar
  17. 17.
    T. Park, C. Georgia, A.J. Viescas, Y. Lee, H. Zhou, S.S. Wong, Phys. Rev. B 82, 024431 (2010)CrossRefGoogle Scholar
  18. 18.
    V.R. Palkar, K. Prashanthi, Appl. Phys. Lett. 93, 132906 (2008)CrossRefGoogle Scholar
  19. 19.
    R.J. Zeches, M.D. Rossell, J.X. Zhang, A.J. Hatt, Q. He, C.-H. Yang, A. Kumar, C.H. Wang, A. Melville, C. Adamo, G. Sheng, Y.-H. Chu, J.F. Ihlefeld, R. Erni, C. Ederer, V. Gopalan, L.Q. Chen, D.G. Schlom, N.A. Spaldin, L.W. Martin, R. Ramesh, Science 326, 977 (2009)CrossRefGoogle Scholar
  20. 20.
    S.T. Zhang, L.H. Pang, Y. Zhang, M.H. Lu, Y.F. Chen, J. Appl. Phys. 100, 114108 (2006)CrossRefGoogle Scholar
  21. 21.
    J.H. Lee, M.A. Oak, H.J. Choi, J.Y. Son, H.M. Jang, J. Mater. Chem. 22, 1667 (2012)CrossRefGoogle Scholar
  22. 22.
    O.E.G. Vazquez, J.C. Wojdeł, O. Dieguez, J.I. Niguez, Phys. Rev. B 85, 064119 (2012)CrossRefGoogle Scholar
  23. 23.
    J. Bielecki, P. Svedlindh, D.T. Tibebu, S. Cai, S.G. Eriksson, L. Borjesson, C.S. Knee, Phys. Rev. B 86, 184422 (2012)CrossRefGoogle Scholar
  24. 24.
    M. Khodabakhsh, C. Sen, H. Khassaf, M.A. Gulgun, I.B. Misirlioglu, J. Alloy. Compd. 604, 117 (2014)CrossRefGoogle Scholar
  25. 25.
    H. Deng, M. Zhang, Z. Hu, Q. Xie, Q. Zhong, J. Wei, H. Yan, J. Alloy. Compd. 582, 273 (2014)CrossRefGoogle Scholar
  26. 26.
    Z. Cheng, X. Wang, S. Dou, H. Kimura, K. Ozawa, Phys. Rev. B 77, 092101 (2008)CrossRefGoogle Scholar
  27. 27.
    A. Reetu, S. Agarwal, N. Sanghi Ashima, Ahlawat, J. Phys. D 45, 165001 (2012)CrossRefGoogle Scholar
  28. 28.
    C. Nayek, A. Tamilselvan, Ch Thirmal, P. Murugavel, S. Balakumar, J. Appl. Phys. 115, 073902 (2014)CrossRefGoogle Scholar
  29. 29.
    Y.H. Lin, Q. Jiang, Y. Wang, C.W. Nan, L. Chen, J. Yu, Appl. Phys. Lett. 90, 172507 (2007)CrossRefGoogle Scholar
  30. 30.
    M. Rangi, S. Sanghi, S. Jangra, K. Kaswan, S. Khasa, A. Agrawal, Ceram. Int. 43, 12095 (2017)CrossRefGoogle Scholar
  31. 31.
    Q.-H. Jiang, C.-W. Nan, Z.-J. Shen, J. Am. Ceram. Soc. 89, 2123 (2006)CrossRefGoogle Scholar
  32. 32.
    Y. Du, Z.X. Cheng, M. Shahbazi, E.W. Collings, S.X. Dou, X.L. Wang, J. Alloy. Compd. 490, 637 (2010)CrossRefGoogle Scholar
  33. 33.
    Z. Zhang, P. Wu, L. Chen, J. Wang, Appl. Phys. Lett. 96, 012905 (2010)CrossRefGoogle Scholar
  34. 34.
    G.L. Yuan, S. Wing Or, J. Appl. Phys. 100, 024109 (2006)CrossRefGoogle Scholar
  35. 35.
    V.A. Khomchenko, D.V. Karpinsky, L.C.J. Pereira, A.L. Kholkin, J.A. Paixao, J. Appl. Phys. 113, 214112 (2013)CrossRefGoogle Scholar
  36. 36.
    S. Pillai, D. Bhuwal, A. Banerjee, V. Shelke, Appl. Phys. Lett. 102, 072907 (2013)CrossRefGoogle Scholar
  37. 37.
    S. Pillai, H.A. Reshi, T. Bagwaiya, A. Banerjee, V. Shelke, J. Appl. Phys. 122, 104101 (2017)CrossRefGoogle Scholar
  38. 38.
    S. Pillai, D. Bhuwal, T. Shripathi, V. Shelke, J. Mater. Sci. 24, 2950 (2013)Google Scholar
  39. 39.
    G. Catalan, K. Sardar, N.S. Church, J.F. Scott, R.J. Harrison, S.A.T. Redfern, Phys. Rev. B 79, 214115 (2009)CrossRefGoogle Scholar
  40. 40.
    I.O. Troyanchuk, D.V. Karpinsky, M.V. Bushinsky, V.A. Khomchenko, G.N. Kakazei, J.P. Araujo, M. Tovar, V. Sikolenko, V. Efimov, A.L. Kholkin, Phys. Rev. B 83, 054109 (2011)CrossRefGoogle Scholar
  41. 41.
    A. Lahmar, S. Habouti, M. Dietze, C.-H. Solterbeck, M. Es-Souni, Appl. Phys. Lett. 94, 012903 (2009)CrossRefGoogle Scholar
  42. 42.
    O. Garcia-Zaldivar, S. Diaz-Castanon, F.J. Espinoza-Beltran, M.A. Hernandez-Landaverde, G. Lopez, J. Faloh-Gandarilla, F. Calderon-Pinar, J. Adv. Dielectr. 5, 1550034 (2015)CrossRefGoogle Scholar
  43. 43.
    P.S.V. Mocherla, C. Karthik, R. Ubic, M.S.R. Rao, C. Sudakar, Appl. Phys. Lett. 103, 022910 (2013)CrossRefGoogle Scholar
  44. 44.
    S. Chauhan, M. Kumar, P. Pal, RSC Adv. 6, 68028 (2016)CrossRefGoogle Scholar
  45. 45.
    I.B.S. Banu, S.D. Lakshmi, J. Mater. Sci. 28, 16044 (2017)Google Scholar
  46. 46.
    Z. Quan, H. Hu, S. Xu, W. Liu, G. Fang, M. Li, X. Zhao, J. Sol-Gel Sci. Technol. 48, 261 (2008)CrossRefGoogle Scholar
  47. 47.
    E. Beyreuther, S. Grafstrom, L.M. Eng, C. Thiele, K. Dorr, Phys. Rev. B 73, 155425 (2006)CrossRefGoogle Scholar
  48. 48.
    A. Singh, R. Chatterjee, S.K. Mishra, P.S.R. Krishna, S.L. Chaplot, J. Appl. Phys. 111, 014113 (2012)CrossRefGoogle Scholar
  49. 49.
    E.K. Abdel-Khalek, I. Ibrahim, T.M. Salama, A.M. Elseman, M.M. Mohamed, J. Magn. Magn. Mater. 465, 309 (2018)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of PhysicsBarkatullah UniversityBhopalIndia

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