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Synthesis, energy transfer, charge compensation and luminescence properties of CaZrO3:Eu3+, Bi3+, Li+ phosphor

  • Renping Cao
  • Hui Xiao
  • Falin Zhang
  • Xinyu Cheng
  • Lei Su
  • Fen Xiao
  • Zhiyang Luo
  • Ting Chen
Article
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Abstract

A series of CaZrO3:Bi3+, CaZrO3:Eu3+, CaZrO3:Eu3+, Bi3+, and CaZrO3:Eu3+, Bi3+, Li+ phosphors are synthesized by high-temperature solid-state reaction method in air. Their luminescence properties are researched, compared, and analyzed. CaZrO3:Bi3+ phosphor under excitation at 310 nm emits deep-blue light with chromaticity coordinate (0.1612, 0.0254). CaZrO3:Eu3+ phosphor under excitation at 310 and 395 nm shows red-emitting with chromaticity coordinate (0.6386, 0.3611). CaZrO3:Eu3+, Bi3+ phosphor under excitation at 310 nm exhibits a systematically varied hue from deep-blue to red light by changing Eu3+ ion concentration, and that with excitation at 395 nm only emits red light with chromaticity coordinate (0.6386, 0.3611). The energy transfer process from Bi3+ to Eu3+ ions may be indicated by their spectral properties. The optimal Eu3+ and Bi3+ ions concentrations are 5 mol% and 0.9 mol%, respectively. The emission intensity CaZrO3:Eu3+, Bi3+ phosphor may be enhanced about 1.6 times due to the co-doping Li+ ion as charge compensator role. The luminous mechanism of CaZrO3:Eu3+, Bi3+ phosphor is explained by the simplified energy level diagrams of Bi3+ and Eu3+ ions.

Notes

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 51862015 and 51562011), National Undergraduate Training Program for Innovation and Entrepreneurship (No. 201810419019).

References

  1. 1.
    Q. Du, G. Zhou, J. Zhou, H. Zhou, J. Lumin. 137, 83–87 (2013)CrossRefGoogle Scholar
  2. 2.
    V. Singh, V.K. Rai, M. Haase, J. Appl. Phys. 112, 063105 (2012)CrossRefGoogle Scholar
  3. 3.
    H. Yang, H.S. Lee, P.G. Kotula, Y. Sato, Y. Ikuhara, N.D. Browning, Appl. Phys. Lett. 106, 121904:1–5 (2015)Google Scholar
  4. 4.
    R. Cao, P. Han, W. Luo, T. Fu, Z. Luo, P. Liu, Z. Chen, X. Yu, J. Electron. Mater. 45(7), 3361–3366 (2016)CrossRefGoogle Scholar
  5. 5.
    H. Zhang, X. Fu, S. Niu, Q. Xin, J. Lumin. 128, 1348–1352 (2008)CrossRefGoogle Scholar
  6. 6.
    S. Sakaida, Y. Shimokawa, T. Asaka, S. Honda, Y. Iwamoto, Mater. Res. Bull. 67, 146–151 (2015)CrossRefGoogle Scholar
  7. 7.
    Q. Du, G. Zhou, J. Zhou, H. Zhou, J. Zhan, Z. Yang, J. Rare Earths 30, 1000–1004 (2012)CrossRefGoogle Scholar
  8. 8.
    V. Singh, S. Watanabe, T. Rao, K. Al-Shamery, M. Haase, Y. Jho, J. Lumin. 132, 2036–2042 (2012)CrossRefGoogle Scholar
  9. 9.
    N. Tiwari, V. Dubey, Luminescence 31(3), 837–842 (2016)CrossRefGoogle Scholar
  10. 10.
    V. Singh, G. Sivaramaiah, J. Rao, S. Kim, J. Electron. Mater. 43, 3486–3492 (2014)CrossRefGoogle Scholar
  11. 11.
    Q. Du, G. Zhou, S. Zhang, X. Jia, H. Zhou, Z. Yang, Bull. Mater. Sci. 38, 215–220 (2015)CrossRefGoogle Scholar
  12. 12.
    Q. Du, G. Zhou, J. Zhou, H. Zhou, J. Zhan, Mater. Res. Bull. 47, 3774–3779 (2012)CrossRefGoogle Scholar
  13. 13.
    Y. Li, Y. Wang, J. Inf. Disp. 12, 93–96 (2011)CrossRefGoogle Scholar
  14. 14.
    R. Cao, T. Fu, Y. Cao, S. Jiang, Q. Gou, Z. Chen, P. Liu, J. Mater. Sci.: Mater. Electron. 27, 3514–3519 (2016)Google Scholar
  15. 15.
    H. Akazawa, H. Shinojima, J. Phys. Chem. Solids 117, 60–69 (2018)CrossRefGoogle Scholar
  16. 16.
    J. Huang, L. Zhou, Y. Lan, F. Gong, Q. Li, J. Sun, Cent. Eur. J. Phys. 9, 975–997 (2011) 9.Google Scholar
  17. 17.
    T. Orihashi, T. Nakamura, S. Adachi, RSC Adv. 6, 66130–66139 (2016)CrossRefGoogle Scholar
  18. 18.
    K. Panigrahi, S. Saha, S. Sain, R. Chatterjee, A. Das, U.K. Ghorai, N.S. Das, K.K. Chattopadhyay, Dalton Trans. 47, 12228–12242 (2018)CrossRefGoogle Scholar
  19. 19.
    R. Chatterjee, S. Saha, D. Sen, K. Panigrahi, U.K. Ghorai, G.C. Das, K.K. Chattopadhyay, ACS Omega 3(1), 788–800 (2017)CrossRefGoogle Scholar
  20. 20.
    I. Levin, T.G. Amos, S.M. Bell, L. Farber, T.A. Vanderah, R.S. Roth, B.H. Toby, J. Solid State Chem. 175, 170–181 (2003)CrossRefGoogle Scholar
  21. 21.
    P. Stoch, J. Szczerba, J. Lis, D. Madej, Z. Pedzich, J. Eur. Ceram. Soc. 32, 665–670 (2012)CrossRefGoogle Scholar
  22. 22.
    R.D. Shannon, Acta Crystallogr. A 32, 751–767 (1976)CrossRefGoogle Scholar
  23. 23.
    S.K. Gupta, P.S. Ghosh, N. Pathaka, R. Tewarib, RSC Adv. 5, 56526–56533 (2015)CrossRefGoogle Scholar
  24. 24.
    R. Cao, T. Fu, D. Peng, C. Cao, W. Ruan, X. Yu, Spectrochim. Acta A 169, 192–196 (2016)CrossRefGoogle Scholar
  25. 25.
    S. Yuhei, S. Sho, G. Katsuhiko, N. Yutaka, U. Kazushige, Mater. Sci. Eng. B 161, 100–103 (2009)CrossRefGoogle Scholar
  26. 26.
    H.T. Sun, J.J. Zhou, J.R. Qiu, Prog. Mater. Sci. 64, 1–72 (2014)CrossRefGoogle Scholar
  27. 27.
    R. Cao, D. Peng, T. Fu, Z. Luo, S. Zhou, S. Jiang, J. Fu, J. Mater. Sci.: Mater. Electron. 27(8), 8094–8099 (2016)Google Scholar
  28. 28.
    G. Liu, B. Jacquier, Spectroscopic Properties of Rare Earths in Optical Materials (Springer, Berlin, 2005)Google Scholar
  29. 29.
    Y. Peng, W. Shi, C. Han, Y. Kang, Y. Wang, Z. Zhang, Spectrochim. Acta A 145, 194–197 (2015)CrossRefGoogle Scholar
  30. 30.
    R. Cao, G. Quan, Z. Shi, Q. Gou, T. Chen, Z. Hu, Z. Luo, J. Mater. Sci.: Mater. Electron. 29, 5287–5292 (2018)Google Scholar
  31. 31.
    R.N. Perumal, G. Subalakshmi, E. Varadarajan, S. Sadhasivam, G. Vinitha, J. Mater. Sci.: Mater. Electron. 29, 2638–2644 (2018)Google Scholar
  32. 32.
    G. Blasse, B.C. Grabmaier, Luminescent Materials (Springer, Berlin, 1994)CrossRefGoogle Scholar
  33. 33.
    P. Niu, X. Liu, Y. Wang, W. Zhao, J. Mater. Sci.: Mater. Electron. 29, 124–129 (2018)Google Scholar
  34. 34.
    W. Liu, C. Huang, C. Wu, Y. Chiu, Y. Yeh, T. Chen, J. Mater. Chem. 21(19), 6869–6874 (2011)CrossRefGoogle Scholar
  35. 35.
    A.A. Setlur, A.M. Srivastava, Opt. Mater. 29, 410–415 (2006)CrossRefGoogle Scholar
  36. 36.
    P. Boutinaud, Inorg. Chem. 52(10), 6028–6038 (2013)CrossRefGoogle Scholar
  37. 37.
    H. Zhu, M. Fang, Z. Huang, Y. Liu, K. Chen, C. Tang, L. Zhang, Opt. Mater. 49, 266–270 (2015)CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Mathematics and PhysicsJinggangshan UniversityJi’anChina
  2. 2.College of Mechanical Manufacture and AutomationJinggangshan UniversityJi’anChina

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