Electrical and optical responses of composite films based on N,N-dimethylamino-4′-N′-methylstilbazolium 2,4,6-trimethylbenzenesulfonate (DSTMS)-graphene
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N,N-dimethylamino-4′-N′-methylstilbazolium 2,4,6-trimethylbenzenesulfonate (DSTMS)-graphene ex-situ and in-situ composite films with 2% concentration of graphene were first prepared and systematically investigated. The crystallinity of DSTMS-based composite films were confirmed by XRD analysis, and the functional groups of composite films can be obtained by FT-IR. Optical absorptions were recorded using UV–Vis-NIR spectral analysis, and the band gap and extinction coefficient of the films were calculated. The thermal stability of the composite films were analyzed by TG/DSC. The pressure sensitive resistance test showed that the pressure sensitive signal of the composite films were significantly increased after graphene added, while the signal of DSTMS film eventually disappears. This work expands the application of organic nonlinear crystal DSTMS in optics and electricity by doping graphene.
This work was supported by Project of Major Basic Research Projects of Shandong Natural Science Foundation (ZR2018ZB0650), Program for National Natural Science Foundation of China (No. 51172111 and No. 51402159) and a Project of Shandong Province Higher Educational Science and Technology Program (No. J14LA17), China Postdoctoral Science Foundation (No. 2015M57073), the Qingdao Postdoctoral Application Research Project (No. 2015116).
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