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Control of the structure and photoelectrical properties of Cu(InGa)Se2 film by Ga deposition potential in two-step electrodeposition

  • Linrui Zhang
  • Jingjing Qu
  • Tianwei Yu
  • Yichuan Chen
  • Wei Pang
  • MingHao Qu
  • Hao Wang
  • Yongzhe Zhang
  • Hui Yan
Article
  • 9 Downloads

Abstract

In present work, a simple two-step electrodeposition method (first CuIn then Ga) was used to prepare the Cu-In-Ga precursor. The as-deposited films were selenized in nitrogen atmosphere at 550 °C for 40 min. The effect of Ga deposition potential on the structural, morphological, optical and electrical properties were investigated by means of X-ray diffraction, Raman spectra, scanning electron microscopy, UV–visible Spectroscopy and photo-electrochemical measurement, respectively. XRD results show that prepared Cu(InGa)Se2 films have a tetragonal chalcopyrite CIS with preferential orientation along the (112) orientation. And the size of grain and the band gap were various with the increase of the Ga deposited potential, resulting in the effective control of photo-current intensity of Cu(InGa)Se2. The Mott–Schottky plots confirmed all the films exhibited a good p-type semiconductor characteristic.

Notes

Acknowledgements

This project was supported by National Science Foundation of China (NSFC no. 61574009 and no. 11574014).

References

  1. 1.
    A.M. Fernandez, J.A. Turner, B. Lara-Lara, T.G. Deutsch, Superlattices Microstruct. 101, 373–383 (2017)CrossRefGoogle Scholar
  2. 2.
    P. Jackson, R. Wuerz, D. Hariskos, E. Lotter, W. Witte, M. Powalla, Phys. Status Solidi RRL 10, 583–586 (2016)CrossRefGoogle Scholar
  3. 3.
    L. Zhang, T. Li, Y. Chen, W. Pang, M. Qu, X. Song, Y. Zhang, H. Yan, J. Mater. Sci. Mater. Electron. 29, 3482–3491 (2017)CrossRefGoogle Scholar
  4. 4.
    J. Bi, J. Ao, Q. Gao, Z. Zhang, G. Sun, Q. He, Z. Zhou, Y. Sun, Y. Zhang, ACS Appl. Mater. Interfaces 9, 18682–18690 (2017)CrossRefGoogle Scholar
  5. 5.
    L.R. Zhang, T. Li, H. Wang, W. Pang, Y.C. Chen, X.M. Song, Y.Z. Zhang, H. Yan, Superlattices Microstruct. 114, 370–378 (2018)CrossRefGoogle Scholar
  6. 6.
    R.N. Bhattacharya, M.-K. Oh, Y. Kim, Sol. Energy Mater. Sol. Cells 98, 198–202 (2012)CrossRefGoogle Scholar
  7. 7.
    R. Friedfeld, J.G. Mantovani, Sol. Energy Mater. Sol. Cells 58, 375–385 (1999)CrossRefGoogle Scholar
  8. 8.
    S. Mandati, B.V. Sarada, S.R. Dey, S.V. Joshi, Mater. Lett. 118, 158–160 (2014)CrossRefGoogle Scholar
  9. 9.
    R.N. Bhattacharya, J. Electrochem. Soc. 157, D406–D410 (2010)CrossRefGoogle Scholar
  10. 10.
    Y. Lai, J. Liu, Y. Jia, W. Bo, F. Liu, Z. Zhang, L. Jie, Y. Liu, J. Electrochem. Soc. 158, D704 (2011)CrossRefGoogle Scholar
  11. 11.
    M. Park, S. Ahn, J.H. Yun, J. Gwak, A. Cho, S. Ahn, K. Shin, D. Nam, H. Cheong, K. Yoon, J. Alloys Compd. 513, 68–74 (2012)CrossRefGoogle Scholar
  12. 12.
    R.N. Bhattacharya, Sol. Energy Mater. Sol. Cells 113, 96–99 (2013)CrossRefGoogle Scholar
  13. 13.
    H. Saidi, M.F. Boujmil, B. Durand, M. Bouaïcha, J. Alloys Compd. 695, 779–786 (2017)CrossRefGoogle Scholar
  14. 14.
    J. Bi, J. Ao, M.-J. Jeng, L. Yao, S. Gao, G. Sun, Q. He, Z. Zhou, Y. Sun, Y.-L. Xiao, L.-B. Chang, Sol. Energy Mater. Sol. Cells 159, 352–361 (2017)CrossRefGoogle Scholar
  15. 15.
    F. Oliva, C. Broussillou, M. Annibaliano, N. Frederich, P.P. Grand, A. Roussy, P. Collot, S. Bodnar, Thin Solid Films 535, 127–132 (2013)CrossRefGoogle Scholar
  16. 16.
    S. Jung, S. Ahn, J.H. Yun, J. Gwak, D. Kim, K. Yoon, Curr. Appl. Phys. 10, 990–996 (2010)CrossRefGoogle Scholar
  17. 17.
    L. Ribeaucourt, E. Chassaing, G. Savidand, D. Lincot, Thin Solid Films 519, 7241–7244 (2011)CrossRefGoogle Scholar
  18. 18.
    M. Kaelin, D. Rudmann, F. Kurdesau, T. Meyer, H. Zogg, A.N. Tiwari, Thin Solid Films 431–432, 58–62 (2003)CrossRefGoogle Scholar
  19. 19.
    S. Mandati, B.V. Sarada, S.R. Dey, S.V. Joshi, J. Power Sources 273, 149–157 (2015)CrossRefGoogle Scholar
  20. 20.
    V. Izquierdo-Roca, E. Saucedo, C.M. Ruiz, X. Fontané, L. Calvo-Barrio, J. Álvarez-Garcia, P.-P. Grand, J.S. Jaime-Ferrer, A. Pérez-Rodríguez, J.R. Morante, V. Bermudez, Phys. Stat. Sol. A 206, 1001–1004 (2009)CrossRefGoogle Scholar
  21. 21.
    S. Mandati, S.R. Dey, S.V. Josh, J. Electrochem. Soc. 160, D173–D177 (2013)CrossRefGoogle Scholar
  22. 22.
    Y. Cho, D.-W. Kim, S. Ahn, D. Nam, H. Cheong, G.Y. Jeong, J. Gwak, J.H. Yun, Thin Solid Films 546, 358–361 (2013)CrossRefGoogle Scholar
  23. 23.
    I.-H. Choi, Thin Solid Films 519, 4390–4393 (2011)CrossRefGoogle Scholar
  24. 24.
    J. Koo, S. Kwon, Y.-S. Roh, S.-J. Lee, K.-Y. Jung, W.N. Shafarman, J.-H. Park, D.H. Kim, J.-M. Myoung, W.K. Kim, Electron. Mater. Lett. 12, 484–493 (2016)CrossRefGoogle Scholar
  25. 25.
    J. López-García, M. Placidi, X. Fontané, V. Izquierdo-Roca, M. Espindola, E. Saucedo, C. Guillén, J. Herrero, A. Pérez-Rodriguez, Sol. Energy Mater. Sol. Cells 132, 245–251 (2015)CrossRefGoogle Scholar
  26. 26.
    X. Zhu, Z. Zhou, Y. Wang, L. Zhang, A. Li, F. Huang, Sol. Energy Mater. Sol. Cells 101, 57–61 (2012)CrossRefGoogle Scholar
  27. 27.
    S. Theodoropoulou, D. Papadimitriou, N. Rega, S. Siebentritt, M.C. Lux-Steiner, Thin Solid Films 511–512, 690–694 (2006)CrossRefGoogle Scholar
  28. 28.
    M. Nagao, A. Miura, S. Watauchi, T. Takei, N. Kumada, I. Tanaka, J. Cryst. Growth 412, 16–19 (2015)CrossRefGoogle Scholar
  29. 29.
    P.T. Erslev, J.W. Lee, W.N. Shafarman, J.D. Cohen, Thin Solid Films 517, 2277–2281 (2009)CrossRefGoogle Scholar
  30. 30.
    J.J. Scragg, Copper Zinc Tin Sulfide Thin Films for Photovoltaics, 1nd edn. (Springer, Berlin Heidelberg, 2011), pp. 172–173CrossRefGoogle Scholar
  31. 31.
    H. Ye, V.A. Akhavan, B.W. Goodfellow, M.G. Panthani, B.A. Korgel, A.J. Bard, J. Phys. Chem. C 115, 234–240 (2011)CrossRefGoogle Scholar
  32. 32.
    A.M. Fernandez, P.J. Sebastian, M.E. Calixto, S.A. Gamboa, O. Solorza, Thin Solid Films 298, 92–97 (1997)CrossRefGoogle Scholar
  33. 33.
    K. Ueda, T. Hase, H. Yanagi, H. Kawazoe, H. Hosono, H. Ohta, M. Orita, M. Hirano, J. Appl. Phys. 89, 1790 (2001)CrossRefGoogle Scholar
  34. 34.
    L. Kronik, J.-F. Guillemoles, D. Braunger, H.-W. Schock, D. Cahen, Thin Solid Films 361–362, 353–359 (2000)CrossRefGoogle Scholar
  35. 35.
    S.-H. Wei, S.B. Zhang, A. Zunger, Appl. Phys. Lett. 72, 3199–3201 (1998)CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Linrui Zhang
    • 1
  • Jingjing Qu
    • 1
  • Tianwei Yu
    • 1
  • Yichuan Chen
    • 1
  • Wei Pang
    • 1
  • MingHao Qu
    • 2
  • Hao Wang
    • 1
  • Yongzhe Zhang
    • 1
  • Hui Yan
    • 1
  1. 1.The College of Materials Science and EngineeringBeijing University of TechnologyBeijingChina
  2. 2.Hanergy Thin Film Power, R & D CenterChengduChina

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