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The fabrication and thermal conductivity of epoxy composites with 3D nanofillers of AgNWs@SiO2&GNPs

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Abstract

The development of electronic makes increasing attentions focus on the high thermally conductive polymer composites. In this work, outstanding epoxy nanocomposites embedded with 3D structure fillers of silver nanowires@SiO2 and graphite nanoplatelets are prepared successfully. Insulative SiO2 layers coating on the surface of silver nanowires can not only provide abundant silicon hydroxyl groups to react and form strong covalent bonding with epoxy matrix and graphite nanoplatelets, minimizing the scattering of phonon and contributing to construction of thermally conductive network, but also effectively protect electrical insulation from the forming of electrical conductive pathways. An ultrahigh thermal conductivity of nanocomposites 1.092 W/m K, an enhancement of 474% to pristine epoxy, is achieved only with low filler volume fraction of 0.8 vol% silver nanowires@SiO2 and 2.7 vol% graphite nanoplatelets, at the same time, an ultralow volume conductivity less than 1 × 10−5 S/cm is available at the frequency range 1 × 102Hz to 1 × 106Hz, which indicates strong potential in the field of electronic packaging.

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References

  1. J. Gu, W. Dong, S. Xu, Y. Tang, L. Ye, J. Kong, Compos. Sci. Technol. 144, 185–192 (2017)

    Article  Google Scholar 

  2. C. Pan, K. Kou, Q. Jia, Y. Zhang, G. Wu, T. Ji, Compos. Part B 111, 83–90 (2017)

    Article  Google Scholar 

  3. G. Wu, Y. Cheng, Y. Ren, Y. Wang, Z. Wang, H. Wu, J. Alloys Compd. 652, 346–350 (2015)

    Article  Google Scholar 

  4. G. Wu, Y. Cheng, F. Xiang, Z. Jia, Q. Xie, G. Wu, H. Wu, Mater. Sci. Semicond. Process. 41, 6–11 (2016)

    Article  Google Scholar 

  5. Y.-S. Tang, J. Kong, J.-W. Gu, G.-Z. Liang, Polym. Plast. Technol. Eng. 48, 359–366 (2009)

    Article  Google Scholar 

  6. G. Wu, Y. Cheng, Q. Xie, Z. Jia, F. Xiang, H. Wu, Mater. Lett. 144, 157–160 (2015)

    Article  Google Scholar 

  7. N. Chisholm, H. Mahfuz, V.K. Rangari, A. Ashfaq, S. Jeelani, Compos. Struct. 67, 115–124 (2005)

    Article  Google Scholar 

  8. S. Choi, J. Kim, Compos. Part B 51, 140–147 (2013)

    Article  Google Scholar 

  9. Y. Heo, H. Im, J. Kim, J. Kim, J. Nanopart. Res. 14, 1196 (2012)

    Article  Google Scholar 

  10. J. Gu, Q. Zhang, Y. Tang, J. Zhang, J. Kong, J. Dang, H. Zhang, X. Wang, Surf. Coat. Technol. 202, 2891–2896 (2008)

    Article  Google Scholar 

  11. G. Wu, Y. Cheng, K. Wang, Y. Wang, A. Feng, J. Mater. Sci. 27, 5592–5599 (2016)

    Google Scholar 

  12. J. Lee, H. Jung, S. Yu, S. Man Cho, V.K. Tiwari, D. Babu Velusamy, C. Park, Chemistry 11, 1921–1928 (2016)

    Google Scholar 

  13. X. Huang, S. Wang, M. Zhu, K. Yang, P. Jiang, Y. Bando, D. Golberg, C. Zhi, Nanotechnology 26, 015705 (2014)

    Article  Google Scholar 

  14. H. Chen, V.V. Ginzburg, J. Yang, Y. Yang, W. Liu, Y. Huang, L. Du, B. Chen, Prog. Polym. Sci. 59, 41–85 (2016)

    Article  Google Scholar 

  15. J. Gu, Z. Lv, Y. Wu, Y. Guo, L. Tian, H. Qiu, W. Li, Q. Zhang, Compos. Part A 94, 209–216 (2017)

    Article  Google Scholar 

  16. G. Wu, Y. Wang, K. Wang, A. Feng, RSC Adv. 6, 102542–102548 (2016)

    Article  Google Scholar 

  17. J. Gu, S. Xu, Q. Zhuang, Y. Tang, J. Kong, IEEE Trans. Dielectr. Electr. Insul. 24, 784–790 (2017)

    Article  Google Scholar 

  18. G. Wu, J. Li, K. Wang, Y. Wang, C. Pan, A. Feng, J. Mater. Sci. 28, 6544–6551 (2017)

    Google Scholar 

  19. J. Gu, C. Liang, X. Zhao, B. Gan, H. Qiu, Y. Guo, X. Yang, Q. Zhang, D.-Y. Wang, Compos. Sci. Technol. 139, 83–89 (2017)

    Article  Google Scholar 

  20. G. Wu, Y. Cheng, Z. Wang, K. Wang, A. Feng, J. Mater. Sci. 28, 576–581 (2017)

    Google Scholar 

  21. C. Zhi, Y. Bando, T. Terao, C. Tang, H. Kuwahara, D. Golberg, Adv. Funct. Mater. 19, 1857–1862 (2009)

    Article  Google Scholar 

  22. H. Wu, G. Wu, L. Wang, Powder Technol. 269, 443–451 (2015)

    Article  Google Scholar 

  23. G. Wu, H. Wu, K. Wang, C. Zheng, Y. Wang, A. Feng, RSC Adv. 6, 58069–58076 (2016)

    Article  Google Scholar 

  24. S. Kemaloglu, G. Ozkoc, A. Aytac, Thermochim. Acta 499, 40–47 (2010)

    Article  Google Scholar 

  25. K.I. Winey, T. Kashiwagi, M. Mu, MRS Bull. 32, 348–353 (2011)

    Article  Google Scholar 

  26. F.H. Gojny, M.H.G. Wichmann, B. Fiedler, I.A. Kinloch, W. Bauhofer, A.H. Windle, K. Schulte, Polymer 47, 2036–2045 (2006)

    Article  Google Scholar 

  27. K. Kim, M. Kim, Y. Hwang, J. Kim, Ceram. Int. 40, 2047–2056 (2014)

    Article  Google Scholar 

  28. J. Gu, Q. Zhang, J. Dang, C. Xie, Polym. Adv. Technol. 23, 1025–1028 (2012)

    Article  Google Scholar 

  29. X. Huang, C. Zhi, P. Jiang, D. Golberg, Y. Bando, T. Tanaka, Adv. Funct. Mater. 23, 1824–1831 (2013)

    Article  Google Scholar 

  30. C. Min, D. Yu, J. Cao, G. Wang, L. Feng, Carbon 55, 116–125 (2013)

    Article  Google Scholar 

  31. J. Chen, X. Huang, Y. Zhu, P. Jiang, Adv. Funct. Mater. 27, 1604754 (2017)

    Article  Google Scholar 

  32. N. Burger, A. Laachachi, M. Ferriol, M. Lutz, V. Toniazzo, D. Ruch, Prog. Polym. Sci. 61, 1–28 (2016)

    Article  Google Scholar 

  33. J.D. Renteria, S. Ramirez, H. Malekpour, B. Alonso, A. Centeno, A. Zurutuza, A.I. Cocemasov, D.L. Nika, A.A. Balandin, Adv. Funct. Mater. 25, 4664–4672 (2015)

    Article  Google Scholar 

  34. H. Zhu, Y. Li, Z. Fang, J. Xu, F. Cao, J. Wan, C. Preston, B. Yang, L. Hu, ACS Nano 8, 3606–3613 (2014)

    Article  Google Scholar 

  35. C. Yang, H. Gu, W. Lin, M.M. Yuen, C.P. Wong, M. Xiong, B. Gao, Adv. Mater. 23, 3052–3056 (2011)

    Article  Google Scholar 

  36. C. Chen, Y. Tang, Y.S. Ye, Z. Xue, Y. Xue, X. Xie, Y.-W. Mai, Compos. Sci. Technol. 105, 80–85 (2014)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Applied Chemistry, School of Natural and Applied Sciences, Northwestern Polytechnical University, Xi’an, 710072, Shaanxi, China

    Meiyu Yang, Xingwei Wang, Rumin Wang & Shuhua Qi

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  1. Meiyu Yang
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  2. Xingwei Wang
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  3. Rumin Wang
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  4. Shuhua Qi
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Correspondence to Shuhua Qi.

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Yang, M., Wang, X., Wang, R. et al. The fabrication and thermal conductivity of epoxy composites with 3D nanofillers of AgNWs@SiO2&GNPs. J Mater Sci: Mater Electron 28, 16141–16147 (2017). https://doi.org/10.1007/s10854-017-7514-1

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  • DOI: https://doi.org/10.1007/s10854-017-7514-1

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