Zinc oxide nanoparticles: solvent-free synthesis, characterization and application as heterogeneous nanocatalyst for photodegradation of dye from aqueous phase

  • Mojgan Goudarzi
  • Mehdi Mousavi-Kamazani
  • Masoud Salavati-Niasari
Article

Abstract

In present study, for the first time, ZnO nanoparticles have been synthesized via a simple, novel, solvent and template free solid-state thermal decomposition of the mixed Zn(NO3)·6H2O and cochineal powders as a novel starting reagent at 600 °C for 3 h. The as-prepared product was analyzed by XRD, EDS, SEM, TEM, FT-IR and DRS. Besides, the effect of cochineal powder on the morphology and particle size of ZnO nanoparticles was investigated. The results exhibited that cochineal powder prevents the sintering of nanoparticles and leads to formation of uniform particles. Moreover, the efficiency of ZnO nanoparticles as a photocatalyst for the decolorization of methylene orange (MO) has been evaluated and 90% degradation of MO was obtained after 120 min.

Keywords

Photocatalytic Activity Methylene Orange Energy Dispersive Spectrometry Oleylamine Zinc Oxide Nanoparticles 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

Authors are grateful to the council of Iran National Science Foundation (INSF) and University of Kashan for supporting this work by Grant No (159271/5279).

References

  1. 1.
    T. Kawano, H. Imai, Cryst. Growth Des. 6, 1054 (2006)CrossRefGoogle Scholar
  2. 2.
    M. Salavati-Niasari, F. Davar, A. Khansari, J. Alloys Compd. 509, 61 (2011)CrossRefGoogle Scholar
  3. 3.
    J. Tamaki, Sensor Lett. 3, 89 (2005)CrossRefGoogle Scholar
  4. 4.
    M. Kurtz, J. Strunk, O. Hinrichsen, M. Muhler, K. Fink, B. Meyer, C. Wöll, Angew. Chem. Int. Ed. 44, 2790 (2005)CrossRefGoogle Scholar
  5. 5.
    C. Yang, J. Wang, W. Ge, L. Guo, S. Yang, D. Shen, J. Appl. Phys. 90, 4489 (2001)CrossRefGoogle Scholar
  6. 6.
    M. Izaki, K.-T. Mizuno, T. Shinagawa, M. Inaba, A. Tasaka, J. Electrochem. Soc. 153, C668 (2006)CrossRefGoogle Scholar
  7. 7.
    S.H. Lee, S.S. Lee, J.-J. Choi, J. Jeon, K. Ro, Microsyst. Technol. 11, 416 (2005)CrossRefGoogle Scholar
  8. 8.
    K. Vignesh, A. Suganthi, M. Rajarajan, S. Sara, Powder Technol. 224, 331 (2012)CrossRefGoogle Scholar
  9. 9.
    L. Vayssieres, K. Keis, S.-E. Lindquist, A. Hagfeldt, J. Phys. Chem. B 105, 3350 (2001)CrossRefGoogle Scholar
  10. 10.
    Q. Li, Y. Chen, L. Luo, L. Wang, Y. Yu, L. Zhai, J. Alloys Compd. 560, 156 (2013)CrossRefGoogle Scholar
  11. 11.
    S. Muthukumar, C. Gorla, N. Emanetoglu, S. Liang, Y. Lu, J. Cryst. Growth 225, 197 (2001)CrossRefGoogle Scholar
  12. 12.
    Y. Zhang, R.E. Russo, S.S. Mao, Appl. Phys. Lett. 87, 043106 (2005)CrossRefGoogle Scholar
  13. 13.
    T. You, J. Yan, Z. Zhang, J. Li, J. Tian, J. Yun, W. Zhao, Mater. Lett. 66, 246 (2012)CrossRefGoogle Scholar
  14. 14.
    J.Y. Liang, L. Guo, H.B. Xu, L. Jing, L.X. Dong, W.Z. Hua, W.Z. Yu, J. Weber, J. Cryst. Growth 252, 226 (2003)CrossRefGoogle Scholar
  15. 15.
    D. Qian, J. Jiang, P.L. Hansen, Chem. Commun. 3, 1078 (2003)CrossRefGoogle Scholar
  16. 16.
    J.C. Lin, B.-R. Huang, T.C. Lin, Appl. Surf. Sci. 289, 384 (2014)CrossRefGoogle Scholar
  17. 17.
    M. Salavati-Niasari, N. Mir, F. Davar, J. Alloys Compd. 476, 908 (2009)CrossRefGoogle Scholar
  18. 18.
    F. Soofivand, M. Salavati-Niasari, F. Mohandes, Mater. Lett. 98, 55 (2013)CrossRefGoogle Scholar
  19. 19.
    L. Wang, C. Ma, X. Ru, Z. Guo, D. Wu, S. Zhang, G. Yu, Y. Hu, J. Wang, J. Alloys Compd. 647, 57 (2015)CrossRefGoogle Scholar
  20. 20.
    S.H. Choi, E.G. Kim, J. Park, K. An, N. Lee, S.C. Kim, T. Hyeon, J. Phys. Chem. B 109, 14792 (2005)CrossRefGoogle Scholar
  21. 21.
    M. Salavati-Niasari, F. Davar, M. Mazaheri, Mater. Lett. 62, 1890 (2008)CrossRefGoogle Scholar
  22. 22.
    J. Liu, Y. Bei, H. Wu, D. Shen, J. Gong, X. Li, Y. Wang, N. Jiang, J. Jiang, Mater. Lett. 61, 2837 (2007)CrossRefGoogle Scholar
  23. 23.
    K. Kanade, B. Kale, R. Aiyer, B. Das, Mater. Res. Bull. 41, 590 (2006)CrossRefGoogle Scholar
  24. 24.
    M. Muruganandham, J. Wu, Appl. Catal. B 80, 32 (2008)CrossRefGoogle Scholar
  25. 25.
    M. Goudarzi, N. Mir, M. Mousavi-Kamazani, S. Bagheri, M. Salavati-Niasari, Sci. Rep. 6, 32539 (2016)CrossRefGoogle Scholar
  26. 26.
    M. Mousavi-Kamazani, M. Salavati-Niasari, M. Ramezani, J. Clust. Sci. 24, 927 (2013)CrossRefGoogle Scholar
  27. 27.
    M. Goudarzi, D. Ghanbari, M. Salavati-Niasari, J. Mater. Sci. Mater. Electron. 26, 8798 (2015).CrossRefGoogle Scholar
  28. 28.
    J. Tauc, R. Grigorovici, A. Vancu, Phys. Status Solidi B 15, 627 (1966)CrossRefGoogle Scholar
  29. 29.
    M. Mousavi-Kamazani, M. Salavati-Niasari, S.M. Hosseinpour-Mashkani, M. Goudarzi, Mater. Lett. 145, 99 (2015)CrossRefGoogle Scholar
  30. 30.
    M. Mousavi-Kamazani, M. Salavati-Niasari, M. Sadeghinia, Mater. Lett. 142, 145 (2015)CrossRefGoogle Scholar
  31. 31.
    M. Panahi-Kalamuei, S. Alizadeh, M. Mousavi-Kamazani, M. Salavati-Niasari, J. Ind. Eng. Chem. 21, 1301–1305 (2015)CrossRefGoogle Scholar
  32. 32.
    M. Salavati-Niasari, S. Alizadeh, M. Mousavi-Kamazani, N. Mir, O. Rezaei, E. Ahmadi, J. Clust. Sci. 24, 1181–1191 (2013)CrossRefGoogle Scholar
  33. 33.
    M. Goudarzi, Z. Zarghami, M. Salavati-Niasari, J. Mater. Sci. Mater. Electron. 27, 9789 (2016).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  • Mojgan Goudarzi
    • 1
  • Mehdi Mousavi-Kamazani
    • 1
  • Masoud Salavati-Niasari
    • 2
  1. 1.Young Researchers and Elites Club, Arak BranchIslamic Azad UniversityArakIran
  2. 2.Institute of Nano Science and Nano TechnologyUniversity of KashanKashanIslamic Republic of Iran

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