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Effect of multiple times pre-sintering on the dielectric properties of TiO2/glass composite

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Abstract

NanoTiO2/glass composite was potential in pulse power capacitors applications. The glass addition could deduce the porosity, suppress the grain size and improve the BDS of the composite, simultaneously. In this study, the composite was densified successfully by the method of repeating the pre-sintering and ball milling procedure multiple times, which could improve the density and the breakdown strength (BDS) of the composite significantly. When the ratio of TiO2 with 15 % glass addition and the number of pre-sintering times was 4, the energy density achieved the highest energy density 1.41 J/cm3. The method was very simple and inexpensive to compatible with multilayer ceramic capacitor, comparing to sol–gel method and other methods.

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References

  1. W. Hu, Y. Liu, R.L. Withers, T.J. Frankcombe, L. Noren, A. Snashall, M. Kitchin, P. Smith, B. Gong, H. Chen, J. Schiemer, F. Brink, J. Wong-Leung, Electron-pinned defect-dipoles for high-performance colossal permittivity materials. Nat. Mater. 12(9), 821–826 (2013)

    Article  Google Scholar 

  2. N. Ortega, A. Kumar, J.F. Scott, B.C. Douglas, M. Tomazawa, K. Shalini, D.G.B. Diestra, R.S. Katiyar, Relaxor-ferroelectric superlattices: high energy density capacitors. J. Phys.: Condens. Matter 24(44), 445901 (2012)

    Google Scholar 

  3. Y. Zhang, J. Huang, T. Ma, X. Wang, C. Deng, X. Dai, Sintering temperature dependence of energy-storage properties in (Ba, Sr)TiO3 glass-ceramics. J. Am. Ceram. Soc. 94(6), 1805–1810 (2011)

    Article  Google Scholar 

  4. D.P. Shay, N.J. Podraza, N.J. Donnelly, C.A. Randall, High energy density, high temperature capacitors utilizing Mn-doped 0.8CaTiO3–0.2CaHfO3 Ceramics. J. Am. Ceram. Soc. 95(4), 1348–1355 (2012)

    Article  Google Scholar 

  5. S. Jiang, L. Zhang, G. Zhang, S. Liu, J. Yi, X. Xiong, Y. Yu, J. He, Y. Zeng, Effect of Zr:Sn ratio in the lead lanthanum zirconate stannate titanate anti-ferroelectric ceramics on energy storage properties. Ceram. Int. 39(5), 5571–5575 (2013)

    Article  Google Scholar 

  6. Q. Zhang, Y. Zhang, X. Wang, T. Ma, Z. Yuan, Influence of sintering temperature on energy storage properties of BaTiO3–(Sr1−1.5x Bi x ) TiO3 ceramics. Ceram. Int. 38(6), 4765–4770 (2012)

    Article  Google Scholar 

  7. W. Huebner, S.C. Zhang, High energy density dielectrics for symmetric blumleins. In Proceedings of the 12th IEEE International Symposium on Applications of Ferroelectrics (ISAF 2000), Honolulu, July 21–Aug 02 2000

  8. C.C. Homes, T. Vogt, S.M. Shapiro, S. Wakimoto, A.P. Ramirez, Optical response of high-dielectric-constant perovskite-related oxide. Science 293(5330), 673–676 (2001)

    Article  Google Scholar 

  9. S. Krohns, P. Lunkenheimer, S. Meissner, A. Reller, B. Gleich, A. Rathgeber, T. Gaugler, H.U. Buhl, D.C. Sinclair, A. Loidl, The route to resource-efficient novel materials. Nat. Mater. 10(12), 899–901 (2011)

    Article  Google Scholar 

  10. R. Macklin, Electrostatic energy storage. Nature 262, 171 (1976)

    Article  Google Scholar 

  11. Y. Ye, S.C. Zhang, F. Dogan, E. Schamiloglu, J. Gaudet, P. Castro, M. Roybal, M. Joler, C. Christodoulou, Influence of nanocrystalline grain size on the breakdown strength of ceramic dielectrics. In Proceedings of the 14th IEEE International Pulsed Power Conference, Dallas, 15–18 June 2003

  12. C.T. Dervos, J. Novacovich, P. Vassiliou, P. Skafidas, Novacovich, Permittivity properties of thermally treated TiO2. Mater. Lett. 58(9), 1502–1507 (2004)

    Article  Google Scholar 

  13. W. Zhang, X. Pei, J. Chen, H. He, Effects of Al doping on properties of xAl–3 % In–TiO2 photocatalyst prepared by a sol–gel method. Mater. Sci. Semicon. Process. 38, 24–30 (2015)

    Article  Google Scholar 

  14. X. Cheng, Z. Li, J. Wu, Colossal permittivity in ceramics of TiO2 Co-doped with niobium and trivalent cation. J. Mater. Chem. A 3(11), 5805–5810 (2015)

    Article  Google Scholar 

  15. G.S. Park, S.Y. Park, S. Heo, O. Kwon, K. Cho, K.Y. Han, S.J. Kang, A. Yoon, M. Kim, Origin of leakage paths driven by electric fields in Al-doped TiO2 films. Adv. Mater. 26(48), 8225–8230 (2014)

    Article  Google Scholar 

  16. J. Li, F. Li, Y. Zhuang, L. Jin, L. Wang, X. Wei, Z. Xu, S. Zhang, Microstructure and dielectric properties of (Nb + In) co-doped rutile TiO2 ceramics. J. Appl. Phys. 116(7), 074105 (2014)

    Article  Google Scholar 

  17. W. Hu, Y. Liu, R.L. Withers, T.J. Frankcombe, L. Noren, A. Snashall, M. Kitchin, P. Smith, B. Gong, H. Chen, J. Schiemer, F. Brink, J. Wong-Leung, Electron-pinned defect-dipoles for high-performance colossal permittivity materials. Nat. Mater. 12(9), 821–826 (2013)

    Article  Google Scholar 

  18. R. Vazquez-Reina, S. Chao, V. Petrovsky, F. Dogan, S. Greenbaum, Electrical and electron paramagnetic resonance spectroscopy characterization of Mn-doped nanostructured TiO2 for capacitor applications. J. Power Sources 210, 21–25 (2012)

    Article  Google Scholar 

  19. S. Chao, F. Dogan, Effects of manganese doping on the dielectric properties of titanium dioxide ceramics. J. Am. Ceram. Soc. 94(1), 179–186 (2011)

    Article  Google Scholar 

  20. C. Neusel, G.A. Schneider, Size-dependence of the dielectric breakdown strength from nano- to millimeter scale. J. Mech. Phys. Solids 63, 201–213 (2014)

    Article  Google Scholar 

  21. Q.L. Wang, O. Varghese, C.A. Grimes, E.C. Dickey, grain boundary blocking and segregation effects in yttrium-doped polycrystalline titanium dioxide. Solid State Ion. 178(3-4), 187–194 (2007)

    Article  Google Scholar 

  22. F.W. MacDougall, J.B. Ennis, R.A. Cooper, J. Bates, and K. Seal, High energy density pulsed power capacitors. In Proceedings of the 14th IEEE International Pulsed Power Conference, Dallas, 15–18 June 2003

  23. Z. Song, H. Liu, H. Hao, S. Zhang, M. Cao, Z. Yao, Z. Wang, W. Hu, Y. Shi, B. Hu, The effect of grain boundary on the energy storage properties of (Ba0.4Sr0.6 M)TiO3 paraelectric ceramics by varying grain sizes. IEEE Trans. Ultrason. Ferroelectr. Freq. Control 62(4), 609–616 (2015)

    Article  Google Scholar 

  24. C. Neusel, H. Jelitto, G.A. Schneider, Electrical conduction mechanism in bulk ceramic insulators at high voltages until dielectric breakdown. J. Appl Phys. 117(15), 154902 (2015)

    Article  Google Scholar 

Download references

Acknowledgments

This work is supported by the State Key Program of National Natural Science of China (Grant Nos. 50932002 and 51172035).

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Authors and Affiliations

  1. State Key Laboratory of Electronic Thin Films and Integrated Devices, Collaboration Innovation Center of Electric Materials and Devices, University of Electronic Science and Technology of China, Chengdu, 610054, Sichuan, China

    Meng Wei, Jihua Zhang, Jianfeng Liu, Hongwei Chen, Hetuo Chen & Chuanren Yang

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  1. Meng Wei
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  2. Jihua Zhang
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  3. Jianfeng Liu
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  4. Hongwei Chen
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  5. Hetuo Chen
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Correspondence to Jihua Zhang.

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Wei, M., Zhang, J., Liu, J. et al. Effect of multiple times pre-sintering on the dielectric properties of TiO2/glass composite. J Mater Sci: Mater Electron 28, 526–531 (2017). https://doi.org/10.1007/s10854-016-5554-6

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  • DOI: https://doi.org/10.1007/s10854-016-5554-6

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