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A facile route to preparation of Co3O4 nanoplates and investigation of their charge storage ability as electrode material for supercapacitors

  • Mustafa Aghazadeh
  • Rohollah Ahmadi
  • Davoud Gharailou
  • Mohammad Reza Ganjali
  • Parviz Norouzi
Article

Abstract

A fast, cheap and facile method was developed for the preparation of Co3O4 nanoplates at large-scale. According to this method, initially β-Co(OH)2 nanoplates were prepared through a simple, template- and additive-free electrodeposition route and then the Co3O4 nanoplates were obtained via the calcination of the hydroxide precursor at 500 °C for 3 h, under an O2 atmosphere. The products were characterized by XRD, IR, DCS-TG and SEM techniques, and electrochemical investigations by cyclic voltammetry, charge–discharge tests and EIS measurements, which confirmed the excellent supercapacitive performance of the Co3O4 nanoplates including their high contribution and electrochemical utilization in the redox reactions, reversible redox reactions, low diffusion resistance, high specific capacitance of 485 F g−1, and an 84.1 % capacity retention after 3000 cycling at the applied discharge current density of 5 A g−1.

Keywords

Specific Capacitance Co3O4 Electrochemical Impedance Spectroscopy Cyclic Voltammetric Curve Electrochemical Impedance Spectroscopy Measurement 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Mustafa Aghazadeh
    • 1
  • Rohollah Ahmadi
    • 2
  • Davoud Gharailou
    • 3
  • Mohammad Reza Ganjali
    • 3
    • 4
  • Parviz Norouzi
    • 3
  1. 1.Nuclear Science and Technology Research Institute (NSTRI)TehranIran
  2. 2.Chemistry Department, Saveh BranchIslamic Azad UniversitySavehIran
  3. 3.Center of Excellence in Electrochemistry, Faculty of ChemistryUniversity of TehranTehranIran
  4. 4.Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences InstituteTehran University of Medical SciencesTehranIran

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