Immobilization of silver nanoparticles onto the surface of Pb-based glass frit by a one-pot procedure involving polyol process and its application in conductive thick films

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Abstract

Silver nanoparticles (Ag NPs) were immobilized onto the surface of Pb-based glass frit by a fast one-pot synthetic method which only involved two reagents: AgNO3 and ethylene glycol (EG). The EG played two crucial roles in the procedure: reducing agent and reaction medium. XRD, SEM and TEM analysis revealed that Ag NPs were densely deposited onto the surface. The as-prepared composite powders were subsequently applied in conductive silver thick films. Sheet resistance was recorded by a four-point probe electrical contact method. Results showed that Ag NPs on the surface affected electrical conductivity of the films. The film from the composite powder with Ag NPs about 15 nm in diameter showed a resistance value of 5 mΩ/square as compared to 6.2 mΩ/square of that from the pure glass frit.

Keywords

Ethyl Cellulose PbO2 Glass Frit Electroless Plating Electroless Deposition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Notes

Acknowledgments

The authors gratefully acknowledge the writing guidance from Prof. Feng Zheng and help in the experiment from Hongbo Tang.

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.School of Material Science and EngineeringCentral South UniversityChangshaPeople’s Republic of China
  2. 2.College of Chemistry and Biology EngineeringYichun UniversityYichunPeople’s Republic of China

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