Synthesis and photoelectric property of poly (3-octylthiophene)/titanium dioxide nano-composite material
- 253 Downloads
- 11 Citations
Abstract
A conducting polymer composite, poly (3-octylthiophene)/titanium dioxide nano-composite was first synthesized through the ultrasonic method. The results from X-ray diffraction, X-ray photoelectron spectroscopy and infrared spectroscopy show that there is chemical interaction in the composite, which indicates that TiO2 was successfully coated by poly (3-octylthiophene) molecules. The energy gap of the poly (3-octylthiophene)/titanium dioxide composite is lower to 0.65 eV; and it also shows that the optical performance of the new material is far superior than POT or TiO2 separately, by Ultraviolet–visible spectra and fluorescence spectroscopy.
Keywords
TiO2 Thiophene Nanocomposite Film High Occupied Molecular Orbital Lower Unoccupied Molecular OrbitalNotes
Acknowledgments
The work was supported by the National High Technology Research and Development Program of China (863 Program) under Grant no. 2006AA03z412, and the Research Fund for the Doctoral Program of Higher Education (No. 20050010014).
References
- 1.R.D. McCullough, The chemistry of conducting polythiophenes. Adv. Mater. 10, 93–116 (1998)CrossRefGoogle Scholar
- 2.N. Hebestreit, J. Hofmann, U. Rammelt, W. Plieth, Physical, electrochemical characterization of nanocomposites formed from polythiophene, titanium dioxide. Electrochim. Acta 48, 1779–1788 (2003)CrossRefGoogle Scholar
- 3.C.L. Huisman, A. Goossens, J. Schoonman, Preparation of a nanostructured composite of titanium dioxide, polythiophene: a new route towards 3D heterojunction solar cells. Synth. Met. 138, 237–241 (2003)CrossRefGoogle Scholar
- 4.G.D. Sharma, P. Suresh, S.Kumar Sharma, M.S. Roy, Optical and electrical properties of hybrid photovoltaic devices from poly (3-phenyl hydrazone thiophene) (PPHT) and TiO2 blend films. Sol. Energy Mater. Sol. Cells 92(6), 1–70 (2008)Google Scholar
- 5.R. Sugimoto, S. Takeda, H.B. Gu, K. Yoshino et al., Preparation of soluble polythiophene derivatives utilizing transition metal halides as catalysts and their property. Chem. Express 1, 635–638 (1986)Google Scholar
- 6.C. Visy, G. Bencsik, Z. N’emeth, A. V’ertes, Synthesis and characterization of chemically and electrochemically prepared conducting polymer/iron oxalate composites. Electrochim. Acta 53, 3942–3947 (2008)CrossRefGoogle Scholar
- 7.J.C. Xu, W.M. Liu, H.L. Li, Titanium dioxide doped polyaniline. Mater. Sci. Eng. Biomimetic. Supramol. Syst. C 25, 444–447 (2005)MathSciNetGoogle Scholar
- 8.J.F. Moulder, W.F. Stickle, P.E. Sobol, K.D. Bomben, Handbook of X-ray Photoelectron Spectroscopy (Physical Electronics, Inc, Bellingham, 1995)Google Scholar
- 9.E.T. Kang et al., Surface modifications of poly (3-alkylthiophene) films by graft copolymerization. Macromolecules 25, 6842–6848 (1992)CrossRefADSGoogle Scholar
- 10.M.R. Karim, C.J. Lee, M.S. Lee, J. Polym. Sci. A 44, 5283 (2006)CrossRefGoogle Scholar
- 11.J.E. Mark, Polymer Data Handbook (Oxford University Press, Oxford, 1999)Google Scholar
- 12.A.O. Patil, A.J. Heeger, F. Wudl, Chem. Rev. 88, 183 (1988)CrossRefGoogle Scholar
- 13.L.G. Tong, X.G. Qian, J.Y. Wang, Funct. Mater. 33, 5 (2002)Google Scholar