Journal of Materials Science: Materials in Electronics

, Volume 20, Issue 11, pp 1073–1077

Novel nonlinear optical materials based on dihydropyridine organic chromophore deposited on mica substrate

  • T. Kolev
  • B. Koleva
  • J. Kasperczyk
  • Ivan Kityk
  • S. Tkaczyk
  • M. Spiteler
  • Ali H. Reshak
  • W. Kuznik
Article

Abstract

We have synthesized novel composites based on a 1-methyl-4-[2-(3-methoxy-4-oxocyclohexadienyliden)ethyliden]-1,4-dihydropyridine chromophore incorporated into a polymer PMMA host (weight content of 7.5%) deposited on the mica substrate. In the result of simultaneous application of external dc-electric field and thermal heating we have measured values of second order optical effect of about 122 pm/V at 1,064 nm fundamental laser wavelength. This effect show very weak reversibility after the dc-field switching off. Optical properties of the embedded compound were elucidated by means of IR–LD spectroscopy of oriented colloids in nematic host. UV-spectroscopy, 1H- and 13C-NMR methods were also used. Quantum chemical calculations have been carried out in order to describe electronic structure and optical properties.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • T. Kolev
    • 1
    • 2
  • B. Koleva
    • 3
  • J. Kasperczyk
    • 4
  • Ivan Kityk
    • 5
  • S. Tkaczyk
    • 4
  • M. Spiteler
    • 6
  • Ali H. Reshak
    • 7
    • 8
  • W. Kuznik
    • 5
  1. 1.Institute of Organic ChemistryBASSofiaBulgaria
  2. 2.Faculty of ChemistryPlovdiv UniversityPlovdivBulgaria
  3. 3.Faculty of ChemistrySofia UniversitySofiaBulgaria
  4. 4.Institute of PhysicsJ. Dlugosz UniversityCzestochowaPoland
  5. 5.Faculty of ChemistrySilesian University of TechnologyGliwicePoland
  6. 6.Institut für UmweltforschungUniversität DortmundDortmundGermany
  7. 7.Institute of Physical BiologySouth Bohemia UniversityNove HradyCzech Republic
  8. 8.Institute of System Biology and EcologyAcademy of SciencesNove HradyCzech Republic

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