Abstract
Activated carbon (AC) has been widely used in the prevention and control of air and water pollution due to its excellent adsorption ability. However, the adsorption capacity of AC for targeting organic compounds is reduced because of the competitive adsorption of water molecules. The current study proposes hydrophobic modification and regeneration of waste AC as a solution to these issues. Using waste AC as raw material, SiO2 particles were introduced to increase its surface roughness and micropores of AC. Nonpolar alkyl chain groups were grafted on the surface of AC to improve its hydrophobic performance, and high-temperature regeneration was used to increase its specific surface area. The experimental results showed that the water contact angle of AC increased from 30° (hydrophilic) to 142° (hydrophobic) after modification, and it maintained an angle of 139° even after high-temperature regeneration. The specific surface area of hydrophobic AC increased from 290 to 1075 m2 g−1 and the equilibrium adsorption capacity of hydrophobic AC for methylene blue is 425.4 mg g−1 after regeneration. AC-adsorbed methylene blue also has excellent hydrophobicity (145°) and high specific surface area (1250 m2 g−1) after being modified and regenerated by the same methods. After being exposed to air for 600 days, the modified AC still has good hydrophobicity (125°). This indicates that our method of hydrophobic modification combined with regeneration has great significance to the recovery and utilization of waste AC.
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Bradley R, Smith M, Andreu A, Falco M (2011) Surface studies of novel hydrophobic active carbons. Appl Surf Sci 257:2912–2919
Bjorklund K, Li LY (2016) Sorption of DOM and hydrophobic organic compounds onto sewage-based activated carbon. Water Sci Technol 74:852–860
Kameda T, Horikoshi K, Kumagai S, Saito Y, Yoshioka T (2020) Adsorption of urea, creatinine, and uric acid onto spherical activated carbon. Sep Purif Technol 237:116367
Wang W, Deng S, Li D, Ren L, Shan D, Wang B, Huang J, Wang Y, Yu G (2017) Sorption behavior and mechanism of organophosphate flame retardants on activated carbons. Chem Eng J 332:286–292
You Y, Liu X (2019) Modeling of CO2 adsorption and recovery from wet flue gas by using activated carbon. Chem Eng J 369:672–685
Aslan M, Zeiger M, Jackel N, Grobelsek I, Weingarth D, Presser V (2016) Improved capacitive deionization performance of mixed hydrophobic/hydrophilic activated carbon electrodes. J Phys Condens Matter 28:114003
Zhao L, Wu C, Lu X, Ng D, Truong Y, Xie Z (2018) Activated carbon enhanced hydrophobic/hydrophilic dual-layer nanofiber composite membranes for high-performance direct contact membrane distillation. Desalination 446:59–69
Coleman S, Coronado P, Maxwell R, Reynolds J (2003) Granulated activated carbon modified with hydrophobic silica aerogel-potential composite materials for the removal of uranium from aqueous solutions. Environ Sci Technol 37:2286–2290
Liu Y, Gu Y, Hou Y, Yang Y, Deng S, Wei Z (2015) Hydrophobic activated carbon supported Ni-based acid-resistant catalyst for selective hydrogenation of phthalic anhydride to phthalide. Chem Eng J 275:271–280
Om Prakash M, Gujjala R, Panchal M, Ojha S (2020) Mechanical characterization of arhar biomass based porous nano activated carbon polymer composites. Polym Composite 41:3113–3123
Jaseela PK, Garvasis J, Joseph A (2019) Selective adsorption of methylene blue (MB) dye from aqueous mixture of MB and methyl orange (MO) using mesoporous titania (TiO2)-poly vinyl alcohol (PVA) nanocomposite. J Mol Liq 286:110908
Mechi N, Khemis IB, Dotto GL, Franco D, Sellaoui L, Lamine AB (2019) Investigation of the adsorption mechanism of methylene blue (MB) on Cortaderia selloana flower spikes (FSs) and on C. selloana flower spikes derived carbon fibers (CFs). J Mol Liq 280:268–273
Liu Z, Chen G, Hua F, Li X (2020) Synthesis of mesoporous magnetic MnFe2O4@CS-SiO2 microsphere and its adsorption performance of Zn2+ and MB studies. J Environ Manage 263:110377
Qiu J, Feng Y, Zhang X, Jia M, Yao J (2017) Acid-promoted synthesis of UiO-66 for highly selective adsorption of anionic dyes: adsorption performance and mechanisms. J Coll Interf Sci 499:151–158
Dizge N, Aydiner C, Demirbas E, Kobya M, Kara S (2008) Adsorption of reactive dyes from aqueous solutions by fly ash: kinetic and equilibrium studies. J Hazard Mater 150:737–746
Ravikumar K, Krishnan S, Ramalingam S, Balu K (2007) Optimization of process variables by the application of response surface methodology for dye removal using a novel adsorbent. Dyes Pigments 72:66–74
Muthukumar M, Sargunamani D, Selvakumar N (2005) Statistical analysis of the effect of aromatic, azo and sulphonic acid groups on decolouration of acid dye effluents using advanced oxidation processes. Dyes Pigments 65:151–158
Pereira MFR, Soares SF, Órfão JJ, Figueiredo JL (2003) Adsorption of dyes on activated carbons: influence of surface chemical groups. Carbon 41:811–821
Qiao X, Hu F, Tian F, Hou D, Li D (2016) Equilibrium and kinetic studies on MB adsorption by ultrathin 2D MoS2 nanosheets. RSC Adv 6:11631
Kaur H, Bansiwal A, Hippargi G, Pophali GR (2017) Effect of hydrophobicity of pharmaceuticals and personal care products for adsorption on activated carbon: adsorption isotherms, kinetics and mechanism. Environ Sci Pollut Res 25:20473–20485
Li Z, Jin Y, Chen T, Tang F, Cai J, Ma J (2021) Trimethylchlorosilane modified activated carbon for the adsorption of VOCs at high humidity. Sep Purif Technol 272:118659
Ding H, Zhu Y, Wu Y, Zhang J, Deng H, Zheng H, Liu Z, Zhao C (2020) In situ regeneration of phenol-saturated activated carbon fiber by an electro-peroxymonosulfate process. Environ Sci Technol 54:10944–10953
Yagmur E, Turkoglu S, Banford A, Aktas Z (2017) The relative performance of microwave regenerated activated carbons on the removal of phenolic pollutants. J Clean Prod 149:1109–1117
Sun Z, Wang M, Fan J, Zhou Y, Zhang L (2020) Regeneration performance of activated carbon for desulfurization. Appl Sci 10:6107
Li L, Liu S, Liu J (2011) Surface modification of coconut shell based activated carbon for the improvement of hydrophobic VOC removal. J Hazard Mater 192:683–690
Li X, Zhang L, Yang Z, He Z, Ran J (2020) Hydrophobic modified activated carbon using PDMS for the adsorption of VOCs in humid condition. Sep Purif Technol 239:116517
Oz M, Lorke DE, Petroianu GA (2009) Methylene blue and Alzheimer’s disease. Biochem Pharmacol 78:927–932
Shah-Khan MG, Lovely J, Degnim AC (2012) Safety of methylene blue dye for lymphatic mapping in patients taking selective serotonin reuptake inhibitors. Am J Surg 204:798–799
Radhi MM, Jaffar Al-Mulla EA, Hoiwdy WH (2012) Effect of temperature on frying oils: infrared spectroscopic studies. Res Chem Intermed 39:3173–3179
Zhu X, Wang D, Ni Y, Wang J, Nie C, Yang C, Lu X, Qiu J, Li L (2020) Cleaner approach to fine coal flotation by renewable collectors prepared by waste oil transesterification. J. Clean. Prod. 252:119822
Badii K, Church JS, Golkarnarenji G, Naebe M, Khayyam H (2016) Chemical structure based prediction of PAN and oxidized PAN fiber density through a non-linear mathematical model. Polym Degrad Stabil 131:53–61
Rodríguez-Hermida S, Tsang MY, Vignatti C, Stylianou KC, Guillerm V, Pérez-Carvajal J, Teixidor F, Viñas C (2016) Switchable surface hydrophobicity-hydrophilicity of a metal-organic framework. Angew Chem Int Ed 55:16049–16053
Huang G, Yang Q, Xu Q, Yu S, Jiang H (2016) Polydimethylsiloxane coating for a palladium MOF composite: highly improved catalytic performance by surface hydrophobization. Angew Chem Int Ed 55:7379–7383
Peng C, Chen Z, Tiwari MK (2018) All-organic superhydrophobic coatings with mechanochemical robustness and liquid impalement resistance. Nat Mater 17:355–360
Schute K, Louven Y, Detoni C, Rose M (2016) selective liquid phase adsorption of biogenic HMF on hydrophobic spherical activated carbons. Chem Ing Tech 88:355–362
Ono Y, Futamura R, Hattori Y, Sakai T, Kaneko K (2017) Adsorption-desorption mediated separation of low concentrated D2O from water with hydrophobic activated carbon fiber. J Coll Interface Sci 508:14–17
Mu´ller E.A., Gubbins K.E, (1998) Molecular simulation study of hydrophilic and hydrophobic behavior of activated carbon surfaces. Carbon 36:1433–1438
Gonçalves M, Molina-Sabio M, Rodriguez-Reinoso F (2010) Adsorption of non-ionic surfactants on hydrophobic and hydrophilic carbon surfaces. J Anal Appl Pyrolysis 89:17–21
Zou X, Zhang H, Chen T, Li H, Meng C, Xia Y, Guo J (2019) Preparation and characterization of polyacrylamide/sodium alginate microspheres and its adsorption of MB dye. Colloids Surf A 567:184–192
Li W, Wei H, Liu Y, Li S, Wang G, Han H (2021) Fabrication of novel starch-based composite hydrogel microspheres combining Diels-Alder reaction with spray drying for MB adsorption. J Environ Chem Eng 9:105929
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Li, W., Zhang, Q., Zhang, J. et al. Fabrication of hydrophobic regenerated activated carbon with high specific surface area. J Mater Sci 56, 19969–19982 (2021). https://doi.org/10.1007/s10853-021-06525-6
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DOI: https://doi.org/10.1007/s10853-021-06525-6