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Electrospun cyclodextrin nanofibers as precursor for carbon nanofibers

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Abstract

The carbon nanofibers (CNF) based on the electrospun polymer-free hydroxypropyl-β-cyclodextrin (HPβCD) nanofibers were obtained by the combination of chemical and thermal (pyrolysis) treatment. The thermal and chemical decomposition of HPβCD makes it challenging to obtain persistent CNF from HPβCD nanofibers. The chemical treatment of HPβCD nanofibers by using 0.6 mM H2SO4 partially dissolves nanofibers and resulted in fused CNF while direct pyrolysis of HPβCD nanofibers totally ruins the nanofiber structure and produces char. The partial chemical treatment of HPβCD nanofibers with 10 µM H2SO4 dehydrates the top layer of the nanofibers, and a shield-like structure is formed which helps to retain the fibrous morphology during the pyrolysis. The diameter of HPβCD nanofibers was reduced after carbonization process where CNF having average diameter of 380 ± 150 nm were obtained. The presence of typical D and G Raman bands and XRD peak at 2θ ~ 26° further validates CNF formation from HPβCD nanofibers. The oxygen content is decreased from 34.7 to 5.8%, and carbon content increased from 62.3% to 94.2% after transformation of HPβCD nanofibers into CNF. To the best of our knowledge, for the first time, this study reports the use of electrospun polymer-free HPβCD nanofibers as a precursor to produce CNF.

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References

  1. 1

    Hirsch A (2010) The era of carbon allotropes. Nat Mater 9:868–871

  2. 2

    Sharon M, Mishra N, Patil B, Mewada A, Gurung R, Sharon M (2015) Conversion of polypropylene to two-dimensional graphene, one-dimensional carbon nano tubes and zero-dimensional C-dots, all exhibiting typical sp2-hexagonal carbon rings. IET Circuits Devices Syst 9:59–66

  3. 3

    Maniecki T, Shtyka O, Mierczynski P, Ciesielski R, Czylkowska A, Leyko J et al (2018) Carbon nanotubes: properties, synthesis, and application. Fibre Chem 50:297–300

  4. 4

    Castro Neto AH, Guinea F, Peres NMR, Novoselov KS, Geim AK (2009) The electronic properties of graphene. Rev Mod Phys 81:109–162

  5. 5

    Brozena AH, Kim M, Powell LR, Wang Y (2019) Controlling the optical properties of carbon nanotubes with organic colour-centre quantum defects. Rev. Chem, Nat. https://doi.org/10.1038/s41570-019-0103-5

  6. 6

    Balandin AA (2011) Thermal properties of graphene and nanostructured carbon materials. Nat Mater 10:569–581

  7. 7

    Goze C, Vaccarini L, Henrard L, Bernier P, Hernandez E, Rubio A (1999) Elastic and mechanical properties of carbon nanotubes. Synth Met 103:2500–2501

  8. 8

    Candelaria SL, Shao Y, Zhou W, Li X, Xiao J, Zhanget JG et al (2012) Nanostructured carbon for energy storage and conversion. Nano Energy 1:195–220

  9. 9

    Pech D, Brunet M, Durou H, Huang P, Mochalin V, Gogotsi Y et al (2010) Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. Nat Nanotechnol 5:651–654

  10. 10

    Qureshi A, Kang WP, Davidson JL, Gurbuz Y (2009) Review on carbon-derived, solid-state, micro and nano sensors for electrochemical sensing applications. Diam Relat Mater 18:1401–1420

  11. 11

    Yang W, Thordarson P, Gooding JJ, Ringer SP, Braet F (2007) Carbon nanotubes for biological and biomedical applications. Nanotechnology 18:1–12

  12. 12

    Street KW, Miyoshi K, Vander Wal RL (2007) Application of carbon based nano-materials to aeronautics and space lubrication. In: Erdemir A, Martin J-M (eds) Superlubricity. Elsevier, Amsterdam, pp 311–340

  13. 13

    Mauter MS, Elimelech M (2008) Critical review environmental applications of carbon-based nanomaterials. Am Chem Soc 42:5843–5859

  14. 14

    Huang X (2009) Fabrication and properties of carbon fibers. Materials (Basel) 2:2369–2403

  15. 15

    Newcomb BA (2016) Processing, structure, and properties of carbon fibers. Compos Part A 91:262–282

  16. 16

    Zhang D, Bhat GS (1994) Carbon fibers from polyethylene-based precursors. Mater Manuf Process 9:221–235

  17. 17

    Stanzione J, La Scala J (2016) Sustainable polymers and polymer science: dedicated to the life and work of Richard P. Wool. J Appl Polym Sci 133:1–2

  18. 18

    Hiremath N, Mays J, Bhat G (2017) Recent developments in carbon fibers and carbon nanotube-based fibers: a review. Polym Rev 57:339–368

  19. 19

    Uyar T, Kny E (2017) Electrospun materials for tissue engineering and biomedical applications: research, design and commercialization, Woodhead Publishing Series in Biomaterials, 1st edn. Elsevier, London

  20. 20

    Khalily MA, Patil B, Yilmaz E, Uyar T (2019) Atomic layer deposition of Co3O4 nanocrystals on N-doped electrospun carbon nanofibers for oxygen reduction and oxygen evolution reactions. Nanoscale Adv 1:1224–1231

  21. 21

    Yang Y, Centrone A, Chen L, Simeon F, Alan Hatton T, Rutledge GC (2011) Highly porous electrospun polyvinylidene fluoride (PVDF)-based carbon fiber. Carbon 49:3395–3403

  22. 22

    Patil B, Satilmis B, Khalily MA, Uyar T (2019) Atomic layer deposition of NiOOH/Ni(OH)2 on PIM-1-based N-doped carbon nanofibers for electrochemical water splitting in alkaline medium. Chemsuschem 12:1469–1477

  23. 23

    Ruiz-Rosas R, Bedia J, Lallave M, Loscertales IG, Barrero A, Rodríguez-Mirasol J et al (2010) The production of submicron diameter carbon fibers by the electrospinning of lignin. Carbon 48:696–705

  24. 24

    Zhang B, Kang F, Tarascon JM, Kim JK (2016) Recent advances in electrospun carbon nanofibers and their application in electrochemical energy storage. Prog Mater Sci 76:319–380

  25. 25

    Kumar M, Hietala M, Oksman K (2019) Lignin-based electrospun carbon nanofibers. Front Mater 6:1–6

  26. 26

    Szejtli J (1998) Introduction and general overview of cyclodextrin chemistry. Chem Rev 98:1743–1754

  27. 27

    Szente L (2002) Highly soluble cyclodextrin derivatives: chemistry, properties, and trends in development. Adv Drug Deliv Rev 36:17–28

  28. 28

    Topuz F, Uyar T (2018) Influence of hydrogen-bonding additives on electrospinning of cyclodextrin nanofibers. ACS Omega 3:18311–18322

  29. 29

    Manasco JL, Saquing CD, Tang C, Khan SA (2012) Cyclodextrin fibers via polymer-free electrospinning. RSC Adv 2:3778–3784

  30. 30

    Celebioglu A, Uyar T (2012) Electrospinning of nanofibers from non-polymeric systems: polymer-free nanofibers from cyclodextrin derivatives. Nanoscale 4:621–631

  31. 31

    Celebioglu A, Uyar T (2019) Electrospinning of cyclodextrins: hydroxypropyl-alpha-cyclodextrin nanofibers. J Mater Sci. https://doi.org/10.1007/s10853-019-03983-x

  32. 32

    Celebioglu A, Uyar T (2010) Cyclodextrin nanofibers by electrospinning. Chem Commun 46:6903–6905

  33. 33

    Vass P, Démuth B, Farkas A, Hirsch E, Szabó E, Nagyi B et al (2019) Continuous alternative to freeze drying: manufacturing of cyclodextrin-based reconstitution powder from aqueous solution using scaled-up electrospinning. J Control Release 298:120–127

  34. 34

    Yıldız ZI, Uyar T (2019) Fast-dissolving electrospun nanofibrous films of paracetamol/cyclodextrin inclusion complexes. Appl Surf Sci 492:626–633

  35. 35

    Yıldız ZI, Celebioglu A, Uyar T (2017) Polymer-free electrospun nanofibers from sulfobutyl ether7-beta-cyclodextrin (SBE7-β-CD) inclusion complex with sulfisoxazole fast-dissolving and enhanced water-solubility of sulfisoxazole. Int J Pharm 531:550–558

  36. 36

    Kida T, Sato S, Yoshida H, Teragaki A, Akashi M (2014) 1,1,1,3,3,3-Hexafluoro-2-propanol (HFIP) as a novel and effective solvent to facilely prepare cyclodextrin-assembled materials. Chem Commun 50:14245–14248

  37. 37

    Celebioglu A, Uyar T (2013) Electrospinning of nanofibers from non-polymeric systems: electrospun nanofibers from native cyclodextrins. J Colloid Interface Sci 404:1–7

  38. 38

    Ahn Y, Kang Y, Ku M, Yang Y-H, Jung S, Kim H (2013) Preparation of β-cyclodextrin fiber using electrospinning. RSC Adv 3:14983–14987

  39. 39

    Online VA (2013) Electrospun gamma-cyclodextrin (γ-CD) nanofibers for the entrapment of volatile organic compounds. RSC Adv 1:22891–22895

  40. 40

    Jaouadi M, Hbaieb S, Guedidi H, Reinert L, Amdouni N, Duclaux L (2017) Preparation and characterization of carbons from β-cyclodextrin dehydration and from olive pomace activation and their application for boron adsorption. J Saudi Chem Soc 21:822–829

  41. 41

    Trotta F, Zanetti M, Camino G (2000) Thermal degradation of cyclodextrins. Polym Degrad Stab 69:373–379

  42. 42

    Zhu C, Krumm C, Facas GG, Neurock M, Dauenhauer PJ (2017) Energetics of cellulose and cyclodextrin glycosidic bond cleavage. React Chem Eng 2:201–214

  43. 43

    Zanetti M, Anceschi A, Magnacca G, Spezzati G, Caldera F, Rosi GP et al (2016) Micro porous carbon spheres from cyclodextrin nanosponges. Microporous Mesoporous Mater 235:178–184

  44. 44

    Cecone C, Zanetti M, Anceschi A, Caldera F, Trotta F, Bracco P (2019) Microfibers of microporous carbon obtained from the pyrolysis of electrospun β-cyclodextrin pyromellitic dianhydride nanosponges. Polym Degrad Stab 161:277–282

  45. 45

    Celebioglu A, Topuz F, Yildiz ZI, Uyar T (2019) One-step green synthesis of antibacterial silver nanoparticles embedded in electrospun cyclodextrin nanofibers. Carbohydr Polym 207:471–479

  46. 46

    Yang X, Ke W, Zi P, Liu F, Yu L (2008) Detecting and identifying the complexation of nimodipine with hydroxypropyl-β-cyclodextrin present in tablets by Raman spectroscopy. J Pharm Sci 97:2702–2719

  47. 47

    Ferrari AC, Robertson J (2000) Interpretation of Raman spectra of disordered and amorphous carbon. Phys Rev B 61:14095–14107

  48. 48

    Yang Z, Ji H (2013) 2-Hydroxypropyl-β-cyclodextrin polymer as a mimetic enzyme for mediated synthesis of benzaldehyde in water. ACS Sustain Chem Eng 1:1172–1179

  49. 49

    Uyar T, Havelund R, Nur Y, Hacaloglu J, Besenbacher F, Kingshott P (2009) Molecular filters based on cyclodextrin functionalized electrospun fibers. J Membr Sci 332:129–137

  50. 50

    Wu HC, Li YY, Sakoda A (2010) Synthesis and hydrogen storage capacity of exfoliated turbostratic carbon nanofibers. Int J Hydrogen Energy 35:4123–4130

  51. 51

    Jung I, Dikin D, Park S, Cai W, Mielke SL, Ruoff RS (2008) Effect of water vapor on electrical properties of individual reduced graphene oxide sheets. J Phys Chem C 112:20264–20268

  52. 52

    Mettler MS, Mushrif SH, Paulsen AD, Javadekar AD, Vlachos DG, Dauenhauer PJ (2012) Revealing pyrolysis chemistry for biofuels production: conversion of cellulose to furans and small oxygenates. Energy Environ Sci 5:5414–5424

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Correspondence to Bhushan Patil or Tamer Uyar.

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Patil, B., Yildiz, Z.I. & Uyar, T. Electrospun cyclodextrin nanofibers as precursor for carbon nanofibers. J Mater Sci 55, 5655–5666 (2020). https://doi.org/10.1007/s10853-020-04374-3

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