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Journal of Materials Science

, Volume 55, Issue 11, pp 4592–4606 | Cite as

Remarkable catalytic degradation of malachite green by zinc supported on hydroxyapatite encapsulated magnesium ferrite (Zn/HAP/MgFe2O4) magnetic novel nanocomposite

  • Krishna Ch. DasEmail author
  • Siddhartha S. Dhar
Chemical routes to materials

Abstract

The present study reports the synthesis, characterization and catalytic activity of zinc/hydroxyapatite/magnesium ferrite (Zn/HAP/MgFe2O4) as a novel nanocomposite. The nanocomposite was characterized by powder XRD, FTIR, SEM–EDX, TEM, VSM and XPS. The presence of Zn(0) and Zn(II) in the Zn/HAP/MgFe2O4 was confirmed by XPS studies. The composite was applied as a heterogeneous catalyst for the degradation of malachite green in the presence as well as in the absence of H2O2. In the presence of the oxidant H2O2, 100% degradation was achieved in just 2 min while in the absence of H2O2 it took almost 2 h for complete degradation. The enhancement in the rate of the degradation of the dye in the presence of H2O2 was due to fenton and fenton-like mechanism involving the formation of reactive oxygen species, such as hydroxyl and perhydroxyl radicals (HO· and HOO·). The Zn/HAP/MgFe2O4 showed high stability and because of its super-paramagnetic behaviour it could be easily separated by external magnet from the reaction mixture. Kinetic studies showed that the degradation of the dye follows first order.

Notes

Acknowledgements

The authors are highly grateful to the Department of Chemistry, NIT, Silchar and G. C. College, Silchar, Assam, India, for providing infrastructure to carry out the research work. The authors would also like to offer their sincere thanks to CIF, NIT, Silchar, Assam; STIC, Cochin, Kerala; SAIC, Tezpur University, Assam and IIT, Guwahati and IIT Roorkee for providing analytical facilities.

References

  1. 1.
    Khataee A, Gholami P, Vahid B (2016) Heterogeneous sono-Fenton-like process using nanostructured pyrite prepared by Ar glow discharge plasma for treatment of a textile dye. Ultrason Sonochem 29:213–225.  https://doi.org/10.1016/j.ultsonch.2015.09.012 CrossRefGoogle Scholar
  2. 2.
    Fazal T, Mushtaq A, Rehman F et al (2018) Bioremediation of textile wastewater and successive biodiesel production using microalgae. Renew Sustain Energy Rev 82:3107–3126.  https://doi.org/10.1016/j.rser.2017.10.029 CrossRefGoogle Scholar
  3. 3.
    Srivastava S, Sinha R, Roy D (2004) Toxicological effects of malachite green. Aquat Toxicol 66:319–329.  https://doi.org/10.1016/j.aquatox.2003.09.008 CrossRefGoogle Scholar
  4. 4.
    Cheng W, Wang S, Lu L et al (2008) Removal of malachite green (MG) from aqueous solutions by native and heat-treated anaerobic granular sludge. Biochem Eng J 39:538–546.  https://doi.org/10.1016/j.bej.2007.10.016 CrossRefGoogle Scholar
  5. 5.
    Meena S, Vaya D, Das B (2016) Photocatalytic degradation of Malachite Green dye by modified ZnO nanomaterial. Bull Mater Sci 39:1735–1743.  https://doi.org/10.1007/s12034-016-1318-4 CrossRefGoogle Scholar
  6. 6.
    Rao K (1995) Inhibition of DNA synthesis in primary rat hepatocyte cultures by malachite green: a new liver tumor promoter. Toxicol Lett 81:107–113.  https://doi.org/10.1016/0378-4274(95)03413-7 CrossRefGoogle Scholar
  7. 7.
    Alderman D, Clifton-Hadley R (1993) Malachite green: a pharmacokinetic study in rainbow trout, Oncorhynchus mykiss (Walbaum). J Fish Dis 16:297–311.  https://doi.org/10.1111/j.1365-2761.1993.tb00864.x CrossRefGoogle Scholar
  8. 8.
    Vergis B, Hari Krishna R, Kottam N et al (2017) Removal of malachite green from aqueous solution by magnetic CuFe2O4 nano-adsorbent synthesized by one pot solution combustion method. J Nanostruct Chem 8:1–12.  https://doi.org/10.1007/s40097-017-0249-y CrossRefGoogle Scholar
  9. 9.
    Tolia J, Chakraborty M, Murthy Z (2012) Photocatalytic degradation of malachite green dye using doped and undoped ZnS nanoparticles. Pol J Chem Technol.  https://doi.org/10.2478/v10026-012-0065-6 CrossRefGoogle Scholar
  10. 10.
    Gupta V, Jain R, Varshney S (2007) Electrochemical removal of the hazardous dye Reactofix Red 3 BFN from industrial effluents. J Colloid Interface Sci 312:292–296.  https://doi.org/10.1016/j.jcis.2007.03.054 CrossRefGoogle Scholar
  11. 11.
    Li J, Li M, Li J, Sun H (2007) Removal of disperse blue 2BLN from aqueous solution by combination of ultrasound and exfoliated graphite. Ultrason Sonochem 14:62–66.  https://doi.org/10.1016/j.ultsonch.2006.01.006 CrossRefGoogle Scholar
  12. 12.
    Li J, Li M, Li J, Sun H (2007) Decolorization of azo dye direct scarlet 4BS solution using exfoliated graphite under ultrasonic irradiation. Ultrason Sonochem 14:241–245.  https://doi.org/10.1016/j.ultsonch.2006.04.005 CrossRefGoogle Scholar
  13. 13.
    Gómez-Pastora J, Bringas E, Ortiz I (2014) Recent progress and future challenges on the use of high performance magnetic nano-adsorbents in environmental applications. Chem Eng J 256:187–204.  https://doi.org/10.1016/j.cej.2014.06.119 CrossRefGoogle Scholar
  14. 14.
    Wojnárovits L, Pálfi T, Takács E (2007) Kinetics and mechanism of azo dye destruction in advanced oxidation processes. Radiat Phys Chem 76:1497–1501.  https://doi.org/10.1016/j.radphyschem.2007.02.060 CrossRefGoogle Scholar
  15. 15.
    Prado A, Costa L (2009) Photocatalytic decouloration of malachite green dye by application of TiO2 nanotubes. J Hazard Mater 169:297–301.  https://doi.org/10.1016/j.jhazmat.2009.03.076 CrossRefGoogle Scholar
  16. 16.
    Iram M, Guo C, Guan Y et al (2010) Adsorption and magnetic removal of neutral red dye from aqueous solution using Fe3O4 hollow nanospheres. J Hazard Mater 181:1039–1050.  https://doi.org/10.1016/j.jhazmat.2010.05.119 CrossRefGoogle Scholar
  17. 17.
    Hashemian S, Salimi M (2012) Nano composite a potential low cost adsorbent for removal of cyanine acid. Chem Eng J 188:57–63.  https://doi.org/10.1016/j.cej.2012.02.008 CrossRefGoogle Scholar
  18. 18.
    Ozmen M, Can K, Arslan G et al (2010) Adsorption of Cu(II) from aqueous solution by using modified Fe3O4 magnetic nanoparticles. Desalination 254:162–169.  https://doi.org/10.1016/j.desal.2009.11.043 CrossRefGoogle Scholar
  19. 19.
    Hema E, Manikandan A, Karthika P et al (2015) A Novel Synthesis of Zn2+-Doped CoFe2O4 spinel nanoparticles: structural, morphological, opto-magnetic and catalytic properties. J Supercond Novel Magn 28:2539–2552.  https://doi.org/10.1007/s10948-015-3054-1 CrossRefGoogle Scholar
  20. 20.
    Jayasree S, Manikandan A, Mohideen A et al (2015) Comparative study of combustion methods, opto-magnetic and catalytic properties of spinel CoAl2O4 nano- and microstructures. Adv Sci Eng Med 7:672–682.  https://doi.org/10.1166/asem.2015.1750 CrossRefGoogle Scholar
  21. 21.
    Mary Jacintha A, Manikandan A, Chinnaraj K et al (2015) Comparative Studies of Spinel MnFe <SUB> 2</SUB> O<SUB> 4</SUB> Nanostructures: structural, morphological, optical, magnetic and catalytic properties. J Nanosci Nanotechnol 15:9732–9740.  https://doi.org/10.1166/jnn.2015.10343 CrossRefGoogle Scholar
  22. 22.
    Raj K, Moskowitz B, Casciari R (1995) Advances in ferrofluid technology. J Magn Magn Mater 149:174–180.  https://doi.org/10.1016/0304-8853(95)00365-7 CrossRefGoogle Scholar
  23. 23.
    Kefeni K, Mamba B, Msagati T (2017) Application of spinel ferrite nanoparticles in water and wastewater treatment: a review. Sep Purif Technol 188:399–422.  https://doi.org/10.1016/j.seppur.2017.07.015 CrossRefGoogle Scholar
  24. 24.
    Radoń A, Łoński S, Warski T et al (2019) Catalytic activity of non-spherical shaped magnetite nanoparticles in degradation of Sudan I, Rhodamine B and Methylene Blue dyes. Appl Surf Sci 487:1018–1025.  https://doi.org/10.1016/j.apsusc.2019.05.091 CrossRefGoogle Scholar
  25. 25.
    Safavi A, Momeni S (2012) Highly efficient degradation of azo dyes by palladium/hydroxyapatite/Fe3O4 nanocatalyst. J Hazard Mater 201–202:125–131.  https://doi.org/10.1016/j.jhazmat.2011.11.048 CrossRefGoogle Scholar
  26. 26.
    Zarei Z, Akhlaghinia B (2016) Zn(ii) anchored onto the magnetic natural hydroxyapatite (ZnII/HAP/Fe3O4): as a novel, green and recyclable catalyst for A3-coupling reaction towards propargylamine synthesis under solvent-free conditions. RSC Advances 6:106473–106484.  https://doi.org/10.1039/c6ra20501a CrossRefGoogle Scholar
  27. 27.
    Moeinpour F, Khojastehnezhad A (2015) Cesium carbonate supported on hydroxyapatite coated Ni0.5Zn0.5Fe2O4 magnetic nanoparticles as an efficient and green catalyst for the synthesis of pyrano[2,3-c]pyrazoles. Chin Chem Lett 26:575–579.  https://doi.org/10.1016/j.cclet.2015.01.033 CrossRefGoogle Scholar
  28. 28.
    Rezayati S, Abbasi Z, Nezhad E et al (2016) Three-component synthesis of pyrano[2,3-d]pyrimidinone derivatives catalyzed by Ni2+ supported on hydroxyapatite-core–shell-γ-Fe2O3 nanoparticles in aqueous medium. Res Chem Intermed 42:7597–7609.  https://doi.org/10.1007/s11164-016-2555-2 CrossRefGoogle Scholar
  29. 29.
    Jeseentharani V, George M, Jeyaraj B et al (2013) Synthesis of metal ferrite (MFe2O4, M = Co, Cu, Mg, Ni, Zn) nanoparticles as humidity sensor materials. J Exp Nanosci 8:358–370.  https://doi.org/10.1080/17458080.2012.690893 CrossRefGoogle Scholar
  30. 30.
    Alexander L, Klug H (1950) Determination of crystallite size with the X-ray spectrometer. J Appl Phys 21:137–142.  https://doi.org/10.1063/1.1699612 CrossRefGoogle Scholar
  31. 31.
    Klug H, Alexander L (1974) X-ray diffraction procedures for polycrystalline and amorphous materials. Wiley, New YorkGoogle Scholar
  32. 32.
    Lassoued A, Lassoued M, Dkhil B et al (2018) Photocatalytic degradation of methyl orange dye by NiFe2O4 nanoparticles under visible irradiation: effect of varying the synthesis temperature. J Mater Sci Mater Electron 29:7057–7067.  https://doi.org/10.1007/s10854-018-8693-0 CrossRefGoogle Scholar
  33. 33.
    Pradeep A, Priyadharsini P, Chandrasekaran G (2008) Sol–gel route of synthesis of nanoparticles of MgFe2O4 and XRD, FTIR and VSM study. J Magn Magn Mater 320:2774–2779.  https://doi.org/10.1016/j.jmmm.2008.06.012 CrossRefGoogle Scholar
  34. 34.
    Mathubala G, Manikandan A, Arul Antony S, Ramar P (2016) Photocatalytic degradation of methylene blue dye and magneto-optical studies of magnetically recyclable spinel NixMn1−xFe2O4 (x = 0.0–1.0) nanoparticles. J Mol Struct 1113:79–87.  https://doi.org/10.1016/j.molstruc.2016.02.032 CrossRefGoogle Scholar
  35. 35.
    Foroughi F, Hassanzadeh-Tabrizi S, Amighian J (2015) Microemulsion synthesis and magnetic properties of hydroxyapatite-encapsulated nano CoFe2O4. J Magn Magn Mater 382:182–187.  https://doi.org/10.1016/j.jmmm.2015.01.075 CrossRefGoogle Scholar
  36. 36.
    Al-Najar B, Khezami L, Judith Vijaya J et al (2016) Effect of synthesis route on the uptake of Ni and Cd by MgFe2O4 nanopowders. Appl Phys A.  https://doi.org/10.1007/s00339-016-0710-7 CrossRefGoogle Scholar
  37. 37.
    Foroughi F, Hassanzadeh-Tabrizi S, Bigham A (2016) In situ microemulsion synthesis of hydroxyapatite-MgFe2O4 nanocomposite as a magnetic drug delivery system. Mater Sci Eng C 68:774–779.  https://doi.org/10.1016/j.msec.2016.07.028 CrossRefGoogle Scholar
  38. 38.
    Petrović S, Kirilov-Stefanov P, Karanović L et al (2004) Mechanochemical activation in synthesis of LaTi 0.5Mg0.5O3 perovskite-type oxides. Mater Sci Forum 453–454:417–422.  https://doi.org/10.4028/www.scientific.net/msf.453-454.417 CrossRefGoogle Scholar
  39. 39.
    Yan W, Bian W, Jin C et al (2015) An efficient Bi-functional electrocatalyst based on strongly coupled CoFe2O4/carbon nanotubes hybrid for oxygen reduction and oxygen evolution. Electrochim Acta 177:65–72.  https://doi.org/10.1016/j.electacta.2015.02.044 CrossRefGoogle Scholar
  40. 40.
    Wang Y, Zhang L, Li H et al (2014) Solid state synthesis of Fe2P nanoparticles as high-performance anode materials for nickel-based rechargeable batteries. J Power Sour 253:360–365.  https://doi.org/10.1016/j.jpowsour.2013.12.056 CrossRefGoogle Scholar
  41. 41.
    Negrila C, Predoi M, Iconaru S, Predoi D (2018) Development of zinc-doped hydroxyapatite by sol–gel method for medical applications. Molecules 23:2986–3000.  https://doi.org/10.3390/molecules23112986 CrossRefGoogle Scholar
  42. 42.
    Liu S, Bian W, Yang Z et al (2014) A facile synthesis of CoFe2O4/biocarbon nanocomposites as efficient bi-functional electrocatalysts for the oxygen reduction and oxygen evolution reaction. J Mater Chem A 2:18012–18017.  https://doi.org/10.1039/c4ta04115a CrossRefGoogle Scholar
  43. 43.
    NuLi Y, Chu Y, Qin Q (2004) Nanocrystalline ZnFe2O4 and Ag-Doped ZnFe2O4 films used as new anode materials for li-ion batteries. J Electrochem Soc 151:A1077–A1083.  https://doi.org/10.1149/1.1760576 CrossRefGoogle Scholar
  44. 44.
    Feliu S, Barranco V (2003) XPS study of the surface chemistry of conventional hot-dip galvanised pure Zn, galvanneal and Zn–Al alloy coatings on steel. Acta Mater 51:5413–5424.  https://doi.org/10.1016/s1359-6454(03)00408-7 CrossRefGoogle Scholar
  45. 45.
    Nonkumwong J, Ananta S, Jantaratana P et al (2015) Phase formation, morphology and magnetic properties of MgFe2O4 nanoparticles synthesized by hydrothermal technique. J Magn Magn Mater.  https://doi.org/10.1016/j.jmmm.2015.01.001 CrossRefGoogle Scholar
  46. 46.
    Kulsi C, Ghosh A, Mondal A et al (2017) Remarkable photo-catalytic degradation of malachite green by nickel doped bismuth selenide under visible light irradiation. Appl Surf Sci 392:540–548.  https://doi.org/10.1016/j.apsusc.2016.09.063 CrossRefGoogle Scholar
  47. 47.
    Abbas M, Rao B, Reddy V, Kim C (2014) Fe3O4/TiO2 core/shell nanocubes: single-batch surfactantless synthesis, characterization and efficient catalysts for methylene blue degradation. Ceram Int 40:11177–11186.  https://doi.org/10.1016/j.ceramint.2014.03.148 CrossRefGoogle Scholar
  48. 48.
    Hajnajafi M, Khorshidi A, Gilani A, Heidari B (2018) Catalytic degradation of malachite green in aqueous solution by porous manganese oxide octahedral molecular sieve (OMS-2) nanorods. Res Chem Intermed 44:3313–3323.  https://doi.org/10.1007/s11164-018-3308-1 CrossRefGoogle Scholar
  49. 49.
    Jiang D, Yuan Y, Zhao D et al (2018) Facile synthesis of three-dimensional diatomite/manganese silicate nanosheet composites for enhanced Fenton-like catalytic degradation of malachite green dye. J Nanopart Res.  https://doi.org/10.1007/s11051-018-4226-2 CrossRefGoogle Scholar
  50. 50.
    Hassani A, Eghbali P, Ekicibil A, Metin Ö (2018) Monodisperse cobalt ferrite nanoparticles assembled on mesoporous graphitic carbon nitride (CoFe2O4/mpg-C3N4): a magnetically recoverable nanocomposite for the photocatalytic degradation of organic dyes. J Magn Magn Mater 456:400–412.  https://doi.org/10.1016/j.jmmm.2018.02.067 CrossRefGoogle Scholar
  51. 51.
    Saikia L, Bhuyan D, Saikia M et al (2015) Photocatalytic performance of ZnO nanomaterials for self sensitized degradation of malachite green dye under solar light. Appl Catal A 490:42–49.  https://doi.org/10.1016/j.apcata.2014.10.053 CrossRefGoogle Scholar
  52. 52.
    Ma Y, Ni M, Li S (2018) Optimization of malachite green removal from water by TiO2 nanoparticles under UV irradiation. Nanomaterials 8:428–438.  https://doi.org/10.3390/nano8060428 CrossRefGoogle Scholar
  53. 53.
    Nanda B, Pradhan A, Parida K (2016) A comparative study on adsorption and photocatalytic dye degradation under visible light irradiation by mesoporous MnO2 modified MCM-41 nanocomposite. Microporous Mesoporous Mater 226:229–242.  https://doi.org/10.1016/j.micromeso.2015.12.027 CrossRefGoogle Scholar

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Authors and Affiliations

  1. 1.Department of ChemistryG. C. CollegeSilcharIndia
  2. 2.Department of ChemistryNational Institute of TechnologySilcharIndia

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