Synthesis of Sn2Nb2O7-GO nanocomposite as an anode material with enhanced lithium storage performance

  • Xingang KongEmail author
  • Dingying Ma
  • Jiarui Zhang
  • Qinqin Gong
  • Yong Wang
  • Qi Feng
Energy materials


Sn2Nb2O7-GO nanocomposite was prepared via a facile hydrothermal process. The sample presented that Sn2Nb2O7 nanocrystals were homogeneously dispersed and tightly anchored on the surface of the GO nanosheets. The GO nanosheets not only act as a buffer matrix to promote the structural integrity of the active material, but also serve as a conductive media to accelerate the charge transfer and lithium-ion diffusion. As a result, Sn2Nb2O7-GO nanocomposite showed enhanced electrochemical performances compared with pure Sn2Nb2O7 and Mixture. As anode material for lithium-ion batteries, the Sn2Nb2O7-GO electrode exhibited a specific capacity of 576.6 mAh g−1 at 0.1 A g−1 current density after 100 cycles. What is more, at a higher current density 2 A g−1, a reversible capacity of about 237.8 mAh g−1 was achieved.



The authors acknowledgment the support of Project Supported by the Natural Science Foundation of China (No. 51502163), Keypoint Research and Invention in Shaanxi Province of China (No. 2017GY-186), Service local special plan project of Education Department of Shaanxi Province (19JC009), the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry.

Supplementary material

10853_2019_4220_MOESM1_ESM.docx (3.3 mb)
Supplementary material 1 (DOCX 3429 kb)


  1. 1.
    Liu L, Xie F, Lyu J et al (2016) Tin-based anode materials with well-designed architectures for next-generation lithium-ion batteries. J Power Sources 321:11–35CrossRefGoogle Scholar
  2. 2.
    Wang H, Huang H, Niu C et al (2015) Ternary Sn–Ti–O based nanostructures as anodes for lithium ion batteries. Small 11(12):1364–1383CrossRefGoogle Scholar
  3. 3.
    Wang JF, He DN (2018) In situ growth of heterostructured Sn/SnO nanospheres embedded in crumpled graphene as an anode material for lithium ion batteries. Dalton Trans 47(43):15307–15311CrossRefGoogle Scholar
  4. 4.
    Bian Z, Li A, He R et al (2018) Metal-organic framework-templated porous SnO/C polyhedrons for high-performance lithium-ion batteries. Electrochim Acta 289:389–396CrossRefGoogle Scholar
  5. 5.
    Wang X, Cao X, Bourgeois L et al (2012) N-doped grapheme-SnO2 sandwich paper for high-performance lithium-ion batteries. Adv Func Mater 22(13):2682–2690CrossRefGoogle Scholar
  6. 6.
    Paek SM, Yoo EJ, Honma I (2008) Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure. Nano Lett 9(1):72–75CrossRefGoogle Scholar
  7. 7.
    Zou Y, Wang Y (2013) Microwave solvothermal synthesis of flower-like SnS2 and SnO2 nanostructures as high-rate anodes for lithium ion batteries. Chem Eng J 229:183–189CrossRefGoogle Scholar
  8. 8.
    Shmeliov A, Shannon M, Wang P et al (2014) Unusual stacking variations in liquid-phase exfoliated transition metal dichalcogenides. ACS Nano 8(4):3690–3699CrossRefGoogle Scholar
  9. 9.
    Im HS, Myung Y, Cho YJ et al (2013) Facile phase and composition tuned synthesis of tin chalcogenide nanocrystals. RSC Adv 3(26):10349–10354CrossRefGoogle Scholar
  10. 10.
    Xu H, Chen J, Wang D et al (2017) Hierarchically porous carbon-coated SnO2@graphene foams as anodes for lithium ion storage. Carbon 124:565–575CrossRefGoogle Scholar
  11. 11.
    Wan Y, Sha Y, Luo S et al (2015) Facile synthesis of tin dioxide-based high performance anodes for lithium ion batteries assisted by graphene gel. J Power Sources 295:41–46CrossRefGoogle Scholar
  12. 12.
    Lee CW, Park HK, Park S et al (2015) Ta-substituted SnNb2−xTaxO6 photocatalysts for hydrogen evolution under visible light irradiation. J Mater Chem A 3(2):825–831CrossRefGoogle Scholar
  13. 13.
    Katayama S, Hayashi H, Kumagai Y et al (2016) Electronic structure and defect chemistry of tin (II) complex oxide SnNb2O6. J Phys Chem C 120(18):9604–9611CrossRefGoogle Scholar
  14. 14.
    Taira N, Kakinuma T (2012) Photocatalytic activity of Sn2M2O7 (M=Nb and Ta) pyrochlore oxides with blue LEDs irradiation. J Ceram Soc Jpn 120(1407):551–553CrossRefGoogle Scholar
  15. 15.
    Kong X, Zhang J, Huang J et al (2019) Microwave assisted hydrothermal synthesis of tin niobates nanosheets with high cycle stability as lithium-ion battery anodes. Chin Chem Lett 30(3):771–774CrossRefGoogle Scholar
  16. 16.
    Zhai P, Qin J, Guo L et al (2017) Smart hybridization of Sn2Nb2O7/SnO2@3D carbon nanocomposites with enhanced sodium storage performance through self-buffering effects. J Mater Chem A 5(25):13052–13061CrossRefGoogle Scholar
  17. 17.
    Jahel A, Ghimbeu CM, Monconduit L et al (2014) Confined ultrasmall SnO2 particles in micro/mesoporous carbon as an extremely long cycle-life anode material for Li-ion batteries. Adv Energy Mater 4(11):1400025CrossRefGoogle Scholar
  18. 18.
    Li X, Meng X, Liu J et al (2012) Tin oxide with controlled morphology and crystallinity by atomic layer deposition onto graphene nanosheets for enhanced lithium storage. Adv Func Mater 22(8):1647–1654CrossRefGoogle Scholar
  19. 19.
    Liang J, Wei W, Zhong D et al (2012) One-step in situ synthesis of SnO2/graphene nanocomposites and its application as an anode material for Li-ion batteries. ACS Appl Mater Interfaces 4(1):454–459CrossRefGoogle Scholar
  20. 20.
    Lu Z, Wang H (2014) Fluoride-assisted coaxial growth of SnO2 over-layers on multiwall carbon nanotubes with controlled thickness for lithium ion batteries. Cryst Eng Common 16(4):550–555CrossRefGoogle Scholar
  21. 21.
    Liu X, Wu M, Li M et al (2013) Facile encapsulation of nanosized SnO2 particles in carbon nanotubes as an efficient anode of Li-ion batteries. J Mater Chem A 1(33):9527–9535CrossRefGoogle Scholar
  22. 22.
    Ouyang H, Gong Q, Li C et al (2019) Porphyra derived hierarchical porous carbon with high graphitization for ultra-stable lithium-ion batteries. Mater Lett 235:111–115CrossRefGoogle Scholar
  23. 23.
    Wang F, Jiao H, He E et al (2016) Facile synthesis of ultrafine SnO2 nanoparticles embedded in carbon networks as a high-performance anode for lithium-ion batteries. J Power Sources 326:78–83CrossRefGoogle Scholar
  24. 24.
    Sun J, Sun C, Batabyal SK et al (2012) Morphology and stoichiometry control of hierarchical CuInSe2/SnO2 nanostructures by directed electrochemical assembly for solar energy harvesting. Electrochem Commun 15(1):18–21CrossRefGoogle Scholar
  25. 25.
    Kong X, Hu D, Wen P et al (2013) Transformation of potassium Lindquist hexaniobate to various potassium niobates: solvothermal synthesis and structural evolution mechanism. Dalton Trans 42(21):7699–7709CrossRefGoogle Scholar
  26. 26.
    Reddy MJK, Ryu SH, Shanmugharaj AM (2016) Synthesis of SnO2 pillared carbon using long chain alkylamine grafted graphene oxide: an efficient anode material for lithium ion batteries. Nanoscale 8(1):471–482CrossRefGoogle Scholar
  27. 27.
    Liu X, Zhong X, Yang Z et al (2015) Gram-scale synthesis of graphene-mesoporous SnO2 composite as anode for lithium-ion batteries. Electrochim Acta 152:178–186CrossRefGoogle Scholar
  28. 28.
    Li Q, Kako T, Ye J (2011) Facile ion-exchanged synthesis of Sn2+ incorporated potassium titanate nanoribbons and their visible-light-responded photocatalytic activity. Int J Hydrogen Energy 36(8):4716–4723CrossRefGoogle Scholar
  29. 29.
    Ding J, Wang L, Liu Q et al (2015) Remarkable enhancement in visible-light absorption and electron transfer of carbon nitride nanosheets with 1% tungstate dopant. Appl Catal B 176:91–98Google Scholar
  30. 30.
    Atuchin VV, Kalabin IE, Kesler VG et al (2005) Nb 3d and O 1s core levels and chemical bonding in niobates. J Electron Spectrosc Relat Phenom 142(2):129–134CrossRefGoogle Scholar
  31. 31.
    Zhang Z, Yates JT Jr (2012) Band bending in semiconductors: chemical and physical consequences at surfaces and interfaces. Chem Rev 112(10):5520–5551CrossRefGoogle Scholar
  32. 32.
    Lin J, Peng Z, Xiang C et al (2013) Graphene nanoribbon and nanostructured SnO2 composite anodes for lithium ion batteries. ACS Nano 7(7):6001–6006CrossRefGoogle Scholar
  33. 33.
    Chen X, Huang Y, Li T et al (2017) Self-assembly of novel hierarchical flowers-like Sn3O4 decorated on 2D graphene nanosheets hybrid as high-performance anode materials for LIBs. Appl Surf Sci 405:13–19CrossRefGoogle Scholar
  34. 34.
    Han Q, Yi Z, Wang F et al (2017) Preparation of bamboo carbon fiber and sandwich-like bamboo carbon fiber@SnO2@carbon composites and their potential application in structural lithium-ion battery anodes. J Alloy Compd 709:227–233CrossRefGoogle Scholar
  35. 35.
    Teng Y, Zhao H, Zhang Z et al (2016) MoS2 nanosheets vertically grown on graphene sheets for lithium-ion battery anodes. ACS Nano 10:8526–8535CrossRefGoogle Scholar
  36. 36.
    Liu H, Hu R, Sun W et al (2013) Sn@SnOx/C nanocomposites prepared by oxygen plasma-assisted milling as cyclic durable anodes for lithium ion batteries. J Power Sources 242:114–121CrossRefGoogle Scholar
  37. 37.
    Hu R, Chen D, Waller G et al (2016) Dramatically enhanced reversibility of Li2O in SnO2-based electrodes: the effect of nanostructure on high initial reversible capacity. Energy Environ Sci 9(2):595–603CrossRefGoogle Scholar
  38. 38.
    Lu X, Wu G, Xiong Q et al (2017) Laser in situ synthesis of SnO2/N-doped graphene nanocomposite with enhanced lithium storage properties based on both alloying and insertion reactions. Appl Surf Sci 422:645–653CrossRefGoogle Scholar

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Authors and Affiliations

  1. 1.School of Materials Science and EngineeringShaanxi University of Science and TechnologyWeiyang, Xi’anPeople’s Republic of China
  2. 2.Department of Advanced Materials Science, Faculty of EngineeringKagawa UniversityTakamatsu-shiJapan

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