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Journal of Materials Science

, Volume 54, Issue 13, pp 9466–9477 | Cite as

Mesoporous amorphous TiO2 shell-coated ZIF-8 as an efficient and recyclable catalyst for transesterification to synthesize diphenyl carbonate

  • Bingying Jia
  • Ping Cao
  • Hua Zhang
  • Gongying WangEmail author
Chemical routes to materials
  • 30 Downloads

Abstract

The catalysts containing tetra-coordinated titanium have been widely used for transesterification. The key issue in the design of these catalysts is the stability of tetra-coordinated titanium. In this study, mesoporous amorphous titanium oxides coated on a zeolitic imidazolate framework (ZIF-8) were developed by using a hexadecylamine (HDA) surfactant as a structure-directing agent. The mesopores surface areas of the amorphous TiO2 shell could be simply controlled by changing the dosage of HDA in the synthetic process. The novel, efficient and recyclable heterogeneous catalyst was introduced to the synthesis of diphenyl carbonate from dimethyl carbonate and phenyl acetate for the first time. The catalyst structure was characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, nitrogen adsorption–desorption, Fourier transform infrared spectroscopy and thermogravimetric analysis. The effects of the molar ratio of Ti to Zn, HDA amount, catalyst amount, reaction time and reusability on the yield of the transesterification products were also determined. The results showed that the mesopores of TiO2 shell facilitated reactants and productions diffusion to increase the conversion of phenyl acetate and yield of diphenyl carbonate. Moreover, the coordination between titanium and ZIF-8 also endowed the catalysts with reasonable reusability.

Notes

Acknowledgements

We gratefully acknowledge financial support from the Department of Science and Technology of Sichuan Province (No. 2018CC0139).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflicts of interest.

Supplementary material

10853_2019_3595_MOESM1_ESM.docx (966 kb)
Supplementary material 1 (DOCX 965 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Chengdu Institute of Organic ChemistryChinese Academy of SciencesChengduChina
  2. 2.National Engineering Laboratory for VOCs Pollution Control Material and TechnologyUniversity of Chinese Academy of SciencesBeijingChina
  3. 3.School of Chemical EngineeringChongqing University of TechnologyChongqingChina

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