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Engineering Ni3+ inside nickel selenide as efficient bifunctional oxygen electrocatalysts for Zn–air batteries

  • Qiu-Ren Pan
  • Si-Jie Li
  • Kaixin Tong
  • Chong Xie
  • Lijuan Peng
  • Nan LiEmail author
  • Dong-Yao Wang
  • Hong SuEmail author
Energy materials
  • 14 Downloads

Abstract

Developing a high-efficienct, low-cost and stable non-noble-metal-based bifunctional electrocatalyst for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) as oxygen electrode material in the rechargeable zinc–air battery is crucial in renewable energy conversion technologies. In this work, nitrogen-doped hollow carbon sphere (NHCS) decorated with various nickel selenide (NixSe) nanoparticles had been designed and successfully prepared. Among them, the Ni0.85Se–NHCS with the highest percentage of Ni3+ could serve as a new efficient bifunctional electrocatalyst toward ORR/OER (with an onset potential of 0.850 V for ORR and a potential of 1.583 V at 10 mA·cm−2 for OER) in an alkaline medium. Furthermore, the assembled Zn–air battery coupled with Ni0.85Se–NHCS electrode has excellent discharging–charging performance and long lifetime. This work provides a valuable understanding on transition metal non-oxide electrocatalysts and expands the applications of selenide-based materials.

Notes

Acknowledgements

This study was funded by Guangzhou municipal Science and Technology Project (No.201607010263), Featured Innovation Project of Guangdong Universities (No. 2017KTSCX142), Undergraduate’s Innovation Training Program (No. 201711078005), and “Climbing” Program of Undergraduate of Guangdong Province (No. pdjh2019b0388).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10853_2019_3520_MOESM1_ESM.docx (2.3 mb)
Supplementary material 1 (DOCX 2332 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Chemistry and Chemical Engineering/Institute of Clean Energy and MaterialsGuangzhou UniversityGuangzhouChina
  2. 2.Institute of Ground Water and Earth SciencesJinan UniversityGuangzhouChina

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