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Journal of Materials Science

, Volume 54, Issue 5, pp 4192–4201 | Cite as

Direct laser writing of graphene films from a polyether ether ketone precursor

  • Chenguang Zhu
  • Dongmei Zhao
  • Kedian Wang
  • Xia Dong
  • Wenqiang Duan
  • Fangcheng Wang
  • Meng Gao
  • Guan Zhang
Energy materials
  • 117 Downloads

Abstract

Graphene-based micro-supercapacitors exhibit excellent electrochemical performance that can easily meet the energy storage requirements of micro-electronic products. However, the complex preparation and transfer process steps of traditional preparation methods limit their wide application. Direct laser writing can deposit graphene laser-induced graphene (LIG) onto a specific substrate-patterned electrodes. This approach offers great advantages in the preparation of miniature and complex-patterned electrodes, but currently there is a limited choice of precursor materials. In this reported study, biocompatible polyether ether ketone (PEEK) was irradiated using a high repetition rate picosecond laser to produce graphene. Various photothermal and photochemical reactions were involved in the one-step conversion of PEEK into a film comprised of a several layers (3–4) of graphene. The electrochemical testing of a three-electrode system containing this novel graphene showed that LIG had a specific capacitance of 20.4 mF cm−2 at a scan speed of 10 mV s−1, and the capacitance was reversibly maintained with 89.37% retention of the initial capacitance after 5000 cycles. The novel LIG with higher specific capacitance and cycle stability has great potential for use in energy storage micro-devices.

Notes

Acknowledgements

The authors sincerely thank financial support from the National Natural Science Foundation of China (Grant No. 51775419).

Compliance with ethical standards

Conflict of interest

All authors declare that they have no conflict of interest.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.State Key Laboratory for Manufacturing System EngineeringXi′an Jiaotong UniversityXi′anChina
  2. 2.Shaanxi Key Laboratory of Intelligent RobotsXi′an Jiaotong UniversityXi′anChina
  3. 3.School of Mechanical EngineeringXi′an Jiaotong UniversityXi′anChina
  4. 4.Engineering Training CenterXinjiang UniversityÜrümqiChina

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