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Journal of Materials Science

, Volume 54, Issue 5, pp 4168–4179 | Cite as

Mesoporous, nitrogen-doped, graphitized carbon nanosheets embedded with cobalt nanoparticles for efficient oxygen electroreduction

  • Ni Zhou
  • Ligui Li
  • Shaowei Chen
  • Xinwen Peng
  • Wenhan Niu
  • Yunpeng Qu
Energy materials
  • 62 Downloads

Abstract

Nitrogen-doped graphitized carbon nanosheets embedded with crystalline cobalt nanoparticles are facilely synthesized with the aid of melamine-containing hydrogen-bonded organic frameworks (HOF). Experimentally, HOF microrods with an in situ polymerized dopamine (DA) overlayer are coordinated with Co2+ cations and used as a precursor. After pyrolyzing the Co@DA-HOF precursor, irregular sheet-like carbons comprising a large number of Co nanoparticles as well as abundant mesopores are obtained (Co@MPC-T). The thermal decomposition of melamine-containing HOF microrods during high-temperature pyrolysis helps generate the abundant porous structures in the resulting catalyst samples. Thus, synthesized Co@MPC-T catalysts display an apparent ORR activity, and the one pyrolyzed at 800 °C is determined to show the highest ORR catalytic activity among the series, with a half-wave potential of + 0.796 V, a diffusion-limiting current density of 5.492 mA cm−2 at + 0.200 V and a kinetic current of 51.40 mA cm−2 that is even two times higher than the 20.10 mA cm−2 for commercial Pt/C catalyst. Moreover, benefiting from the protection of graphitized carbon overlayer, Co@MPC-800 shows a substantially higher operation stability as well as superior tolerance to fuel crossover, as compared with the commercial Pt/C catalyst. The remarkable ORR performance of Co@MPC-800 highlights the high potential of graphitized two-dimensional carbon composites with nonprecious transition metal nanoparticles in electrocatalysis.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (NSFC 51402111 and 21528301), Guangdong Innovative and Entrepreneurial Research Team Program (2014ZT05N200) and the Fundamental Research Funds for the Central Universities (SCUT Grant No. 2018ZD21).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10853_2018_3121_MOESM1_ESM.docx (2.1 mb)
Supplementary material 1 (DOCX 2151 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Guangzhou Key Laboratory for Surface Chemistry of Energy Materials, New Energy Research Institute, School of Environment and Energy, Guangzhou Higher Education Mega CenterSouth China University of TechnologyGuangzhouChina
  2. 2.Department of Chemistry and BiochemistryUniversity of CaliforniaSanta CruzUSA
  3. 3.State Key Laboratory of Pulp and Paper EngineeringSouth China University of TechnologyGuangzhouChina
  4. 4.Shenzhen Yaya Zhixian Technology Co., Ltd.ShenzhenChina

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