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Journal of Materials Science

, Volume 54, Issue 7, pp 5625–5640 | Cite as

Nitrogen- and oxygen-rich dual-decorated carbon materials with porosity for high-performance supercapacitors

  • Haijun Chen
  • Jing Chen
  • Daming Chen
  • Huanming Wei
  • Ping Liu
  • Wei Wei
  • Hualin LinEmail author
  • Sheng HanEmail author
Energy materials
  • 99 Downloads

Abstract

A series of N/O co-doping porous carbon materials are fabricated from benzotriazole as nitrogen-containing precursor through simple chemical activation (phosphoric acid as activator) and thermolysis process under nitrogen atmosphere. Abundant heteroatoms or functional groups (O: 11.4 at.%; N: 6.5 at.%) in the N/O-3-700 sample can improve the overall electrochemical performance of the material, which is because they can enhance physicochemical properties and induce the pronounced pseudocapacitance. In three-electrode system, the resultant product (N/O-3-700) has a highest specific capacitance value of 357.8 F g−1 at 0.1 A g−1 and good cycle stability (remains more than 94% after 10000 at 1 A g−1), which are attributed to large specific area (1337.7 m2 g−1) and proper functional groups (the sum of N-5 and N-6 content: 42.2 at.%; quinone: 14.3 at.%, C=O and/or COOH: 16.0 at.%). And in symmetric two-electrode cell, the N/O-3-700//N/O-3-700 cell possesses highest energy density of 17.80 Wh kg−1 at 1 A g−1 and still has a high energy density (12.51 Wh kg−1) at 10 A g−1. Thus, the N/O-doped porous carbon can be used for supercapacitors.

Notes

Acknowledgements

This work was supported from the National Natural Science Foundation of China (Project Numbers 21606151, 21504057 and 21707092), Shanghai Excellent Technology Leaders Program (Project Number 17XD1424900), Shanghai Leading Talent Program (Project Number 017), Science and Technology Commission of Shanghai Municipality Project (Project Number 18090503800), Shanghai Natural Science Foundation of Shanghai (Project Numbers 17ZR1441700 and 14ZR1440500), Collaborative Innovation Fund of SIT (Project Number XTCX2015-9), Professor of Special Appointment at Shanghai Institutions of Higher Learning (Eastern Scholar), Shanghai Association for Science and Technology Achievements Transformation Alliance Program (Project Number LM201680).

Compliance with ethical standards

Conflict of interest

All authors listed have declared that they have no conflict of interest.

Supplementary material

10853_2018_2993_MOESM1_ESM.doc (1.6 mb)
Supplementary material 1 (DOC 1624 kb)

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Authors and Affiliations

  1. 1.School of Chemical and Environmental EngineeringShanghai Institute of TechnologyShanghaiPeople’s Republic of China

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