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Journal of Materials Science

, Volume 54, Issue 1, pp 383–395 | Cite as

Preparation of stable and high-efficient poly(m-phenylenediamine)/reduced graphene oxide composites for hexavalent chromium removal

  • Linfeng Jin
  • Lei Huang
  • Lili Ren
  • Yingjie He
  • Jingwen Tang
  • Sheng Wang
  • Weichun Yang
  • Haiying Wang
  • Liyuan Chai
Composites
  • 714 Downloads

Abstract

Structural instability of polymers under strong acidic condition severely limits their application in the field of environment. A synthetic strategy for the preparation of poly(m-phenylenediamine)/reduced graphene oxide (PmPD/rGO) composites was proposed for Cr(VI) removal in strong acidic solution, which involved in situ reduction of graphene oxide (GO) and assembly of PmPD nanoparticles. Effects of in situ reduction of GO on oxidation polymerization, property and Cr(VI) adsorption capacity of composites were investigated methodically. Compared to pure PmPD, PmPD/rGO composites exhibited favorable stability in strong acidic solution. Moreover, the polymerization yield of PmPD/rGO composites increased from 75 to 91%. The maximum Cr(VI) adsorption capacity of composites calculated by the Langmuir model reached 526.24 mg g−1. The mechanisms of PmPD/rGO composites preparation and Cr(VI) removal were analyzed in detail. The synthetic strategy shows promising prospect to expand application of polymers, especially for Cr(VI) removal in strong acidic solution.

Notes

Acknowledgements

This research is financially supported by the National Key Research and Development Program of China (2016YFC0403003), the National Key Research and Development Program of China (2017YFC0210401).

Supplementary material

10853_2018_2844_MOESM1_ESM.docx (608 kb)
Supplementary material 1 (DOCX 607 kb)

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Environmental Engineering, School of Metallurgy and EnvironmentCentral South UniversityChangshaChina
  2. 2.Chinese National Engineering Research Center for Control and Treatment of Heavy Metals PollutionChangshaChina

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