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ZnS nanoparticles coated with graphene-like nano-cell as anode materials for high rate capability lithium-ion batteries

  • Huiwei Du
  • Xuchun Gui
  • Rongliang Yang
  • Hao Zhang
  • Zhiqiang Lin
  • Binghao Liang
  • Wenjun Chen
  • Hai Zhu
  • Jun Chen
Energy materials
  • 2 Downloads

Abstract

A core–shell structure ZnS nanocomposite was synthesized by wrapping ZnS nanoparticles up in graphene-like nano-cell (GLC@ZnS) through chemical vapor deposition. The morphological and structural characteristics exhibit that the obtained GLC@ZnS composite possesses high-quality ZnS nano-sized particles and laminated graphene-like layers shell. When applied as anode materials for lithium-ion batteries, the GLC@ZnS composite (high ZnS content of 97.2%) with diameter of 30 nm delivers high reversible capacities (1134 mAh g−1 after 100 cycles at 0.5 A g−1, 890 mAh g−1 after 200 cycles at 1.0 A g−1) and excellent rate capability (701 mAh g−1 at 8.0 A g−1). The excellent electrochemical performance of the composite is ascribed to the inclosed graphene-like nano-cell, which could localize the active materials and enhance the exchange of charges and ions.

Notes

Acknowledgements

This work was financially supported by National Natural Science Foundation of China (Grant No. 51772335), Guangdong Natural Science Foundation (Grant No. 2016A030313346), Guangdong Youth Top-notch Talent Support Program (Grant No. 2015TQ01C201).

Supplementary material

10853_2018_2674_MOESM1_ESM.doc (1.5 mb)
Supplementary material 1 (DOC 1516 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.State Key Lab of Optoelectronic Materials and Technologies, School of Electronics and Information TechnologySun Yat-sen UniversityGuangzhouPeople’s Republic of China
  2. 2.Instrumental Analysis and Research Center (IARC)Sun Yat-sen UniversityGuangzhouPeople’s Republic of China
  3. 3.State Key Laboratory of Optoelectronic Materials and Technologies, School of PhysicsSun Yat-Sen UniversityGuangzhouChina
  4. 4.Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information TechnologySun Yat-sen UniversityGuangzhouPeople’s Republic of China

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