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Journal of Materials Science

, Volume 53, Issue 13, pp 9449–9462 | Cite as

Synthesis of manganese oxide electrocatalysts in supercritical carbon dioxide

  • V. V. Zefirov
  • I. V. Elmanovich
  • E. E. Levin
  • S. S. Abramchuk
  • E. P. Kharitonova
  • A. A. Khokhlov
  • M. S. Kondratenko
  • M. O. Gallyamov
Chemical routes to materials
  • 189 Downloads

Abstract

In this work, a novel method of preparing manganese oxide nanoparticles from an organometallic precursor dissolved in supercritical carbon dioxide (sc CO2) was presented. Using the new approach, nanomaterials mostly consisting of manganese oxides in β-MnO2 and ε-MnO2 phases with small-sized (~ 40 nm) grains and low polydispersity index (~ 0.12) can be synthesized, which was consistently proved by means of thermogravimetric and X-ray diffraction analysis, scanning and transmission electron microscopy. Moreover, reasonable electrocatalytic activity of the obtained materials was detected by a rotating disk electrode method.

Notes

Acknowledgements

The authors are grateful to Professor G.A. Tsirlina from the Lomonosov Moscow State University for her valuable guidance in electrochemical experiments and discussion of the results. Research reported in this publication (in the parts of V.V.Z., S.S.A, M.S.K., M.O.G contributions) was supported by Centre for Electrochemical Energy of Skolkovo Institute of Science and Technology.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interests.

Supplementary material

10853_2018_2242_MOESM1_ESM.pdf (278 kb)
Supplementary material 1 (PDF 278 kb)

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Authors and Affiliations

  1. 1.Faculty of Physics and Faculty of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation
  2. 2.A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of SciencesMoscowRussian Federation

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