Catalytic conversion of Kraft lignin to bio-multilayer graphene materials under different atmospheres
Kraft lignin was catalytic graphitized by iron at 1000 °C in argon, hydrogen, CO2, methane, and natural gas atmospheres, respectively. The effect of atmospheric agent types on product distribution (gas, liquid, and solid carbon yields) was analyzed. The solid products were characterized by scanning electron microscopy, Raman, high-resolution transmission electron microscopy, and X-ray diffraction. Experimental results have shown that the degree of graphitization of Kraft lignin depends not only on the highest temperature, but also the type of ambient gas phase during heat treatment. Methane and natural gas in the ambient gas phase seem to accelerate the formation of multilayer graphene materials with a range of 2–30 layers, and hydrogen and carbon dioxide have an etching effect on solid carbon species during the catalytic graphitization process, while multilayer graphene-encapsulated iron nanoparticles were the main products in the case of argon.
This work was supported by the USDA Forest Service through Grant No. 16-JV-11111124-075. The authors would like to acknowledge Domtar Corp., North Carolina, for providing Kraft lignin for this study. The assistance of Ms. Amanda Lawrence of the Institute for Imaging and Analytical Technologies (I2AT) at Mississippi State University is gratefully acknowledged.
- 4.Yan Q, Toghiani H, Yu F, Cai Z, Zhang J (2011) Effects of pyrolysis conditions on yield of bio-chars from pine chips. For Prod J 61(5):367–371Google Scholar
- 11.Mitchel WC, Boeckl J, Tomlin D, Lu W, Rigueur J, Reynolds J (2005) Growth of carbon nanotubes by sublimation of silicon carbide substrates. In: Razeghi M, Brown GJ (eds) International Society for Optics and Photonics, p 77. https://doi.org/10.1117/12.590456
- 13.Lu WJ, Boeckl J, Mitchel WC, Rigueur J, Collins WE (2006) Role of oxygen in growth of carbon nanotubes on SiC. Mater Sci Forum 527–529:1575–1578. https://doi.org/10.4028/www.scientific.net/MSF.527-529.1575 CrossRefGoogle Scholar
- 29.Abdelaziz Omar Y, Brink Daniel P, Prothmann Jens, Ravi Krithika, Sun Mingzhe, García-Hidalgo Javier, Sandahl Margareta, Hulteberg Christian P, Turner Charlotta, Lidén Gunnar, Gorwa-Grauslun Marie F (2016) Biological valorization of low molecular weight lignin. Biotechnol Adv 34(8):1318–1346CrossRefGoogle Scholar
- 30.Fengel D, Wegener G (1984) Wood (Chemistry, Ultrastructure, Reactions). Walter de Gruyter, New YorkGoogle Scholar