Journal of Materials Science

, Volume 53, Issue 9, pp 6552–6561 | Cite as

C-doped Cr2O3/NaY composite membrane supported on stainless steel mesh with enhanced photocatalytic activity for cyclohexane oxidation

  • Xiaoxia Zhao
  • Ying ZhangEmail author
  • Ping Qiu
  • Ping Wen
  • Hui Wang
  • Guang Xu
  • Yang Han


In this study, a C-doped Cr2O3/NaY composite membrane supported on stainless steel mesh with layer-by-layer structure was successfully synthesized and used in the partial oxidation of cyclohexane. In the composite membrane, NaY zeolite membrane acted as absorbent and the C-doped Cr2O3 behaved as photocatalyst, which was successfully prepared using a chromium-containing MOF as precursor. The supported composite membrane was characterized by a series of analysis techniques. Comparing with the stainless steel mesh-supported C-doped Cr2O3 membrane, the supported C-doped Cr2O3/NaY composite membrane exhibited superior visible-light-driven photocatalytic performance for cyclohexane oxidation. This is due to its layer-by-layer structure and NaY membrane with high surface areas and polarity which can preferentially adsorb KA oil products, avoiding their overoxidation.



We acknowledge the financial support by the National Natural Science Foundation of China (No. 21676296) and National Key Research and Development Plan (Grant No. 2016YFC0303700).


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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.The State Key Laboratory of Heavy Oil ProcessingChina University of PetroleumBeijingPeople’s Republic of China
  2. 2.Department of Materials Science and EngineeringChina University of Petroleum (Beijing)BeijingPeople’s Republic of China

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