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Journal of Materials Science

, Volume 53, Issue 7, pp 5467–5476 | Cite as

Poly(NIPAAm-co-Ru(bpy) 3 2+ ) hydrogels crosslinked by double-bond end-capped Pluronic F127: preparation, properties and coupling with the BZ reaction

  • Hongwei ZhouEmail author
  • Bo Yan
  • Jie Li
  • Hanbin Liu
  • Qiang Wang
  • Xiaobin Ding
  • Xilang JinEmail author
  • Aijie Ma
  • Weixing Chen
  • Jingjing Yang
  • Chunyan Luo
  • Gai Zhang
  • Weifeng Zhao
Polymers

Abstract

Topological network design is an effective way to obtain new functionalities and regulate the properties of stimuli responsive hydrogels. In this work, poly(NIPAAm-co-Ru(bpy) 3 2+ ) hydrogels (NIPAAm: N-isopropylacrylamide, Ru(bpy) 3 2+ : Ruthenium bipyridine complex monomer) crosslinked by amphiphilic triblock copolymers were designed and constructed by a photo-induced gelation method, utilizing double-bond end-capped Pluronic F127 (F127DA) as the crosslinking agent, NIPAAm and Ru(bpy) 3 2+ as the monomers, α-ketoglutaric acid as the photoinitiator and H2O as the solvent. The resulting F127DA crosslinked hydrogels exhibit unique swelling behaviors, mechanical properties, fluorescent behaviors and thermosensitive properties and can be coupled with the BZ reaction. The present example may enrich the family of metal-containing polymer materials and provide clues to develop other functional hydrogels by designing topologically crosslinked network.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 51603164, 51373175, 61604120), the Natural Science Basic Research Plan in Shaanxi Province of China (Nos. 2016JQ5036, No. 2017ZDJC-22), the Young Talent Fund of University Association for Science and Technology in Shaanxi, China (20170706), and the Start-up Funding for Scientific Research in Xi’an Technological University (Nos. 0853-302020350).

Supplementary material

10853_2017_1929_MOESM1_ESM.avi (5.4 mb)
Supplementary material 1 (AVI 5545 kb)

Supplementary material 2 (AVI 2118 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • Hongwei Zhou
    • 1
    Email author
  • Bo Yan
    • 1
  • Jie Li
    • 2
  • Hanbin Liu
    • 3
  • Qiang Wang
    • 1
  • Xiaobin Ding
    • 2
  • Xilang Jin
    • 1
    Email author
  • Aijie Ma
    • 1
  • Weixing Chen
    • 1
  • Jingjing Yang
    • 1
  • Chunyan Luo
    • 1
  • Gai Zhang
    • 1
  • Weifeng Zhao
    • 1
  1. 1.School of Materials and Chemical EngineeringXi’an Technological UniversityXi’anPeople’s Republic of China
  2. 2.Chengdu Institute of Organic ChemistryUniversity of Chinese Academy of SciencesChengduPeople’s Republic of China
  3. 3.School of Bioresources Chemical and Materials EngineeringShaanxi University of Science and TechnologyXi’anPeople’s Republic of China

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