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Journal of Materials Science

, Volume 53, Issue 7, pp 5051–5062 | Cite as

Preparation and evaluation of magnetic field-induced orientation on magnetic nanoparticles on PVA nanocomposite films

  • Mozhgan Chaichi
  • Farhad Sharif
  • Saeedeh Mazinani
Composites
  • 340 Downloads

Abstract

Magnetite Fe3O4 particles (M) were dispersed in polyvinyl alcohol (PVA) and oriented successfully by applying low external magnetic field. Observed orientation was verified by image analysis using ImageJ software. Crystallinity of the M/PVA samples was examined using DSC, showing a lower crystallinity by addition of particles and higher crystallinity resulting from orientation. Orientation of 0.05 and 0.1 wt% of M particles increased crystallinity of nanocomposites 39 and 57%, respectively. Tensile tests were also measured to examine the mechanical properties of oriented and non-oriented samples. Results show that the mechanical properties of samples including elongation at break and modulus had improved in the direction of oriented particles. Afterward, graphene oxide particles were magnetized [magnetic graphene oxide (MGO)] and dispersed in PVA resulting in improved mechanical properties. PVA/MGO nanocomposites showed better mechanical properties than PVA/M, although no improvement in the crystallinity was observed.

Notes

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflicts of interest.

References

  1. 1.
    Yonemura H et al (2008) Magnetic orientation of single-walled carbon nanotubes or their composites using polymer wrapping. Sci Technol Adv Mater 9:024213–024219CrossRefGoogle Scholar
  2. 2.
    Bolisetty S et al (2013) Magnetic-responsive hybrids of Fe3O4 nanoparticles with β-lactoglobulin amyloid fibrils and nanoclusters. ACS Nano 7(7):6146–6155CrossRefGoogle Scholar
  3. 3.
    Wu L et al (2014) Magnetically induced anisotropic orientation of graphene oxide locked by in situ hydrogelation. ACS Nano 8(5):4640–4649CrossRefGoogle Scholar
  4. 4.
    Zheng Y et al (2010) Fabrication of shape controlled Fe3O4 nanostructure. Mater Charact 61(4):489–492CrossRefGoogle Scholar
  5. 5.
    Sun J et al (2015) One-step synthesis of magnetic graphene oxide nanocomposite and its application in magnetic solid phase extraction of heavy metal ions from biological samples. Talanta 132:557–563CrossRefGoogle Scholar
  6. 6.
    Mahmoudi M, Shokrgozar MA (2015) Super paramagnetic iron oxide nanoparticles with metallic coatings and a method of synthesizing the same. Google PatentsGoogle Scholar
  7. 7.
    Teixeira S et al (2017) Photocatalytic degradation of recalcitrant micropollutants by reusable Fe3O4/SiO2/TiO2 particles. J Photochem Photobiol A Chem 345:27–35CrossRefGoogle Scholar
  8. 8.
    Rathi AK et al (2016) Magnetite (ferrites)-supported nano-catalysts: sustainable applications in organic transformations. In: Ferrites and ferrates: chemistry and applications in sustainable energy and environmental remediation, pp 39–78. ACS Publications, WashingtonGoogle Scholar
  9. 9.
    Pelligra CI, Majewski PW, Osuji CO (2013) Large area vertical alignment of ZnO nanowires in semiconducting polymer thin films directed by magnetic fields. Nanoscale 5(21):10511–10517CrossRefGoogle Scholar
  10. 10.
    Erb RM et al (2012) Composites reinforced in three dimensions by using low magnetic fields. Science 335(6065):199–204CrossRefGoogle Scholar
  11. 11.
    Wu S et al (2015) Epoxy nanocomposites containing magnetite-carbon nanofibers aligned using a weak magnetic field. Polymer 68:25–34CrossRefGoogle Scholar
  12. 12.
    Fragouli D et al (2014) Polymeric films with electric and magnetic anisotropy due to magnetically assembled functional nanofibers. ACS Appl Mater Interfaces 6(6):4535–4541CrossRefGoogle Scholar
  13. 13.
    Jiao W et al (2014) Improving the gas barrier properties of Fe3O4/graphite nanoplatelet reinforced nanocomposites by a low magnetic field induced alignment. Compos Sci Technol 99:124–130CrossRefGoogle Scholar
  14. 14.
    Yan H et al (2014) Enhanced thermal conductivity in polymer composites with aligned graphene nanosheets. J Mater Sci 49(15):5256–5264.  https://doi.org/10.1007/s10853-014-8198-z CrossRefGoogle Scholar
  15. 15.
    Min D et al (2017) Greatly enhanced microwave absorption properties of highly oriented flake carbonyl iron/epoxy resin composites under applied magnetic field. J Mater Sci 52(4):2373–2383.  https://doi.org/10.1007/s10853-016-0532-1 CrossRefGoogle Scholar
  16. 16.
    Marins JA et al (2015) Anisotropic reinforcement of epoxy-based nanocomposites with aligned magnetite–sepiolite hybrid nanofiller. Compos Sci Technol 112:34–41CrossRefGoogle Scholar
  17. 17.
    Zhang J et al (2014) Magnetic and mechanical properties of polyvinyl alcohol (PVA) nanocomposites with hybrid nanofillers—graphene oxide tethered with magnetic Fe3O4 nanoparticles. Chem Eng J 237:462–468CrossRefGoogle Scholar
  18. 18.
    Boukhvalov D, Katsnelson M (2009) Chemical functionalization of graphene. J Phys Condens Matter 21(34):344205–344217CrossRefGoogle Scholar
  19. 19.
    Erickson K et al (2010) Determination of the local chemical structure of graphene oxide and reduced graphene oxide. Adv Mater 22(40):4467–4472CrossRefGoogle Scholar
  20. 20.
    Liang J et al (2009) Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites. Adv Func Mater 19(14):2297–2302CrossRefGoogle Scholar
  21. 21.
    Zhao X et al (2010) Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites. Macromolecules 43(5):2357–2363CrossRefGoogle Scholar
  22. 22.
    Cano M et al (2013) Improving the mechanical properties of graphene oxide based materials by covalent attachment of polymer chains. Carbon 52:363–371CrossRefGoogle Scholar
  23. 23.
    Lee S, Hong JY, Jang J (2013) The effect of graphene nanofiller on the crystallization behavior and mechanical properties of poly(vinyl alcohol). Polym Int 62(6):901–908CrossRefGoogle Scholar
  24. 24.
    Yang X, Shang S, Li L (2011) Layer-structured poly(vinyl alcohol)/graphene oxide nanocomposites with improved thermal and mechanical properties. J Appl Polym Sci 120(3):1355–1360CrossRefGoogle Scholar
  25. 25.
    Yang X et al (2010) Synthesis and characterization of layer-aligned poly(vinyl alcohol)/graphene nanocomposites. Polymer 51(15):3431–3435CrossRefGoogle Scholar
  26. 26.
    Morimune S, Nishino T, Goto T (2012) Poly(vinyl alcohol)/graphene oxide nanocomposites prepared by a simple eco-process. Polym J 44(10):1056–1063CrossRefGoogle Scholar
  27. 27.
    Morimune S et al (2014) Uniaxial drawing of poly(vinyl alcohol)/graphene oxide nanocomposites. Carbon 70:38–45CrossRefGoogle Scholar
  28. 28.
    Liu L et al (2013) High mechanical performance of layered graphene oxide/poly(vinyl alcohol) nanocomposite films. Small 9(14):2466–2472CrossRefGoogle Scholar
  29. 29.
    Ma H-L et al (2013) Enhanced mechanical properties of poly(vinyl alcohol) nanocomposites with glucose-reduced graphene oxide. Mater Lett 102:15–18CrossRefGoogle Scholar
  30. 30.
    Liu K et al (2016) Influence of reduced graphene oxide on the rheological response and chain orientation on shear deformation of high density polyethylene. Polymer 87:8–16CrossRefGoogle Scholar
  31. 31.
    Liu D et al (2016) Effect of oxidation degrees of graphene oxide on the structure and properties of poly(vinyl alcohol) composite films. Compos Sci Technol 129:146–152CrossRefGoogle Scholar
  32. 32.
    Hummers WS Jr, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80(6):1339CrossRefGoogle Scholar
  33. 33.
    Chen J et al (2013) An improved Hummers method for eco-friendly synthesis of graphene oxide. Carbon 64:225–229CrossRefGoogle Scholar
  34. 34.
    Deng J-H et al (2013) Simultaneous removal of Cd(II) and ionic dyes from aqueous solution using magnetic graphene oxide nanocomposite as an adsorbent. Chem Eng J 226:189–200CrossRefGoogle Scholar
  35. 35.
    Qi T et al (2015) Synthesis, characterization and adsorption properties of magnetite/reduced graphene oxide nanocomposites. Talanta 144:1116–1124CrossRefGoogle Scholar
  36. 36.
    Ye N et al (2014) Synthesis of magnetite/graphene oxide/chitosan composite and its application for protein adsorption. Mater Sci Eng C 45:8–14CrossRefGoogle Scholar
  37. 37.
    Wang Z et al (2003) Exfoliated PP/clay nanocomposites using ammonium-terminated PP as the organic modification for montmorillonite. Macromolecules 36(24):8919–8922CrossRefGoogle Scholar
  38. 38.
    Strawhecker K, Manias E (2003) Crystallization behavior of poly(ethylene oxide) in the presence of Na+ montmorillonite fillers. Chem Mater 15(4):844–849CrossRefGoogle Scholar
  39. 39.
    Lepot N et al (2011) Influence of incorporation of ZnO nanoparticles and biaxial orientation on mechanical and oxygen barrier properties of polypropylene films for food packaging applications. J Appl Polym Sci 120(3):1616–1623CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  1. 1.Department of Polymer Engineering and Color TechnologyAmirkabir University of TechnologyTehranIran
  2. 2.Amirkabir Nanotechnology Research Institute (ANTRI)Amirkabir University of TechnologyTehranIran

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