Optimization of the metakaolin geopolymer preparation for maximized ammonium adsorption capacity
Geopolymers are functional materials that can be used in various environmental applications such as adsorbents in pollutant removal from wastewaters. Metakaolin geopolymer (MK-GP) has been proven to be especially suitable for ammonium (NH4 +) removal. In this research, the optimal reagent and raw material ratios in the preparation of MK-GP in terms of NH4 + adsorption capacity were investigated. The response surface methodology based on the face-centered central composite design was used to optimize the levels of three factors: the amounts of hydroxide, silicate, and metakaolin. In addition, the effect of Na or K as the charge-balancing cation was studied. Empirical models were fitted to the experimental data using multiple linear regression. The significance of the models was confirmed by means of analysis of variance. Optimal NH4 + removal efficiency was achieved when the amounts of hydroxide and silicate were maximized, the amount of metakaolin was minimized, and Na-based reagents were used. These trends are most likely a result of optimized conversion of metakaolin into MK-GP.
KeywordsZeolite Adsorption Capacity Geopolymer Natural Zeolite Silicate Solution
This work was supported by the Finnish Funding Agency for Innovation (TEKES) [Grant Number 4096/31/2014, project GeoSorbents]. Authors gratefully acknowledge the contributions of Henrik Romar, Riikka Juhola, Tom Heyninck, Esther Takaluoma, Kai Tiihonen, and Marjukka Hyyryläinen in the laboratory work.
- 1.Provis JL, Van Deventer JSJ (2009) Introduction to geopolymers. In: Provis JL, Van Deventer JSJ (eds) Geopolymers—structure, processing, properties and industrial applications. CRC Press, Boca Raton, pp 1–11Google Scholar
- 6.Mužek MN, Svilovic S, Ugrina M, Zelic J (2015) Removal of copper and cobalt ions by fly ash-based geopolymer from solutions-equilibrium study. Desalin Water Treat 57:10689–10699Google Scholar
- 19.Jha B, Singh D (2011) A review on synthesis, characterization and industrial applications of flyash zeolites. J Mat Educ 33:65–132Google Scholar
- 28.López FJ, Sugita S, Tagaya M, Kobayashi T (2014) Metakaolin-based geopolymers for targeted adsorbents to heavy metal ion separation. J Mater Sci Chem Eng 2:16–27Google Scholar
- 36.Davidovits J (2011) Geopolymer chemistry & applications, 3rd edn. Institut Geopolymere, Saint-QuentinGoogle Scholar