Recent approaches and future prospects of bacterial cellulose-based electroconductive materials
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Abstract
The interest in studying cellulose especially bacterial cellulose (BC) and BC-based composites has increased dramatically, due to their outstanding properties. Among them, BC-based electroconductive composites seem to capture more attention because of their perfect structure and controllable synthesis as well as potential values. Meanwhile, the development of carbon fibers is becoming a hot spot in recent years. Here, we concentrate on describing their numerous approaches, and some improvements in the process, which are discussed in greater details with an emphasis on their functional properties and potential applications. The challenges in commercial scale applications are discussed and the efficiencies of various electroconductive composites are compared, in order to exploit its far-reaching application value.
Keywords
Graphene Oxide PANI MoS2 Bacterial Cellulose Phytic AcidNotes
Acknowledgements
This work was supported by “The Fundamental Research Funds for the Central Universities (No. 30920130121001),” “National Natural Science Foundation of China (No. 51272106) (No. 21206076),” “Natural Science Foundation of Jiangsu Province (No. BK2012401),” and “A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD, China).” The authors are grateful to “Synergetic Research Center for Advanced Micro-Nano-Materials and Technology of Jiangsu Province.”
References
- 1.Gatenholm P, Klemm D (2010) Bacterial nanocellulose as a renewable material for biomedical applications. MRS Bull 35(03):208–213CrossRefGoogle Scholar
- 2.Brown AJ (1886) XLIII.—On an acetic ferment which forms cellulose. J Chem Soc Trans 49:432–439CrossRefGoogle Scholar
- 3.Yoshinaga F, Tonouchi N, Watanabe K (1997) Research progress in production of bacterial cellulose by aeration and agitation culture and its application as a new industrial material. Biosci Biotechnol Biochem 61(2):219–224CrossRefGoogle Scholar
- 4.Thiruvengadam V, Vitta S (2013) Ni–bacterial cellulose nanocomposite; a magnetically active inorganic–organic hybrid gel. RSC Adv 3(31):12765–12773CrossRefGoogle Scholar
- 5.Iguchi M, Yamanaka S, Budhiono A (2000) Bacterial cellulose—a masterpiece of nature’s arts. J Mater Sci 35(2):261–270. doi: 10.1023/A:1004775229149 CrossRefGoogle Scholar
- 6.Huang Y, Zhu C, Yang J, Nie Y, Chen C, Sun D (2014) Recent advances in bacterial cellulose. Cellulose 21(1):1–30CrossRefGoogle Scholar
- 7.Klemm D, Schumann D, Udhardt U, Marsch S (2001) Bacterial synthesized cellulose—artificial blood vessels for microsurgery. Prog Polym Sci 26(9):1561–1603CrossRefGoogle Scholar
- 8.Luo C, Stoyanov SD, Stride E, Pelan E, Edirisinghe M (2012) Electrospinning versus fibre production methods: from specifics to technological convergence. Chem Soc Rev 41(13):4708–4735CrossRefGoogle Scholar
- 9.Jradi K, Bideau B, Chabot B, Daneault C (2012) Characterization of conductive composite films based on TEMPO-oxidized cellulose nanofibers and polypyrrole. J Mater Sci 47(8):3752–3762. doi: 10.1007/s10853-011-6226-9 CrossRefGoogle Scholar
- 10.Yang J, Sun D, Li J, Yang X, Yu J, Hao Q, Liu W, Liu J, Zou Z, Gu J (2009) In situ deposition of platinum nanoparticles on bacterial cellulose membranes and evaluation of PEM fuel cell performance. Electrochim Acta 54(26):6300–6305CrossRefGoogle Scholar
- 11.Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Ed 44(22):3358–3393CrossRefGoogle Scholar
- 12.Olsson RT, Samir MA, Salazar-Alvarez G, Belova L, Ström V, Berglund LA, Ikkala O, Nogues J, Gedde UW (2010) Making flexible magnetic aerogels and stiff magnetic nanopaper using cellulose nanofibrils as templates. Nat Nanotechnol 5(8):584–588CrossRefGoogle Scholar
- 13.Legnani C, Vilani C, Calil V, Barud H, Quirino W, Achete C, Ribeiro S, Cremona M (2008) Bacterial cellulose membrane as flexible substrate for organic light emitting devices. Thin Solid Films 517(3):1016–1020CrossRefGoogle Scholar
- 14.Zakirov AS, Yuldashev SU, Wang HJ, Lee JC, Kang TW, Mamadalimov AT (2010) Study on electrical transport and photoconductivity in iodine-doped cellulose fibers. J Mater Sci 46(4):896–901. doi: 10.1007/s10853-010-4832-6 CrossRefGoogle Scholar
- 15.Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50(24):5438–5466CrossRefGoogle Scholar
- 16.Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40(7):3941–3994CrossRefGoogle Scholar
- 17.Snook GA, Kao P, Best AS (2011) Conducting-polymer-based supercapacitor devices and electrodes. J Power Sources 196(1):1–12CrossRefGoogle Scholar
- 18.Ramya R, Sivasubramanian R, Sangaranarayanan M (2013) Conducting polymers-based electrochemical supercapacitors—progress and prospects. Electrochim Acta 101:109–129CrossRefGoogle Scholar
- 19.Malhotra BD, Chaubey A, Singh S (2006) Prospects of conducting polymers in biosensors. Anal Chim Acta 578(1):59–74CrossRefGoogle Scholar
- 20.Bhadra S, Singha NK, Khastgir D (2008) Effect of aromatic substitution in aniline on the properties of polyaniline. Eur Polym J 44(6):1763–1770CrossRefGoogle Scholar
- 21.Mihranyan A, Esmaeili M, Razaq A, Alexeichik D, Lindström T (2012) Influence of the nanocellulose raw material characteristics on the electrochemical and mechanical properties of conductive paper electrodes. J Mater Sci 47(10):4463–4472. doi: 10.1007/s10853-012-6305-6 CrossRefGoogle Scholar
- 22.Zhang X, Zhang J, Song W, Liu Z (2006) Controllable synthesis of conducting polypyrrole nanostructures. J Phys Chem B 110(3):1158–1165CrossRefGoogle Scholar
- 23.Müller D, Rambo C, Recouvreux D, Porto L, Barra G (2011) Chemical in situ polymerization of polypyrrole on bacterial cellulose nanofibers. Synth Met 161(1):106–111CrossRefGoogle Scholar
- 24.Shi Z, Gao H, Feng J, Ding B, Cao X, Kuga S, Wang Y, Zhang L, Cai J (2014) In situ synthesis of robust conductive cellulose/polypyrrole composite aerogels and their potential application in nerve regeneration. Angew Chem Int Ed 53(21):5380–5384CrossRefGoogle Scholar
- 25.Wang H, Bian L, Zhou P, Tang J, Tang W (2013) Core–sheath structured bacterial cellulose/polypyrrole nanocomposites with excellent conductivity as supercapacitors. J Mater Chem A 1(3):578–584CrossRefGoogle Scholar
- 26.Xu J, Zhu L, Bai Z, Liang G, Liu L, Fang D, Xu W (2013) Conductive polypyrrole–bacterial cellulose nanocomposite membranes as flexible supercapacitor electrode. Org Electron 14(12):3331–3338CrossRefGoogle Scholar
- 27.Li S, Huang D, Yang J, Zhang B, Zhang X, Yang G, Wang M, Shen Y (2014) Freestanding bacterial cellulose–polypyrrole nanofibres paper electrodes for advanced energy storage devices. Nano Energy 9:309–317CrossRefGoogle Scholar
- 28.Su F, Poh CK, Chen JS, Xu G, Wang D, Li Q, Lin J, Lou XW (2011) Nitrogen-containing microporous carbon nanospheres with improved capacitive properties. Energy Environ Sci 4(3):717–724CrossRefGoogle Scholar
- 29.Olsson H, Carlsson DO, Nyström G, Sjödin M, Nyholm L, Strømme M (2012) Influence of the cellulose substrate on the electrochemical properties of paper-based polypyrrole electrode materials. J Mater Sci 47(13):5317–5325. doi: 10.1007/s10853-012-6418-y CrossRefGoogle Scholar
- 30.Muller D, Rambo CR, Porto LM, Schreiner WH, Barra GM (2013) Structure and properties of polypyrrole/bacterial cellulose nanocomposites. Carbohydr Polym 94(1):655–662. doi: 10.1016/j.carbpol.2013.01.041 CrossRefGoogle Scholar
- 31.Yuan L, Yao B, Hu B, Huo K, Chen W, Zhou J (2013) Polypyrrole-coated paper for flexible solid-state energy storage. Energy Environ Sci 6(2):470–476CrossRefGoogle Scholar
- 32.Feng Y, Zhang X, Shen Y, Yoshino K, Feng W (2012) A mechanically strong, flexible and conductive film based on bacterial cellulose/graphene nanocomposite. Carbohydr Polym 87(1):644–649. doi: 10.1016/j.carbpol.2011.08.039 CrossRefGoogle Scholar
- 33.Casado U, Quintanilla R, Aranguren M, Marcovich N (2012) Composite films based on shape memory polyurethanes and nanostructured polyaniline or cellulose–polyaniline particles. Synth Met 162(17):1654–1664CrossRefGoogle Scholar
- 34.Kebiche H, Debarnot D, Merzouki A, Poncin-Epaillard F, Haddaoui N (2012) Relationship between ammonia sensing properties of polyaniline nanostructures and their deposition and synthesis methods. Anal Chim Acta 737:64–71CrossRefGoogle Scholar
- 35.Shi Z, Zang S, Jiang F, Huang L, Lu D, Ma Y, Yang G (2012) In situ nano-assembly of bacterial cellulose–polyaniline composites. Rsc Adv 2(3):1040–1046CrossRefGoogle Scholar
- 36.Hu W, Chen S, Yang Z, Liu L, Wang H (2011) Flexible electrically conductive nanocomposite membrane based on bacterial cellulose and polyaniline. J Phys Chem B 115(26):8453–8457CrossRefGoogle Scholar
- 37.Park M, Cheng J, Choi J, Kim J, Hyun J (2013) Electromagnetic nanocomposite of bacterial cellulose using magnetite nanoclusters and polyaniline. Colloids Surf B 102:238–242CrossRefGoogle Scholar
- 38.Lin Z, Guan Z, Huang Z (2013) New bacterial cellulose/polyaniline nanocomposite film with one conductive side through constrained interfacial polymerization. Ind Eng Chem Res 52(8):2869–2874CrossRefGoogle Scholar
- 39.Liu D, Sui G, Bhattacharyya D (2014) Synthesis and characterisation of nanocellulose-based polyaniline conducting films. Compos Sci Technol 99:31–36CrossRefGoogle Scholar
- 40.Wang H, Zhu E, Yang J, Zhou P, Sun D, Tang W (2012) Bacterial cellulose nanofiber-supported polyaniline nanocomposites with flake-shaped morphology as supercapacitor electrodes. J Phys Chem C 116(24):13013–13019CrossRefGoogle Scholar
- 41.Lai F, Miao Y-E, Huang Y, Zhang Y, Liu T (2015) Nitrogen-doped carbon nanofiber/molybdenum disulfide nanocomposites derived from bacterial cellulose for high-efficiency electrocatalytic hydrogen evolution reaction. ACS Appl Mater Interfaces. doi: 10.1021/acsami.5b06274 Google Scholar
- 42.Xu D, Xiao X, Cai J, Zhou J, Zhang L (2015) Highly rate and cycling stable electrode materials constructed from polyaniline/cellulose nanoporous microspheres. J Mater Chem A 3(32):16424–16429CrossRefGoogle Scholar
- 43.Khan S, Ul-Islam M, Khattak WA, Ullah MW, Park JK (2015) Bacterial cellulose–poly (3, 4-ethylenedioxythiophene)–poly (styrenesulfonate) composites for optoelectronic applications. Carbohydr Polym 127:86–93CrossRefGoogle Scholar
- 44.Huang L, Chen K, Peng C, Gerhardt RA (2011) Highly conductive paper fabricated with multiwalled carbon nanotubes and poly (3,4-ethylenedioxythiophene)-poly (styrenesulfonate) by unidirectional drying. J Mater Sci 46(20):6648–6655. doi: 10.1007/s10853-011-5617-2 CrossRefGoogle Scholar
- 45.Chen C, Yu Y, Li K, Zhao M, Liu L, Yang J, Liu J, Sun D (2015) Facile approach to the fabrication of 3D electroconductive nanofibers with controlled size and conductivity templated by bacterial cellulose. Cellulose 22(6):3929–3939CrossRefGoogle Scholar
- 46.Chen C, Zhang T, Zhang Q, Feng Z, Zhu C, Yu Y, Li K, Zhao M, Yang J, Liu J (2015) Three-dimensional BC/PEDOT composite nanofibers with high performance for electrode-cell interface. ACS Appl Mater Interfaces. doi: 10.1021/acsami.5b07273 Google Scholar
- 47.Wang F, Jeon J-H, Park S, Kee C-D, Kim S-J, Oh I-K (2016) A soft biomolecule actuator based on a highly functionalized bacterial cellulose nano-fiber network with carboxylic acid groups. Soft Matter. doi: 10.1039/c5sm00707k Google Scholar
- 48.Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6(3):183–191CrossRefGoogle Scholar
- 49.Castro Neto AH, Guinea F, Peres NMR, Novoselov KS, Geim AK (2009) The electronic properties of graphene. Rev Mod Phys 81(1):109–162. doi: 10.1103/RevModPhys.81.109 CrossRefGoogle Scholar
- 50.Geim AK (2009) Graphene: status and prospects. Science 324(5934):1530–1534CrossRefGoogle Scholar
- 51.Li K, Feng L, Shen J, Zhang Q, Liu Z, Lee ST, Liu J (2014) Patterned substrates of nano-graphene oxide mediating highly localized and efficient gene delivery. ACS Appl Mater Interfaces 6(8):5900–5907. doi: 10.1021/am5008134 CrossRefGoogle Scholar
- 52.Valentini L, Bittolo Bon S, Fortunati E, Kenny JM (2013) Preparation of transparent and conductive cellulose nanocrystals/graphene nanoplatelets films. J Mater Sci 49(3):1009–1013. doi: 10.1007/s10853-013-7776-9 CrossRefGoogle Scholar
- 53.Shao W, Liu H, Liu X, Wang S, Zhang R (2015) Anti-bacterial performances and biocompatibility of bacterial cellulose/graphene oxide composites. RSC Adv 5(7):4795–4803CrossRefGoogle Scholar
- 54.Luo H, Xiong G, Yang Z, Raman SR, Si H, Wan Y (2014) A novel three-dimensional graphene/bacterial cellulose nanocomposite prepared by in situ biosynthesis. Rsc Adv 4(28):14369–14372CrossRefGoogle Scholar
- 55.Liu Y, Zhou J, Zhu E, Tang J, Liu X, Tang W (2015) Facile synthesis of bacterial cellulose fibres covalently intercalated with graphene oxide by one-step cross-linking for robust supercapacitors. J Mater Chem C 3(5):1011–1017. doi: 10.1039/C4TC01822B CrossRefGoogle Scholar
- 56.Wang J, Feng M, Zhan H (2014) Preparation, characterization, and nonlinear optical properties of graphene oxide-carboxymethyl cellulose composite films. Opt Laser Technol 57:84–89CrossRefGoogle Scholar
- 57.Muller D, Silva JP, Rambo C, Barra G, Dourado F, Gama F (2013) Neuronal cells’ behavior on polypyrrole coated bacterial nanocellulose three-dimensional (3D) scaffolds. J Biomater Sci Polym Ed 24(11):1368–1377CrossRefGoogle Scholar
- 58.Liu Y, Zhou J, Tang J, Tang W (2015) Three-dimensional, chemically bonded polypyrrole/bacterial cellulose/graphene composites for high-performance supercapacitors. Chem Mater 27(20):7034–7041CrossRefGoogle Scholar
- 59.Lota G, Fic K, Frackowiak E (2011) Carbon nanotubes and their composites in electrochemical applications. Energy Environ Sci 4(5):1592–1605CrossRefGoogle Scholar
- 60.Kim B, Chung H, Kim W (2012) High-performance supercapacitors based on vertically aligned carbon nanotubes and nonaqueous electrolytes. Nanotechnology 23(15):155401CrossRefGoogle Scholar
- 61.Park W-I, Kim H-S, Kwon S-M, Hong Y-H, Jin H-J (2009) Synthesis of bacterial celluloses in multiwalled carbon nanotube-dispersed medium. Carbohydr Polym 77(3):457–463CrossRefGoogle Scholar
- 62.Yan Z, Chen S, Wang H, Wang B, Wang C, Jiang J (2008) Cellulose synthesized by Acetobacter xylinum in the presence of multi-walled carbon nanotubes. Carbohydr Res 343(1):73–80CrossRefGoogle Scholar
- 63.Yan Z, Chen S, Wang H, Wang B, Jiang J (2008) Biosynthesis of bacterial cellulose/multi-walled carbon nanotubes in agitated culture. Carbohydr Polym 74(3):659–665CrossRefGoogle Scholar
- 64.Yoon SH, Jin H-J, Kook M-C, Pyun YR (2006) Electrically conductive bacterial cellulose by incorporation of carbon nanotubes. Biomacromolecules 7(4):1280–1284CrossRefGoogle Scholar
- 65.Farjana S, Toomadj F, Lundgren P, Sanz-Velasco A, Naboka O, Enoksson P (2013) Conductivity-dependent strain response of carbon nanotube treated bacterial nanocellulose. J SensGoogle Scholar
- 66.Meng C, Liu C, Chen L, Hu C, Fan S (2010) Highly flexible and all-solid-state paperlike polymer supercapacitors. Nano Lett 10(10):4025–4031CrossRefGoogle Scholar
- 67.Miller JR, Simon P (2008) Electrochemical capacitors for energy management. Sci Mag 321(5889):651–652Google Scholar
- 68.Simon P, Gogotsi Y (2008) Materials for electrochemical capacitors. Nat Mater 7(11):845–854CrossRefGoogle Scholar
- 69.Kang YJ, Chun S-J, Lee S-S, Kim B-Y, Kim JH, Chung H, Lee S-Y, Kim W (2012) All-solid-state flexible supercapacitors fabricated with bacterial nanocellulose papers, carbon nanotubes, and triblock-copolymer ion gels. ACS Nano 6(7):6400–6406CrossRefGoogle Scholar
- 70.O-Rak K, Ummartyotin S, Sain M, Manuspiya H (2013) Covalently grafted carbon nanotube on bacterial cellulose composite for flexible touch screen application. Mater Lett 107:247–250CrossRefGoogle Scholar
- 71.Kim YH, Park S, Won K, Kim HJ, Lee SH (2013) Bacterial cellulose–carbon nanotube composite as a biocompatible electrode for the direct electron transfer of glucose oxidase. J Chem Technol Biotechnol 88(6):1067–1070CrossRefGoogle Scholar
- 72.Chen P, Kim H-S, Kwon S-M, Yun YS, Jin H-J (2009) Regenerated bacterial cellulose/multi-walled carbon nanotubes composite fibers prepared by wet-spinning. Curr Appl Phys 9(2):e96–e99CrossRefGoogle Scholar
- 73.Chen P, Yun YS, Bak H, Cho SY, Jin H-J (2010) Multiwalled carbon nanotubes-embedded electrospun bacterial cellulose nanofibers. Mol Cryst Liq Cryst 519(1):169–178CrossRefGoogle Scholar
- 74.Huang HX, Chen SX, Ce Yuan (2008) Platinum nanoparticles supported on activated carbon fiber as catalyst for methanol oxidation. J Power Sources 175(1):166–174CrossRefGoogle Scholar
- 75.Yuan D, Huang X, Yan J, Yu W, Meng H, Rong J (2013) Porous carbon nanofibers derived from bacterial cellulose for sustainable energy storage. Sci Adv Mater 5(11):1694–1700CrossRefGoogle Scholar
- 76.Liu Y, Qin W, Wang Q, Liu R, Liu H (2014) Glassy carbon nanofibers from electrospun cellulose nanofiber. J Mater Sci 50(2):563–569. doi: 10.1007/s10853-014-8612-6 CrossRefGoogle Scholar
- 77.Wu Z-Y, Li C, Liang H-W, Zhang Y-N, Wang X, Chen J-F, Yu S-H (2014) Carbon nanofiber aerogels for emergent cleanup of oil spillage and chemical leakage under harsh conditions. Sci Rep. doi: 10.1038/srep04079 Google Scholar
- 78.Wu ZY, Li C, Liang HW, Chen JF, Yu SH (2013) Ultralight, flexible, and fire-resistant carbon nanofiber aerogels from bacterial cellulose. Angew Chem 125(10):2997–3001CrossRefGoogle Scholar
- 79.Dumanlı AG, Windle AH (2012) Carbon fibres from cellulosic precursors: a review. J Mater Sci 47(10):4236–4250. doi: 10.1007/s10853-011-6081-8 CrossRefGoogle Scholar
- 80.Lee K-Y, Qian H, Tay FH, Blaker JJ, Kazarian SG, Bismarck A (2012) Bacterial cellulose as source for activated nanosized carbon for electric double layer capacitors. J Mater Sci 48(1):367–376. doi: 10.1007/s10853-012-6754-y CrossRefGoogle Scholar
- 81.Wu Z-Y, Liang H-W, Li C, Hu B-C, Xu X-X, Wang Q, Chen J-F, Yu S-H (2014) Dyeing bacterial cellulose pellicles for energetic heteroatom doped carbon nanofiber aerogels. Nano Res 7(12):1861–1872CrossRefGoogle Scholar
- 82.Tong S, Zheng M, Lu Y, Lin Z, Zhang X, He P, Zhou H (2015) Binder-free carbonized bacterial cellulose-supported ruthenium nanoparticles for Li–O2 batteries. Chem Commun 51(34):7302–7304CrossRefGoogle Scholar
- 83.Huang Y, Wang T, Ji M, Yang J, Zhu C, Sun D (2014) Simple preparation of carbonized bacterial cellulose–Pt composite as a high performance electrocatalyst for direct methanol fuel cells (DMFC). Mater Lett 128:93–96CrossRefGoogle Scholar
- 84.Wang S, Liu K, Liu J, Yu ZT, Xu X, Zhao L, Lee T, Lee EK, Reiss J, Lee YK, Chung LW, Huang J, Rettig M, Seligson D, Duraiswamy KN, Shen CK, Tseng HR (2011) Highly efficient capture of circulating tumor cells by using nanostructured silicon substrates with integrated chaotic micromixers. Angew Chem Int Ed Engl 50(13):3084–3088. doi: 10.1002/anie.201005853 CrossRefGoogle Scholar
- 85.Huang Y, Zheng M, Lin Z, Zhao B, Zhang S, Yang J, Zhu C, Zhang H, Sun D, Shi Y (2015) Flexible cathodes and multifunctional interlayers based on carbonized bacterial cellulose for high-performance lithium–sulfur batteries. J Mater Chem A 3(20):10910–10918CrossRefGoogle Scholar
- 86.Wang L, Schütz C, Salazar-Alvarez G, Titirici M-M (2014) Carbon aerogels from bacterial nanocellulose as anodes for lithium ion batteries. RSC Adv 4(34):17549–17554CrossRefGoogle Scholar
- 87.Wan Y, Yang Z, Xiong G, Guo R, Liu Z, Luo H (2015) Anchoring Fe3O4 nanoparticles on three-dimensional carbon nanofibers toward flexible high-performance anodes for lithium-ion batteries. J Power Sources 294:414–419CrossRefGoogle Scholar
- 88.Cruz-Silva E, Lopez-Urias F, Munoz-Sandoval E, Sumpter BG, Terrones H, Charlier J-C, Meunier V, Terrones M (2009) Electronic transport and mechanical properties of phosphorus-and phosphorus—nitrogen-doped carbon nanotubes. ACS Nano 3(7):1913–1921CrossRefGoogle Scholar
- 89.Hu Z, Li S, Cheng P, Yu W, Li R, Shao X, Lin W, Yuan D (2015) N, P-co-doped carbon nanowires prepared from bacterial cellulose for supercapacitor. J Mater Sci 51(5):2627–2633. doi: 10.1007/s10853-015-9576-x CrossRefGoogle Scholar
- 90.Chen LF, Huang ZH, Liang HW, Guan QF, Yu SH (2013) Bacterial-cellulose-derived carbon nanofiber@ MnO2 and nitrogen-doped carbon nanofiber electrode materials: an asymmetric supercapacitor with high energy and power density. Adv Mater 25(34):4746–4752CrossRefGoogle Scholar
- 91.Meng F, Li L, Wu Z, Zhong H, Li J, Yan J (2014) Facile preparation of N-doped carbon nanofiber aerogels from bacterial cellulose as an efficient oxygen reduction reaction electrocatalyst. Chin J Catal 35(6):877–883CrossRefGoogle Scholar
- 92.Liang H-W, Wu Z-Y, Chen L-F, Li C, Yu S-H (2015) Bacterial cellulose derived nitrogen-doped carbon nanofiber aerogel: an efficient metal-free oxygen reduction electrocatalyst for zinc-air battery. Nano Energy 11:366–376CrossRefGoogle Scholar
- 93.Chen L-F, Zhang X-D, Liang H-W, Kong M, Guan Q-F, Chen P, Wu Z-Y, Yu S-H (2012) Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors. ACS Nano 6(8):7092–7102CrossRefGoogle Scholar
- 94.Hulicova-Jurcakova D, Kodama M, Shiraishi S, Hatori H, Zhu ZH, Lu GQ (2009) Nitrogen-enriched nonporous carbon electrodes with extraordinary supercapacitance. Adv Funct Mater 19(11):1800–1809CrossRefGoogle Scholar
- 95.Cao B, Zhang B, Jiang X, Zhang Y, Pan C (2011) Direct synthesis of high concentration N-doped coiled carbon nanofibers from amine flames and its electrochemical properties. J Power Sources 196(18):7868–7873CrossRefGoogle Scholar
- 96.Lota G, Lota K, Frackowiak E (2007) Nanotubes based composites rich in nitrogen for supercapacitor application. Electrochem Commun 9(7):1828–1832CrossRefGoogle Scholar
- 97.Chen L-F, Huang Z-H, Liang H-W, Yao W-T, Yu Z-Y, Yu S-H (2013) Flexible all-solid-state high-power supercapacitor fabricated with nitrogen-doped carbon nanofiber electrode material derived from bacterial cellulose. Energy Environ Sci 6(11):3331–3338CrossRefGoogle Scholar
- 98.Yu W, Lin W, Shao X, Hu Z, Li R, Yuan D (2014) High performance supercapacitor based on Ni3S2/carbon nanofibers and carbon nanofibers electrodes derived from bacterial cellulose. J Power Sources 272:137–143. doi: 10.1016/j.jpowsour.2014.08.064 CrossRefGoogle Scholar
- 99.Chen LF, Huang ZH, Liang HW, Gao HL, Yu SH (2014) Three-dimensional heteroatom-doped carbon nanofiber networks derived from bacterial cellulose for supercapacitors. Adv Funct Mater 24(32):5104–5111. doi: 10.1002/adfm.201400590 CrossRefGoogle Scholar
- 100.Li S, Huang D, Zhang B, Xu X, Wang M, Yang G, Shen Y (2014) Flexible supercapacitors based on bacterial cellulose paper electrodes. Adv Energy Mater 4(10):1301655–1301661Google Scholar