Cr doping and heat treatment effect on core–shell Ni nanocluster film
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Core–shell nickel (CS-Ni) and 5 at.% chromium-doped nickel (CS-Ni5Cr) nanocluster (NC) films, prepared by a nanocluster deposition system, were studied for heat treatment (HT)-induced structural, physical, and magnetic property alterations. Understanding the HT influence and oxidation mechanism at nanoscale can make these nanomaterials potential candidates for applications that involve stainless steel alloys. The contribution of Cr doping in altering the microstructural and relative oxidation kinetics was investigated in detail before and after the HT. The oxidation mechanism describes that the cation diffusivity increases following the doping of 5 at.% of Cr in Ni, which makes the oxidation rate of Ni5Cr HT higher than that of Ni-HT. At a temperature of 600 °C, a dramatic change was observed in surface morphology with many island-like nanostructures on the surface of Ni5Cr. The interface structure of the Cr-rich oxide layer plays a key role in the islands formation via agglomeration of NCs. The as-prepared and HT samples were analyzed by transmission electron microscopy, atomic force microscopy, magnetic force microscopy, energy-dispersive spectroscopy, and vibrating sample magnetometer to provide an insight on the effectiveness of chromium-doped nickel film.
KeywordsHeat Treatment Magnetic Force Microscope Heat Treatment Sample Lift Height Magnetic Force Microscope Image
This work was supported by U.S. Department of Energy (DOE) under Contract DE-FC07-08ID14926, by the INL-LDRD administered by the Center for Advanced Energy Studies (CAES) under the DOE Contract DE-AC07-05ID14517.
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Conflict of Interest
The authors declare that they have no conflict of interest.
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