Journal of Materials Science

, Volume 50, Issue 23, pp 7698–7704 | Cite as

The origin of the effect of aging on the thermoelectric power of maraging C250 steel

  • M. Pinkas
  • O. Moshka
  • S. Okavi
  • M. Shmuelevitsh
  • Y. Gelbstein
  • N. Froumin
  • L. Meshi
Original Paper

Abstract

The sensitivity of thermoelectric power (TEP) to the aging condition of maraging C250 steel was investigated. TEP revealed a high sensitivity to the aging process as its value decreased by ~17 μV/K following 3 h of aging at 510 °C. This is a noticeably large change for metallic systems undergoing metallurgical modifications. Using model alloys, we show that the significant change in TEP is mainly due to the depletion of the matrix from the precipitating elements which change the electron density in the Fermi level, as was confirmed by X-ray photoelectron spectroscopy.

Keywords

Thermoelectric Power Maraging Steel Lath Martensite Ni3Ti C250 Steel 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

This study was supported by the joint IAEC-UPBC Pazy foundation, Grant No. 151. The authors express their gratitude to Mr. S. Levi, Mr. Y. Alon, Mr. M. Amos, Mr. O. Omasi, and Mr. Z. Foxman for their technical assistance.

References

  1. 1.
    Decker RF, Eash JT, Goldman AJ (1962) 18% Ni maraging steel. Trans Quarterly ASM 55(1):58–76Google Scholar
  2. 2.
    Vasudevan VK, Kim SG, Wayman CM (1990) Precipitation reactions and strengthening behavior in 18 wt pct nickel maraging steels. Metall Trans A 21(10):2655–2668CrossRefGoogle Scholar
  3. 3.
    Floreen S (1968) The physical metallurgy of maraging steels. Metall Rev 13(1):115–128Google Scholar
  4. 4.
    Sha W, Cerezo A, Smith GDW (1993) Phase chemistry and precipitation reactions in maragind steels. 1. Introduction and study of Co-containing C-300 steel. Metall Trans 24A:1221–1232CrossRefGoogle Scholar
  5. 5.
    Sha W, Cerezo A, Smith GDW (1993) Phase chemistry and precipitation reactions in maragind steels.2. Co-free T-300 steel. Metall Trans 24A:1233–1239CrossRefGoogle Scholar
  6. 6.
    Tewari R, Mazumder S, Barta IS, Rey GK, Banerjee S (2000) Precipitation in 18 wt% Ni maraging steel of grade 350. Acta Mater 48:1187–1200CrossRefGoogle Scholar
  7. 7.
    Rao MN (2006) Progress in understanding the metallurgy of 18 % Ni ckel maraging steel. Int J Mater Res (formerly Z. Metallkd) 97(11):1594–1607CrossRefGoogle Scholar
  8. 8.
    Viswanathan UK, Dey GK, Asundi MK (1993) Precipitation hardening in 350-grade maraging steel. Metall Trans 24A(11):2429–2442CrossRefGoogle Scholar
  9. 9.
    Moshka O, Pinkas M, Brosh E, Ezersky V, Meshi L (2015) Addressing the issue of precipitates in maraging steels—unambiguous answer. Mater Sci Eng, A 638:232–239CrossRefGoogle Scholar
  10. 10.
    Mahadevan S, Jayakumar T, Rao BPC, Kumar A, Rajkumar KV, Raj B (2008) X-ray diffraction profile analysis for characterizing isothermal aging behavior of M250 grade maraging steel. Metall Mater Trans A 39A(8):1978–1984CrossRefGoogle Scholar
  11. 11.
    Rajkumar KV, Kumar A, Jayakumar T, Raj B (2007) Characterization of aging behavior in M250 grade maraging steel using ultrasonic measurements. Met. Mat. Trans. A 38A(2):236–243CrossRefGoogle Scholar
  12. 12.
    Rajkumar KV, Rao BPC, Sasi B, Kumar A, Jayakumar T, Raj B (2007) Characterization of aging behaviour in M250 grade maraging steel using eddy current non-destructive methodology. Mater Sci Eng, A 464(1–2):233–240CrossRefGoogle Scholar
  13. 13.
    Rajkumar KV, Vaidyanathan S, Kumar A, Jayakumar T, Raj B, Ray KK (2007) Characterization of aging-induced microstructural changes in M250 maraging steel using magnetic parameters. J Magn Magn Mater 312(2):359–365CrossRefGoogle Scholar
  14. 14.
    Barnard RD (1972) Thermoelectricity in metals and alloys. Taylor & Francis Ltd., LondonGoogle Scholar
  15. 15.
    Raynaud GM, Guyot P (1988) Coherent precipitation effect on thermo-power of Al-Cu alloys. Acta Metall 36(1):143–147CrossRefGoogle Scholar
  16. 16.
    Tkalcec I, Azcoitia C, Crevoiserat S, Mari D (2004) Tempering effects on a martensitic high carbon steel. Mater Sci Eng A 387:352–356CrossRefGoogle Scholar
  17. 17.
    Pelletier JM, Vigier G, Merlin J, Merle P, Fouqoet F, Borrelly R (1984) Precipitation effect on thermopower in Al-Cu alloys. Acta Mater 32(7):1069–1078CrossRefGoogle Scholar
  18. 18.
    Ferrer JP, De Cock T, Capdevila C, Caballero FG, de Andrés CG (2007) Comparison of the annealing behaviour between cold and warm rolled. Acta Mater 55(6):2075–2083CrossRefGoogle Scholar
  19. 19.
    Soto-Parra DE, Flores-Zúñiga H, Cuéllar EL, Ochoa-Gamboa RA, Ríos-Jara D (2014) Recrystallization of a Ti-45Ni-5Cu cold-worked shape memory alloy characterized by thermoelectric power and electrical properties. Mater Res 14(4):1023–1030CrossRefGoogle Scholar
  20. 20.
    Kawaguchi Y, Yamanaka S (2002) Mechanism of the change in thermoelectric power of cast duplex stainless. J Alloy Compd 336:301–314CrossRefGoogle Scholar
  21. 21.
    Pinkas M, Foxman Z, Froumin N, Hähner P, Meshi L (2015) Sensitivity of thermo-electric power measurements to α-α’ phase separation in Cr-rich oxide dispersion strengthened steel. J Mater Sci 50:4629–4635. doi: 10.1007/s10853-015-9014-0 CrossRefGoogle Scholar
  22. 22.
    Danon A, Alamo A (2002) Behavior of Eurofer97 reduced activation martensitic steel upon heating and continuous cooling. J Nucl Mater 307:479–483CrossRefGoogle Scholar
  23. 23.
    Niffenegger M, Leber HJ (2009) Monitoring the embrittlement of reactor pressure vessel steels. J Nucl Mater 389:62–67CrossRefGoogle Scholar
  24. 24.
    Houze M, Kleber X, Fouquet F, Delnondedieu M (2004) Study of molybdenum precipitation in steels using thermoelectric power measurement. Scr Mater 51:1171–1176CrossRefGoogle Scholar
  25. 25.
    Caballero FG, Capdevila C, Alvarez LF, de Andres CG (2004) Thermoelectric power studies on a martensitic stainless steel. Scr Mater 50:1061–1066CrossRefGoogle Scholar
  26. 26.
    Mott NF, Jones H (1958) The theory and properties of metals and alloys. Dover, New YorkGoogle Scholar
  27. 27.
    Lavaire N, Massardier V, Merlin J (2004) Quantitative evaluation of the interstitial content (C and/or N) in solid solution in extra-mild steels by thermoelectric power measurements. Scr Mater 50:131–135CrossRefGoogle Scholar
  28. 28.
    Merlin J, Merle P, Garnier S, Bouzekri M (2004) Experimental determination of the carbon solubility limit in ferritic steels. Metall Mater Trans A 35A:1655–1661CrossRefGoogle Scholar
  29. 29.
    Rana R, Singh SB, Mohanty ON (2006) Thermoelectric power studies of copper precipitation in a new interstitial-free steel. Scr Mater 55(12):1107–1110CrossRefGoogle Scholar
  30. 30.
    Pelletier JM, Borrelly R (1982) Temperature and concentration dependences of thermoelectric power at high temperatures in some aluminium alloys. Mater Sci Eng 55:191–202CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • M. Pinkas
    • 1
  • O. Moshka
    • 2
  • S. Okavi
    • 2
  • M. Shmuelevitsh
    • 1
  • Y. Gelbstein
    • 2
  • N. Froumin
    • 2
    • 3
  • L. Meshi
    • 2
    • 3
  1. 1.Nuclear Research Center-NegevBeer-ShevaIsrael
  2. 2.Department of Materials EngineeringBen Gurion University of the NegevBeer-ShevaIsrael
  3. 3.Ilse Katz Institute for Nanoscale Science & TechnologyBen Gurion University of the NegevBeer-ShevaIsrael

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